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There are many methods available to determine the water saturation; these include
petrophysical models (log evaluation), the saturationheight function from capillary
pressure data and determining the water saturation directly from the core.
The first class of models (Vsh models) assumes that the extra
conductivity of the shale is directly related to the volume of the shale
(Simandoux, 1963; Poupon and Leveaux, 1971). These models have
many disadvantages; the major one is that there is no common
indicator of the volume of shale (Vsh) (Ipek, 2002). Furthermore, they
ignore the role of electrical conductivity of clay minerals, which
depends on the type of clay. It has been shown that the Vsh models fail
in many cases to calculate representative values of water saturation
fromwireline logs (Waxman and Smits, 1968; Ipek, 2002; Rezaee and
Lemon, 1996; Al-Ruwaili and Al-Waheed, 2004). The second type of
shale models is called cation exchange capacity (CEC) models. These
models consider the electrical conductivity of clay minerals
(Worthington, 1985). They are based on the CEC which represents
the ability of clay to conduct electricity, such as the Waxman and
Smits and dual water models (Clavier et al., 1984). However, input
parameters for these models are not always available and the
laboratory processes to obtain them can be very time consuming
and sometimes give ambiguous results (Worthington, 1985; Rezaee
and Lemon, 1996; Ipek, 2002; Shokir, 2004).