Beruflich Dokumente
Kultur Dokumente
Background
Background
Structure
-Electrode
-glass plate coated in a TCO
- Semiconductor nanoparticles (typically TiO2 or ZnO)
-applied as a thin film to electrode, on top of TCO Layer
-Natural Dye (typically anthocyanin)
-adsorbed to the layer of semiconductor nanoparticles
-Iodide electrolyte
-in liquid form; placed between two electrodes
-Counter-electrode
-glass plate coated in TCO
-Catalyst
-typically platinum or carbon; coated onto counter-electrode to speed up electrolyte redox reaction
Mechanism
Experiment (preparation)
* Working Electrode
TiO2 powder (0.5g), 1% acetyl acetone, Polyethylene Glycol, Water
* Electrolyte
Mixture of KI and I in ethylene glycole
* Dye
Blueberries, pomegranate, Kimchi liquid
* Counter electrode
Carbon materials (using pencil, candle)
Experiment (TiO2paste)
a. Put 0.5g TiO2 powder into the mortar
b. Add 210ml acetyl acetone
c. Grind the powder gently (slow, more than 15min) until it looks quite
sticky
d. Add 2ml water for 2 or 3 times
e. Add 0.12g polyethylene oxide and grind (not to aerate, more than
15min)
Experiment (deposition)
Experiment (deposition)
Experiment
Experiment
Experiment
* Place electrodes
together
* Hold with paper
binders
* Fill electrolyte
* Capillary effect, filling
holes inside
Natural Dyes
hybrid sp
orbitals from
carbon atoms form
bond
pz and py
orbitals can
overlap to form
bonds, creating
triple bonds
Natural Dye
Absorbance
Photosynthesis
Chloroplasts in plants
absorb light and use
excited electrons in a
process to create
chemically stored
energy
Anthocyanins absorb
in 530-560nm range
Chlorophyll absorbs
over larger range
Efficiency of ipomoea leaf extract fluid is higher than efficiency of spinach extract fluid
Absorption intensity is higher
Absorption wavelength range is broader
Better interaction between TiO2 nanoparticles and the chlorophyll in ipomoea leaf DSSCs
better charge-transfer
Area[sqcm]
1
1
1.21
1.32
1.69
Pm[W]
1.362E-05
3.922E-06
5.747E-06
1.516E-05
5.661E-05
Eff[%]
0.014
0.004
0.005
0.011
0.033
FF[%]
43.477
41.616
41.780
51.425
53.065
Dye
blueberry
blackberry
blackbery
blueberry
blackberry
Dye comparison
TiO2
student
student
student
student
TA
48.000
0.000003
47.000
0.000002
46.000
0.000001
45.000
44.000
0
blackberry
FF[%]
I-V # 1_1
6.00E-05
Isc = 5.59E-5 A
Rsh ~ 1.67E5 ohm*cm2
Pm = 1.36E-5
Vm = 0.358 V
Im = 3.8E-5 A
Rch = 9421 ohm
5.00E-05
blueberry
normalized Eff[%]
Power 1_1
0.000016
0.000014
4.00E-05
0.000012
3.00E-05
0.00001
0.000008
2.00E-05
0.000006
A = 1 cm^2
Dye: blueberry
Prepared by: Student
1.00E-05
0.000004
0.000002
Voc = 0.56V
Rs = 3333 ohm*cm2
0.00E+00
0
0.1
0.2
0.3
0.4
0.5
0.6
-0.2
0.2
0.4
0.6
0.8
Eff[%] vs A[cm2]
60
0.000006
50
0.000005
40
0.000004
30
0.000003
20
0.000002
10
0.000001
0.04
0.035
0.03
0.025
0.02
0.015
0.01
0.005
0
0.95
0
1
1.15
1.35
1.55
1.75
1.21
FF[%]
1.32
normalized Eff[%]
1.69
Pm[W]
1.81E-05
1.9E-05
2.88E-05
3.15E-05
5.42E-05
0.000115
0.000121
Eff[%]
0.036246
0.035099
0.03556
0.038836
0.041033
0.045264
0.047575
FF[%]
49.08639
50.13606
35.30068
50.57554
52.11437
29.97646
47.94563
Dye
blueberry
blueberry
blueberry
blueberry
blueberry
blueberry
blueberry
TiO2
student
student
student
student
TA
student
student
I-V 2_2_13
1.40E-04 Isc = 1.18E-4 A
Rsh ~ 2.7E5 ohm*cm2
1.20E-04
1.00E-04
BH0520_2_TA
Power 2_2_13
Pmax = 3.14E-5 W
Im = 8.76 E-5 A
V = 0.35 V
Rch = 3995 ohm
0.000035
0.00003
0.000025
8.00E-05
0.00002
6.00E-05
0.000015
4.00E-05
0.00001
A = 0.81 cm^2
Dye: blueberry
Prepared by: Student
2.00E-05
0.00E+00
0
0.1
0.2
0.000005
Voc = 0.52 V
Rs = 810 ohm*cm2
0.3
0.4
0.5
0
0.6
-0.2
0.2
0.4
0.6
0.8
Eff[%] vs A[cm2]
0.05
0.048
0.046
0.044
60
0.000014
50
0.000012
0.00001
40
0.000008
0.042
30
0.04
0.000006
0.038
20
0.000004
0.036
0.034
10
0.032
0.03
0.000002
0
0.5
0.5
1.5
2.5
0.54
0.81
0.81
1.32
2.55
3
FF[%]
normalized Eff[%]
2.55
Pm[W]
1.03E-05
1.05E-05
3.27E-06
9.08E-06
5.51E-05
Eff[%]
0.010
0.010
0.009
0.010
0.055
FF[%]
48.672
42.552
35.282
41.815
49.837
Dye
blueberry
blueberry
blueberry
blueberry
blueberry
TiO2
student
student
student
student
TA
0.00006
52
50
48
46
44
42
40
38
36
0.00005
0.00004
0.00003
0.00002
0.00001
0
BH0520_3_1
I-V 3_1
BH0520_3_4 BH0520_3_TA
Pm[W]
6.00E-05
Isc = 5.06E-6A
Rsh ~ 3.33E5 ohm*cm2
Pmax = 1.03E-5 W
Im = 3.65 E-5 A
V = 0.28 V
Rch = 7671 ohm
5.00E-05
FF[%]
Power 3_1
0.000012
4.00E-05
0.00001
3.00E-05
0.000008
0.000006
2.00E-05
0.000004
A = 1 cm^2
Dye: blueberry
Prepared by: Student
1.00E-05
0.000002
Voc = 0.42 V
Rs = 2500 ohm*cm2
0.00E+00
0
0.1
0.2
0.3
0.4
0.5
-0.2
0.2
0.4
0.6
0.8
Eff[%] vs A[cm2]
0.06
60
0.000006
50
0.000005
40
0.000004
30
0.000003
20
0.000002
10
0.000001
0.05
0.04
0.03
0.02
0.01
0
0.36
0.9
0
0.3
0.5
0.7
0.9
1.1
1.3
FF[%]
normalized Eff[%]
1.1
Dye comparison
cell #
Area[sqcm]
BH0520_4_1
0.49
BH0520_4_2
0.72
BH0520_4_3
0.595
BH0520_4_4
0.56
BH0520_4_5
0.72
Pm[W]
1.97E-05
2.74E-05
1.16E-05
8.98E-06
7.52E-06
Eff[%]
0.040
0.038
0.020
0.016
0.010
FF[%]
46.043
50.106
44.902
45.416
47.628
Dye
blueberry
blueberry
Kimchi
Kimchi
Kimchi
TiO2
TA
student
student
student
student
0.0000025
48.500
48.000
47.500
47.000
46.500
46.000
45.500
45.000
44.500
0.000002
0.0000015
0.000001
0.0000005
I-V 4_2
6.00E-05
Isc = 5.69E-6A
Rsh ~ 24000 ohm*cm2
blueberry
Pmax = 2.74E-5 W
Im = 7.41 E-5 A
V = 0.369 V
Rch = 4979ohm
5.00E-05
kimchi juice
normalized Eff[%]
FF[%]
Power 4_2
4.00E-05
0.000014
3.00E-05
0.000012
2.00E-05
0.000008
0.00001
0.000006
1.00E-05
0.000004
A = 0.72 cm^2
Dye: blueberry
Prepared by: Student
0.00E+00
0
0.1
Voc = 0.456 V
Rs = 1200 ohm*cm2
0.2
0.3
0.4
0.000002
0
0.5
-0.2
0.2
0.4
0.6
0.8
Eff[%] vs A[cm2]
51
0.045
0.000003
50
0.04
0.035
48
0.03
47
0.025
46
0.02
45
0.000002
0.0000015
0.000001
44
0.015
0.0000005
43
0.01
42
0.005
0
0.48
0.0000025
49
0
0.49
0.56
0.595
FF[%]
0.53
0.58
0.63
0.68
0.73
0.78
0.72
normalized Eff[%]
0.72
Area[sqcm]
0.765
0.85
Pm[W]
4E-05
2.06E-05
Eff[%]
0.052
0.024
FF[%]
58.141
52.085
Dye
pomegranate
blueberry
60.000
TiO2
TA
student
58.000
56.000
54.000
I-V 5_5
Isc = 7.38E-5 A
8.00E-05
Rsh ~ 3.33E5 ohm*cm2
52.000
50.000
Pmax = 2.06E-5 W
Im = 5.52 E-5 A
V = 0.54 V
Rch = 9782 ohm
7.00E-05
6.00E-05
48.000
BH0520_5_1_31
FF[%]
0.0000045
0.000004
0.0000035
0.000003
0.0000025
0.000002
0.0000015
0.000001
0.0000005
0
BH0520_5_5
normalized Eff[%]
5.00E-05
4.00E-05
Power 5_5
3.00E-05
0.00003
2.00E-05
A = 0.85 cm^2
Dye: blueberry
Prepared by: Student
1.00E-05
0.00E+00
0
0.1
0.00002
Voc = 0.53 V
Rs = 1416 ohm*cm2
0.2
0.3
0.4
0.5
0.00001
0
0.6
-0.2
0.2
0.4
0.6
0.8
Pm[W]
0.000045
0.00004
0.000035
59.000
0.0000045
58.000
0.000004
57.000
0.0000035
56.000
0.00003
0.000003
55.000
0.0000025
0.000025
54.000
0.00002
53.000
0.000015
52.000
0.00001
51.000
0.000001
50.000
0.0000005
0.000005
0.000002
0.0000015
49.000
0
BH0520_5_1_31
BH0520_5_5
0
BH0520_5_1_31
FF[%]
BH0520_5_5
normalized Eff[%]
cell #
Area[sqcm]
BH0520_5_1_3
GOOD
0.765
0
BH0520_5_2
0.9
NGOOD
BH0520_5_3
0.855
Voc[V]
Isc[A]
Jsc[mA/sqcm]
Pm[W]
Vm[V]
Im[A]
Eff[%]
FF[%]
normalized Eff[%]
0.755
1.44E-04
0.188
3.96E-05
0.366
9999
0.015
8.06E-07
4.86E-05
0.001
0.057
1.45E-07
5.85E-08
0.362
0.008
1.08E-04
5.18E-02
36.455
3.96E-06
4.00E-07
7.04E-06
8.95E+02
6.84E-05
9999
8.043
8.06E-02
5.85E-09
Dye
pomegranate
Power
Efficiency
100.000
90.000
80.000
70.000
60.000
50.000
40.000
30.000
20.000
10.000
0.000
0.000045
9999
36.455
8.043
9.00E-02
8.00E-02
7.00E-02
6.00E-02
5.00E-02
4.00E-02
3.00E-02
2.00E-02
1.00E-02
0.00E+00
0.3832, 3.91E-05
0.00004
0.000035
0.00003
Power 5_2_33
0.000025
Power 5_1
0.00002
Power 5_3
0.000015
0.00001
0.000005
FF[%]
normalized Eff[%]
0
-0.2
0.2
0.4
0.6
0.8
Condition
cell #
Area[sqcm]
NGOOD BH0520_5_4
0.85
GOOD
BH0520_5_5
0.85
Voc[V]
0.005
0.535
Isc[A]
6.81E-05
7.39E-05
Jsc[mA/sqcm]
0.080
0.087
Pm[W]
1.64E-08
2.06E-05
Vm[V]
0.003
0.373
Im[A]
6.47E-06
5.52E-05
Eff[%]
1.93E-05
2.42E-02
FF[%]
5.234
52.085
normalized Eff[%]
1.64E-09
2.06E-06
Dye
blueberry
Power
0.000025
Efficiency
60.000
52.085
50.000
2.50E-06
0.00002
2.00E-06
40.000
1.50E-06
0.000015
30.000
Power 5_5
1.00E-06
20.000
10.000
5.00E-07
5.234
0.000
0.00E+00
BH0520_5_4
FF[%]
Power 5_4
0.00001
0.000005
BH0520_5_5
0
normalized Eff[%]
-0.2
0.2
0.4
0.6
0.8
Pm[W]
cell #
Area[sqcm]
BH0520_1_5
1.690
BH0520_2_3
1.320
BH0520_3_5
1.000
BH0520_4_1
0.490
BH0520_5_1
0.765
Average blueberry
cell #
BH0520_1_4
BH0520_2_2
BH0520_3_1
BH0520_4_2
BH0520_5_5
Average
Area[sqcm]
1.320
0.810
1.000
0.720
0.850
blueberry
TA cell
Pm[W]
5.66E-05
5.42E-05
5.51E-05
1.97E-05
4.00E-05
4.51E-05
Eff[%]
0.033
0.041
0.055
0.040
0.052
student cell
Pm[W]
Eff[%]
1.52E-05
0.011
3.15E-05
0.039
1.03E-05
0.010
2.74E-05
0.038
2.06E-05
0.024
2.10E-05
FF[%]
53.065
52.114
49.837
46.043
58.141
51.840
FF[%]
51.425
50.576
48.672
50.106
52.085
50.573
5.00E-05
4.50E-05
4.00E-05
3.50E-05
3.00E-05
2.50E-05
2.00E-05
1.50E-05
1.00E-05
5.00E-06
0.00E+00
Dye
blackberry
blueberry
blueberry
blueberry
pomegranate
Dye
blueberry
blueberry
blueberry
blueberry
blueberry
4.51E-05
2.10E-05
TA TiO2
FF[%]
52.000
51.840
51.500
51.000
50.573
50.500
50.000
49.500
TA TiO2
student TiO2
student TiO2
Isc[A]
9.453E-05
8.144E-05
4.671E-01
4.533E-05
Voc[V]
0.398
0.499
0.000
0.451
Pm[W]
4.50E-05
70.000
4.00E-05
4.00E-05
58.141
60.000
3.50E-05
50.000
3.00E-05
47.451
50.573
45.982
40.000
2.50E-05
2.10E-05
30.000
2.00E-05
1.50E-05
1.00E-05
FF[%]
47.451
50.573
58.141
45.982
9.38E-06
20.000
10.000
4.83E-06
5.00E-06
0.000
0.00E+00
blackberry
blueberry
pomegranate
Kimchi juice
blackberry
FF[%]
normalized Eff[%]
4.50E-06
4.00E-06
3.50E-06
3.00E-06
2.50E-06
2.00E-06
1.50E-06
1.00E-06
5.00E-07
0.00E+00
Isc[A]
1.600E-04
Voc[V]
0.600
1.472E-04
0.499
1.400E-04
0.500
1.200E-04
1.000E-04
0.467
0.451
pomegranate
Kimchi juice
0.398
0.400
9.453E-05
8.144E-05
8.000E-05
0.300
6.000E-05
4.533E-05
0.200
4.000E-05
0.100
2.000E-05
0.000E+00
blackberry
blueberry
pomegranate
Kimchi juice
0.000
blackberry
blueberry
dye
blackberry
blueberry
pomegranate
Kimchi juice
spectrum
300-600
300-650
300-620
n/a
peak
539
560
539
n/a
absorbancy
0.546
0.22
0.35
n/a
Reference: http://teachers.usd497.org/agleue/Gratzel_solar_cell%20assets/data%20and%20results%20and%20UV-Vis%20spectroscopy%20of%20the%20dyes.htm
Efficiency
3.14E-05
53
52
51
50
49
48
47
46
2.74E-05
3.00E-05
2.50E-05
2.06E-05
2.00E-05
1.50E-05
1.36E-05
1.03E-05
1.00E-05
5.00E-06
50.57
1_4
Area[cm2]
1
0.81
1
0.72
0.85
2_2
3_1
Pm[W]
1.36E-05
3.14E-5
1.03E-05
2.74E-05
2.06E-05
4_2
2_2
FF[%]
5_5
normalized Eff[%]
1.52E-06
3.15E-06
1.03E-06
2.74E-06
2.06E-06
50.106
48.672
1_4
0.00E+00
cell #
1_4
2_2
3_1
4_2
5_5
52.085
51.425
FF[%]
51.425
50.57
48.672
50.106
52.085
Rch[ohm]
9421
3995
7671
4979
9782
3_1
4_2
3.50E-06
3.00E-06
2.50E-06
2.00E-06
1.50E-06
1.00E-06
5.00E-07
0.00E+00
5_5
normalized Eff[%]
Rs[ohm*cm2] Rsh[ohm*cm2]
3333
1.67E+05
810
2.70E+05
2500
3.33E+05
1200
2.40E+05
1416
3.33E+05
Isc[A]
5.96E-05
1.18E-04
5.07E-05
1.05E-04
7.39E-05
Voc[V]
0.494
0.525
0.416
0.522
0.535
Dye
blueberry
cell #
1_4
2_2
3_1
4_2
5_5
Rsh[ohm*cm2]
Rs[ohm*cm2]
3500
3333
3.33E+05
3.50E+05
3.00E+05
3000
2500
2500
2.50E+05
2000
2.00E+05
1416
1500
1200
5.00E+04
0.00E+00
2_2
2.70E+05
2.40E+05
1.67E+05
1.50E+05
500
1_4
3.33E+05
1.00E+05
810
1000
Area[cm2]
1
0.81
1
0.72
0.85
3_1
4_2
5_5
1_4
Rch[ohm*cm2] avg
1851.80
2_2
3_1
Rs[ohm*cm2] avg
69708.68
4_2
rs
0.71
5_5
rsh
26.82
cell #
Area[cm2]
1_4
0.0001
2_2
0.81
0.00008
3_1
4_2
0.72
5_5
0.85
Dye
I [A]
blueberry
0.00012
0.00004
0.00002
0
0.1
0.2
0.3
V [V]
0.4
0.5
0.6
Reference: http://www.pveducation.org/
Indicates best fabrication results (fewer defects, better powder preparation etc)
By dye
Pomegranate has best performance
Pm = 4E-5 W, FF = 58%, Normalized efficiency = 4E-6%
Isc = 1.47E-5 A Voc = 0.47 V
Blueberry has moderate performance
By TiO2 powder
TA made TiO2 has better power performance than student made TiO2
Yet similar average FF ~ 50% -> FF reflects ideality of solar cell -> fabrication technique matters
Surfactants
Increasing Lifetime
References
B. Lee, D. B. Buchholz and R. P. H. Chang, An all carbon counter electrode for dye sensitized solar cells. Energy Environ. Sci., 2012, 5, 69416952.
H. Chang, H.M. Wu, T.L. Chen, K.D. Huang, C.S. Jwo, Y.J. Lo, Dye-sensitized solar cell using natural dyes extracted from spinach and ipomoea. Journal of
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