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Gold is readily dissolved by cyanide. Most of the world's gold supply is found in low concentrations in nature and must be dissolved from ore to be acquired. Tailings from the old Meda ponds were combined with water to form a slurry that was pumped to a processing plant where more cyanide was added if needed. Gold extraction in The Aurul plant was approximately 700 mg / liter of slurry.
Gold is readily dissolved by cyanide. Most of the world's gold supply is found in low concentrations in nature and must be dissolved from ore to be acquired. Tailings from the old Meda ponds were combined with water to form a slurry that was pumped to a processing plant where more cyanide was added if needed. Gold extraction in The Aurul plant was approximately 700 mg / liter of slurry.
Gold is readily dissolved by cyanide. Most of the world's gold supply is found in low concentrations in nature and must be dissolved from ore to be acquired. Tailings from the old Meda ponds were combined with water to form a slurry that was pumped to a processing plant where more cyanide was added if needed. Gold extraction in The Aurul plant was approximately 700 mg / liter of slurry.
ore Vat leaching involves mixing extracted ore with a CN solution in large vats. Heap leaching involves piling ore into large heaps and then spraying a CN solution on the heap and allowing the CN solution to trickle through, stripping the gold from the ore.
Gold is readily dissolved by cyanide.
Most the worlds gold supply is found in low concentrations in nature and must be dissolved from ore to be acquired. Less than 10 grams/ton of ore excavated. NaCN is typically used as a solvent and diluted to a concentration of 0.015 0.035% NaCN. Gold extraction in the Aurul plant was approximately 700 mg/liter of slurry.
Most gold mines are often found near water
sources since water is used to dilute the NaCN to acceptable levels for mining. Having a readily available supply of water cuts down on transportation and other costs associated with water needs. In the case of Baia Mare, the tailings from the old Meda ponds, used for gold extraction are combined with water to form a slurry that was pumped to a processing plant where more CN is added if needed. Then the slurry is pumped the rest of the 6.5 km to the new Aurul gold mining site.
The processing plant was in charge of receiving the slurry
from the chronically leaking Meda ponds, assessing the level of cyanide in the slurry and adding more if needed. Cyanide levels were monitored and if needed brought to an acceptable range of 0.015 0.035% NaCN within the slurry and then pumped into the new tailing dams. Extraction of gold as well as other precious metals were done at this site and remaining tailings were then pumped to the dams. To maximize gold extraction, tailings from the new dam were pumped back to the plant for further extraction of extremely low levels of gold and were then pumped back to the tailing dam.
Tailing dams hold CN treated ore wastes from
which gold has been removed. The Aurul tailings contained concentrations of 400 mg/liter of CN and concentrations of free CN of 120 mg/liter. Tailings typically contain 0.60 g/ton of recoverable gold. The Aurul tailings also contained high concentrations of heavy metals such as: iron, cooper, arsenic, cadmium, lead, nickel, and manganese.
The new Aurul tailing dams were built to replace the
chronically leaking Meda ponds located near Baia Mare. The dam covered 93 hectares and was 20 meters high. The dam was built to take advantage of the sloping hills in the area. Lining the dam was a plastic liner that afforded 0% discharge into the surrounding area. The dam wall was constructed on top of a starter dam, with the new dam wall added as more slurry was pumped in. The idea was to have the tailings form the wall as more and more slurry was deposited into the dam. Hydrocyclones were added to assist in lining the dam wall with the tailings.
The dam wall was constructed so that the dam
could deal with storm run-off up to 118 mm. A decanting well was fitted in the center of the dam so that the slurry could be re-circulated back to the processing plant. Drains were also created as additional protection against seepage into the environment.
Large businesses often find it beneficial to found
operations in areas where governmental regulations may not be up to par. Many environmental organizations have pointed this out as a major contribution to the cyanide spill in Baia Mare. The Serbian Minister of Environment announced that he will be suing the company responsible and asks for an international trial to be held.
The
Baia Mare area received approximately
120 mm of snowfall and 40 mm of rain from mid-December until the end of January. The dam was only able to accommodate storm run-off up to 118 mm. On January 30, 2000, due to the precipitation in the area the dam crest was flooded and over 25 meters of the dam wall was washed away.
Marine
Life Plant Life Water compositional change
Estimated 80% of all fish in
the Tisza River died. Thousands of tons of fish died. Some fish were found to contain 2.6 mg of cyanide per kilogram of weight. Extensive damage done to the rivers ecosystems and its fauna, affecting birds, and carnivores. The Cyanide plume that traveled through the rivers was 100 times more concentrated than the limit value for drinking water in the region. 30%-60% plankton killed
The initial affect of the
high Cyanide concentrations on the ecosystem was devastating, however due to Cyanides short lived presence in the water the environment was able to begin recovery.
Heavy metals persist in
the environment and bioaccumulate in living organisms.
Since the incident the
heavy metals have accumulated in the sediments are collecting 6-10km downstream of Baia Mare. They will continue to be washed downstream and spread throughout the river system.
The rivers that fed or were
fed into the Tisza river, have very high heavy metal concentrations, and the concentration is increasing over time. The plume traveled down the length of the river, into the Danube river and then into the Black Sea by which time it had significantly diluted . The waters pH would have changed from the chemical reactions taking place within it.
Cyanide comes in many forms
The most lethal being that of Hydrogen cyanide , HCN, which is lethal to humans at 1.1 mg/kg in the blood. In the plume that sweeped through the river, Cyanide most likely formed complexes with heavy metals associated with it. Even though free floating Cyanide is readily degradable when it forms into a complex ,dilution and degradation become complicated. Complexes: Ferrous ferrocyanide (Fe[FeCN6]) and ferric ferrocyanide (Fe4[FeCN6]3). And Copper ferrocyanide (Cu2[Fe(CN)6])
Cyanide
Time in the environment
Reactions in the water, and wildlife Forms of cyanide.
The
in nature
behavior of heavy metals in nature
What is difficult about removing these contaminants?
Where does it collect?
The Cyanide plume was measured for 2000km from
the point of origin to the Danube delta. Free Cyanide is biodegradable, and as it continued downstream it was easily diluted, this made the ongoing effects of the plume short lived.
The oxidation of cyanide, can
produce cyanate which is less toxic, and readily hydrolyzes to ammonia and carbon dioxide. Cyanide also reacts to Sulfur which is found in the ore and also in the wastewater from the tailings dam. Cyanide and sulfur react to produce thiocyanate, which degrades into cyanate and sulfuric acid. The sulfuric acid would create Hydronium ions which would allow for the further degradation of the cyanate. Hydrogen cyanide gas which has the ability to form during these reactions does not occur, because hydrogen cyanide ionizes in water. Forming CN- anions which contribute to the reaction
The heavy metals that were
included in the plume consisted of copper, iron, zinc, and lead. The high levels of these heavy metals discharged into the rivers, would cause long term affects in the ecosystem, because they are not readily degradable. This discharge creates a chronic pollution whose damage is harder to estimate. These heavy metals mix with the sediments at the water bed, are bioaccumulated from plant and animal life and enter into the ecosystems food chain.
If the wastewater had any
treatment beforehand, the damage would have been lessened. Normally heavy metals can be removed from wastewater through flocculation, but this is in a controlled setting. The heavy metals will continue to be pushed and accumulated throughout the entire region by the physical forces of the water current. New exfilitration and tailings dams were built to collect these moving heavy metals.
The heavy metal contaminants are pumped into an exfiltration
pond where the heavy metals settle and water is drained back into the main pond.
Cyanide
breakdown quickly in sunlight
Into less toxic but longer-lasting forms, such as
cyanate and cyanogen
Free
cyanide breakdown slowly when water
is covered by ice
Protected from direct sun
Sodium hypochlorite was poured into the spill in an
attempt to neutralize the cyanide. Turns cyanide into a less toxic compound The remaining water in the containment pool was diverted into a nearby tailing dam. Sediments from other tailing deposits Were used to seal the breach Reinforce other parts of the dam
A limited outflow of 40-50 liters per second continued
and was treated with sodium hypochlorite until February 2. The cyanide was biologically degraded and diluted as it moved along the length of the river.
Water samples from surface water were taken by
three teams from the 21 sampling stations. Typically, the water sampling locations were identical with those for the sediment sampling. The UN sampling took place about three weeks after the plume had passed
Could not validate any of the results obtained by the
Romanian, Hungarian or Yugoslavian experts.
The UNEP Balkans Task Force took water samples
from the river Danube in FRY on 15-17 February Between Pancevo and the Iron Gate o Cyanide concentrations were from 0.008 mg/L to 0.117 mg/L UN team sampled surface water at the Tisza river Free cyanide concentrations of 0.014 mg/L Within an acceptable range The UN Team recorded the plume of cyanide contamination in the Danube Delta Measurements were taken between 26 and 28 of February gave a maximum concentration of 0.058 mg/L
UNEP joined with ICOLD to produce two Technical Bulletins for laying down design requirements and providing lessons from past incidents as a guide to designers. International Council for Metals and the Environment, a multi-stakeholder process was launched to develop a management code for cyanide
Short term regulations :
Each site will be inspected by suitably qualified personnel and
a safety/risk assessment made Hydro-meteorological data for each site will be re-evaluated in order to ensure that tailings ponds and lagoons are designed to cope with extreme weather events Assessments will be made of the structural capacity of the tailings dams and impoundments to withstand extreme precipitation and snowmelt events Immediate steps to improve safety will be carried out where these are deemed necessary Operational and accident/emergency procedures will be reviewed and improved where necessary at both a facility and local administration level All sites, will immediately be placed under regular surveillance Abandoned sites Daily inspection and tests in times of adverse weather conditions
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Kovac, C ,Cyanide spill threatens health in Hungary. 2000 BMJ 320,7234
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