Beruflich Dokumente
Kultur Dokumente
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Rayleigh
scattering
Stokes
scattering
Anti-Stokes
scattering
(1)
(2)
(3)
(4)
Basic theory of Raman Scattering
Instrumentation and Experimental
techniques
Three Major parts are
1. Excitation Source
2. Sample illumination system and collection
optics
3. Monochromator and detector
Instrumentation and Experimental
techniques
1. Excitation Source:
In modern Raman spectroscopy laser are
used as excitation source because of its high
intensity.
Most commonly used laser
Ar
+
(488 nm), Kr
+
(530.9 or 647.1),
He-Ne(633 nm), Diode laser(782 or 830 nm),
Nd: YAG (1064 nm)
Instrumentation and Experimental
techniques
2. Sample illumination system and collection optics
Instrumentation and Experimental
techniques
3. Monochromator and detector
Instrumentation and Experimental
techniques
M1
M2
Application
Fingerprint probe
Composition can be determined if there are
reference data on well-characterised material.
It usually shows discontinuous changes
across structural phase transitions.
Crystal orientation can usually be
determined.
LabRAM HR 800
Parts Description:
Four basic parts are
1. Laser: He-Ne(633nm),
Ar
+
(488nm)
2. Optics: A filter wheel,
interference filter, notch filter
3. Microscope: 10x, 20x, 50x,
and100x
4. Spectrometer: Gratings- 600
and 1800 grooves/mm
Raman spectra of CuO at different pressures
Pressure dependence of Raman modes of CuO
1
w
a
a
a
a
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