Partially Miscible Liquids: Determination of Mutual Solubility Post Laboratory Report

Experiment No.
2
Partially Miscible Liquids:
Determination of Mutual
Solubility
Group 2
Bello, Jean Raynell
Bustillo, Khazel
De Castro, Lindy Mariel
INTRODUCTION
Many liquid mixtures fall between miscible
and immiscible extremes. Two liquids are
partially miscible if shaking equal volumes
of the liquids together results in a meniscus
visible between two layers of liquid, but the
volumes of the layers are not identical to the
volumes of the liquids originally mixed. Liquids
tend to be immiscible when attractions
between like molecules are much stronger
than attractions between mixed pairs. (Logan,
1998)
PROCEDURE
The density of the sample was obtained
and the volume of water required was
calculated. A number of different mixtures
of phenol and water at 5% increment are
prepared. The mixture was heated in a
water bath with mild stirring and recorded
its constant temperature until the
cloudiness of the solution disappeared and
cooled instantly until the cloudiness
appears. The temperature was recorded.
The procedure was repeated for the
remaining weight ratios.
DATA AND RESULTS GROUP 1
0
10
20
30
40
50
60
70
80
0.00 0.20 0.40 0.60 0.80 1.00
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Phenol-Water Weight Ratio
Temperature vs. Phenol-Water Weight Ratio
T (heating)
T (cooling)
Poly. (T (heating))
Poly. (T (cooling))
Double-Phase
Region
Single-Phase
Region
y = -227.06x2 + 196.68x + 18.075
R = 0.8454
0
10
20
30
40
50
60
70
0.00 0.20 0.40 0.60 0.80 1.00
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Temperature (Heating) vs. Phenol-Water Weight
Ratio
Single-Phase
Region
Double -Phase Region
y = -212.32x2 + 199.35x + 21.842
R = 0.8186
0
10
20
30
40
50
60
70
80
0.00 0.20 0.40 0.60 0.80 1.00
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Temperature (Cooling) vs. Phenol-Water Weight
Ratio
Single-Phase
Region
Double-Phase
Region
0
10
20
30
40
50
60
70
80
90
0.00 0.20 0.40 0.60 0.80 1.00
T
e
m
p
e
r
a
t
u
r
e

(
C
)

T (Heating)
T (Cooling)
Poly. (T (Heating))
Poly. (T (Cooling))
Double-
Phase
Region
Single-Phase
Region
y = -248.11x
2
+ 245.09x + 11.307
R = 0.8116
0
10
20
30
40
50
60
70
80
90
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Ratio
Double-Phase
Region
Single-Phase
Region
y = -197.13x
2
+ 183.54x + 15.207
R = 0.7052
0
10
20
30
40
50
60
70
80
90
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Ratio
Single-Phase
Region
Double-Phase
Region
-10
0
10
20
30
40
50
60
70
80
90
0.00 0.20 0.40 0.60 0.80 1.00
T
e
m
p
e
r
a
t
u
r
e

(
C
)

T (heating)
T (cooling)
Poly. (T (heating))
Poly. (T (cooling))
Single-Phase
Region
Double-Phase
Region
y = -242.22x
2
+ 205.84x + 18.436
R = 0.8096
-10
0
10
20
30
40
50
60
70
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Ratio
Single-Phase
Region
Double-Phase
Region
y = -287.31x
2
+ 258.75x + 19.318
R = 0.8852
0
10
20
30
40
50
60
70
80
90
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Ratio
Single-Phase
Region
Double-Phase
Region
-10
0
10
20
30
40
50
60
70
80
0.00 0.20 0.40 0.60 0.80 1.00
T
e
m
p
e
r
a
t
u
r
e

(
C
)

T (heating)
T (cooling)
Poly. (T (heating))
Poly. (T (cooling))
Double-Phase
Region
Single-Phase
Region
y = -175.47x
2
+ 145.47x + 38.451
R = 0.8393
0
10
20
30
40
50
60
70
80
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Ratio
Single-Phase
Region
Double-Phase Region
y = 800x
2
- 1308x + 536.5
R = 0.9984
0
2
4
6
8
10
12
14
16
18
0.78 0.80 0.82 0.84 0.86 0.88 0.90 0.92 0.94 0.96
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Ratio
Single-Phase Region
Double-Phase Region
0
10
20
30
40
50
60
70
80
90
100
0.00 0.20 0.40 0.60 0.80 1.00
T
e
m
p
e
r
a
t
u
r
e

(
C
)

T (heating)
T (cooling)
Poly. (T (heating))
Poly. (T (cooling))
Single -Phase
Region
Double-Phase
Region
y = -182.4x
2
+ 146.68x + 49.151
R = 0.847
0
10
20
30
40
50
60
70
80
90
100
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Ratio
Double-Phase Region
Single-Phase
Region
y = -200.59x
2
+ 164.48x + 46.581
R = 0.8623
0
10
20
30
40
50
60
70
80
90
100
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Ratio
Double-Phase
Region
Single-Phase
Region
-20
-10
0
10
20
30
40
50
60
70
80
0.00 0.20 0.40 0.60 0.80 1.00
T
e
m
p
e
r
a
t
u
r
e

(
C
)

T (heating)
T (cooling)
Poly. (T (heating))
Poly. (T (cooling))
Single-Phase
Region
Double-Phase
Region
y = -332.72x
2
+ 268.77x + 0.0558
R = 0.83
0
10
20
30
40
50
60
70
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Ratio
Single-Phase
Region
Double-Phase
Region
y = -190.84x
2
+ 163.57x + 34.908
R = 0.8504
0
10
20
30
40
50
60
70
80
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Ratio
Single-Phase
Region
Double-Phase
Region
0
10
20
30
40
50
60
70
80
90
100
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90
T
e
m
p
e
r
a
t
u
r
e

(
C
)

T (heating)
T (cooling)
Poly. (T (heating))
Poly. (T (cooling))
Single-
Phase
Double-Phase
Region
y = -447.95x
2
+ 480.6x - 54.062
R = 0.8768
0
10
20
30
40
50
60
70
80
90
100
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Ratio
Single-Phase
Region
Double-Phase
Region
y = -271.93x
2
+ 278.35x - 13.087
R = 0.9406
0
10
20
30
40
50
60
70
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90
T
e
m
p
e
r
a
t
u
r
e

(
C
)

Ratio
Single-Phase
Region
Double-Phase
Region
ANSWERS TO QUESTIONS
1. Based on the plot, is there a maximum and/or
minimum critical solution temperature? What is the
critical temperature? Compare this with the
literature value.

The maximum critical solution temperature denotes
the warmest point at which cooling will induce
phase separation. On the other hand, the minimum
critical solution temperature denotes the coolest
point at which heating will induce phase
separation. Based on our group's data, the
maximum and minimum critical solution
temperatures are 64*C and 28*C respectively.
2. Are the different temperature readings constant
for the same wt% sample-water mixture? If not,
explain these differences.

The temperature readings were constant.
3. Explain why at high sample concentrations the
solution solidifies during the cooling process.

The concentrated mixture solidifies into a
solution that can be liquefied by a very small
amount of water. Since the freezing point of
phenol is very high thus, a high concentration
solution of phenol with water would solidify on
lower temperatures.
4. Suggest a procedure by which the composition
of a layer can be determined experimentally.

The composition of a layer can be determined
by getting the critical solution temperature
experimentally and plotting the points on the
graph. The weight percentage could
be obtained at the point where in the
temperature intersects the curve.
CONCLUSIONS
At the end of the experiment, the group concluded
the following statements:

The solubility of two partially miscible
liquids can be determined using the mutual
solubility curve for the pair.

Turbidity of the mixture signified the
transition of phases of the mixture.
THANK YOU VERY MUCH
FOR YOUR ATTENTION!

Partially Miscible Liquids: Determination of Mutual Solubility Post Laboratory Report

Hochgeladen von

Dokumentinformationen

Copyright

Verfügbare Formate

Dieses Dokument teilen

Dokument teilen oder einbetten

Freigabeoptionen

Stufen Sie dieses Dokument als nützlich ein?

Sind diese Inhalte unangemessen?

Copyright:

Verfügbare Formate

Partially Miscible Liquids: Determination of Mutual Solubility Post Laboratory Report

Hochgeladen von

Copyright:

Verfügbare Formate

Experiment No.

Das könnte Ihnen auch gefallen