Beruflich Dokumente
Kultur Dokumente
2010
Imperial Sugar
Port Wentworth, Georgia
2/27/2008
CTA Acoustics
Corbin, Kentucky
2/20/2003
West Pharmaceuticals
Kinston, NC
1/29/2003
What is Required?
Ignition Source
Dispersion
(Suspension)
Confinement
Oxygen
Kst The deflagration index of a dust cloud. Kst = (dp/dt)max(V 0.333) bar-m/sec
(per ASTME 1226 testing). Higher Kst values indicate a higher rate of combustion.
Friction
Spark
Chemical Action
Hot Work
Burner Flame
Electricity
Static Electricity
Overheating
Hot Surfaces
Hot Embers
MIE Milli-Joules
400-700 mJ
1.7 mJ
Polylclar 10
4 mJ
PVP K-90
14 mJ
PVP K-30
25 mJ
Gantrez AN-169
1.2 mJ
Deflagration
When an Explosible Material is reduced in size it becomes more dangerous. The smaller the
particle size, the more Surface Area Available for ignition.
The smaller the particles the greater the chance for an explosion to occur.
This is the value of weight of material per Unit Area that will, in a Cloud
form/propogate a Deflagration/Explosion.
This value is Highly Important and key to Determining the Actual RISK in an
Explosive Environment.
Acrylidone LM
60 g/m3
Polyclar 10
40 g/m3
PVP K-90
65 g/m3
PVP K-30
65 g/m3
Gantrez AN-169
60 g/m3
Kst
Kst
Dust
Explosion
Class
ST 0
ST 1
ST 2
ST 3
Kst
Characteristic
(Bar.m/sec)
0
No Explosion
Strong
Explosion
Very Strong
Explosion
Powder
Class
Kst Value
Sugar
ST-1
172
Acrylidone LM
ST-2
278
Polyclar 10
ST-2
210
PVP K90
ST-1
138
PVP K30
ST-1
179
Gantrez AN-169
ST-2
249
Primary Explosions
Primary Explosion A primary explosion can develop pressures that will approach 10 times the initial
pressure of the system. For a primary explosion to occur a dust/powder cloud with the combustible
materials concentration above the MEC must exist, the oxygen concentration must be above the LOC, an
ignition source of sufficient energy must be present and there needs to be an element of confinement.
Prevention is normally attained through preventing the formation of the dust clouds with a dust
concentration above the MEC, by keeping the oxygen concentration below the LOC, by controlling all
ignition sources (electrical, electrostatic, thermal, mechanical) and by defining envelopes for safe
operating conditions as it pertains to self heating. Mitigations normally evaluated include containment,
suppression, and explosion venting.
Operate the Equipment below the Minimum Explosible Concentration (MEC) Powder
Conveyance, Dust Collectors, Drying Chambers, Blenders, etc.
Control Ignition Sources Use only Rated Equipment suitable for Combustible Dust
Atmospheres.
Control Oxygen Level below the LOC (Limiting Oxyen Concentration) Processes operated
under Inert Atmospheres.
Explosion Venting to Safe Location
Suppression Systems & Containment
Acrylidone LM
12%
Polylclar 10
13%
PVP K-30
12%
Gantrez AN-169
9%
Propogating Explosions
Secondary Explosions
Secondary Explosion Secondary explosions are the most severe and destructive of the dust/powder
explosion types. They occur when the powder/dust laying on the floor, beams, building supports, and
equipment are all jarred loose and thrown into one large dust cloud and ignited from the fireball from the
Primary and/or Propagating Explosion. Normally it is the primary explosion occurring in a facility where
housekeeping is below standards that causes the secondary dust cloud to form and has the energy
required to ignite it. Prevention is normally attained by preventing the primary explosion and by
preventing the buildup or accumulation of combustible material. There is very little that could be done to
mitigate the Secondary Dust Explosion. It is imperative that a strict housekeeping policy be followed to
ensure that accumulations and buildups are kept to a minimum.
Housekeeping
Appendix A of NFPA 654 points out that a dust layer 1/32 inch (0.8 mm) thick on the floor
would, when uniformly suspended create a dust hazard concentration of .35 oz/ft3 (350
g/m3) in a room 10ft high.
As a reference this is about the thickness of the lead on a mechanical pencil, or half the
thickness of a dime.
Annex D of NFPA 654 indicates that immediate cleaning is warranted whenever a dust layer
or 1/32 (.8 mm) thickness accumulates over a surface area of at least 5% of the floor of the
facility in any given room. The 5% factor should not be used if the floor area exceeds 20,000
ft2, in which case a 100 ft2 layer of dust is the upper limit.
Accumulations on overhead beams, joists, ducts, tops of equipment, and other surfaces
should be included when determining the dust coverage area. Even vertical surfaces should
be included when determining the dust coverage area.
Housekeeping
An alternative method for considering the Acceptable thickness of dust accumulations from NFPA
654 (6.2.3.2) for powders with bulk densities less than 75 lb/ft3 is as follows:
Product
Equivalent Thickness
3.2 mm
2 mm
1.5 mm
1.6 mm
2.1 mm
Housekeeping
Each Department (Area) within the plant shall develop a documented Housekeeping Procedure which
must include the following elements (Example Housekeeping Checklists included in Appendix A):
Guidelines as to when Equipment should be shut down for repairs concerning powder/dust
including:
A weekly cleaning schedule (at minimum) unless determined & justified as to an adjusted
frequency.
Weekly Cleaning schedule must include assignments as to which job function (positions) are responsible for
which areas within the process.
Weekly cleaning schedule must include Operator Sign-off.
Weekly cleaning documentation shall be maintained by the Area for a period of 6 months.
Acceptable methods of Cleaning must be identified in the cleaning procedure as well as any additional
precautions that must be taken.
Vacuuming (Fixed Pipe House-Vacuum Systems & properly rated portable cleaners are acceptable)
Dry Sweeping & Bagging of Material
Washing the affected Area.
Housekeeping
It is acceptable to limit the extent of dust migration & size of the room that must be cleaned.
NFPA 654 permits the use of physical barriers to limit dust migration in order to minimize the
extent of the housekeeping zone.
Additional Information
ISP Corporate SHP-511 -- Major Hazard Analysis Guidelines for Systems Processing
Combustible Dusts & Powders
http://iportal/departments/Environmental%20Health%20and%20Safet/pages/polici
es.aspx
Additional Information
Additional Information