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Salters AS Chemistry
Summer Revision
By M Thomson
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Minerals to Elements
Polymer Revolution
Atmosphere
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a. Concentration Calculations
Can you answer these questions
If you dissolve 1.00g of NaOH into 250cm3 of
solution, what is its molarity?
How many moles are there in 15cm3 of 0.2M
solution?
1g = 1/40 = 0.025 moles in 250 = 0.1 Moles in 1000 ie 0.1M
a. Ionic Equations
Can you answer these questions
Write ionic equations for Silver with halide ions
Acid with alkali
Ag+(aq) + Cl- (aq) AgCl(s)
b. Titrations
Can you answer these questions
Can you give the details for doing a titration
If 25cm3 of sodium hydroxide are neutralised by
15cm3 of 0.15M sulphuric Acid
M
M
O
0.00225
Na2SO4
+ 2H2O
Fe2+
Cr
Cu
e. Shapes of Molecules
Can you answer these questions
Draw a dot cross diagram for NH3
Describe the shape and bond angle of the molecule
H
Xo
xo
xo
N
xx
g. Intermolecular Bonds
Can you answer these questions
What sort of intermolecular bonds are there between
bromine molecules
What sort of intermolecular bonds occur between HBr
molecules
Br2 Instantaneous dipole induced dipole bonds
HBr Permanent dipole bonds
h. Sodium Chloride
Can you answer these questions
Draw a 3 dimensional structure of sodium chloride
Na+
Na+ Cl-
Cl-
Na+
Na+Cl-
Cl-
Na+ ClNa+
Cl-
Na+
Na+
Na+
Na+ Cl-
Cl- Cl-
Na+Cl- Cl-Na+
Cl-
Na+
ClNa+
i. Oxidation States
Can you answer these questions
What is the definition of Oxidation State
What is the oxidation state of Iodine in KIO3
The number of electrons lost by an atom when forming a
compound or ion
NB not 5+
+4 -2
Oxidised Reduced
+1 -2
X5
X2
p
d
l. Ionisation Enthalpies
Can you answer these questions
Write en expression for the 1st and 2nd ionisation enthalpies of Mg
Explain why the 2ns IE for Mg is higher than the 1st and the 3rd is
much higher
Mg(g) Mg+(g) + eMg+(g) Mg2+(g) + eSuccessive IEs are always larger as you are removing an electron
from an increasingly positively charged ion
The 3rd IE of Mg is much higher as you are breaking into a new
shell which is closer to the nucleus and held more strongly
m. Properties of Halogens
Can you answer these questions
Can you describe the appearance of Cl, Br and I
What happens to their B.Ps
How does their solubility in water and hexane change
Yellow gas, red/brown liquid, black solid
Boiling points increase down group
Solubility decreases down group..more soluble in hexane
n. Manufacturing Chemicals
Compare the following Industrial reactions
The Haber Process making Ammonia
Fermentation of sugar to make alcohol
Haber Process Continuous needs high temperatures
Fermentation: Batch process, works at 40oC
2KCl + Br2
KBr + I2
No reaction
As atoms get larger, they attract electrons less strongly and form
weaker covalent bonds
p. Silver Halides
Can you answer these questions
Can you write equations for sodium chloride,
bromide and iodide reacting with silver nitrate
Can you write them as ionic equations
Can you give the observations for each reaction
AgNO3(aq) + NaX(aq) AgX(s) + NaNO3(aq)
Ag+(aq) + X-(aq) AgX(s)
AgCl White precipitate, AgBr cream , AgI pale yellow
u. Making a Halogenoalkane
Can you answer these questions
How can you make 1-chloropropane from
propan-1-ol?
React it with concentrated HCl
w. Halogenoalkane properties
What are the trends in the properties of
Chlorobutane, bromobutane and Iodobutane
Boiling points
Formation of radicals with UV light
Reaction with water, ammonia and hydroxide
Boiling points increase down group
They form radicals more easily down group (weaker bond)
They get more reactive down group
x. Nucleophilic Substitution
Can you answer these questions
What is meant by hydrolysis?
What is meant by substitution?
What is a nucleophile, give an example
What is a carbocation, draw the structure of one
Splitting of a molecule with water
When one group swaps with another
Nucleus lover something with some negative charge
A Carbon atom with 3 bonds and a positive charge
y. Nucleophilic Substitution
Can you answer these questions
Write a mechanism for the reaction between
sodium hydroxide and bromomethane
What is the product if ammonia is used instead?
H
Forms an amine -NH2
H
HO:-
C + Br H
z. Reactivity of Halogenoalkanes
Can you answer these questions
Which is more polar C-Cl C-Br or C-I
C-Cl
105o
109o
109o
SO2
Cl2
Reduction
Oxidation
Diamond
Graphite
Silicon Dioxide
Na+
Cl-
Buchner Funnel
Base..accepts
Proton
AcidDonates
Proton
Leave somewhere
warm to rise
ENJOY!
Neutralisation
Precipitation
CuSO4 + Fe Cu + FeSO4
Redox
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Elements from the Sea
Polymer Revolution
Atmosphere
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a. Water
Can you answer these questions
Can you show the bonding and shape of water
Can you show the attraction between water molecules
H
H +
O
O -
H +
H
H
O
H
b. Intermolecular Attractions
What forms of attraction are there between
molecules of
Bromine
HBr
H2O
Hydrogen Bonding
c. Dissolving Polymers
Can you answer these questions
Dissolving polymers have OH groups, why does
this make them soluble?
If there are too many OH groups the polymer
becomes insoluble why is this?
OH Groups can hydrogen bond with water
If there are too many OH groups, they will hydrogen
bond with each other making the polymer insoluble
d. Naming Alkenes
Can you answer these questions
What is the name of this alkene
H
H H
CH3
HCCC=CCH
H H
H H
Hex-3-ene
Alcohol
C6H5OH
Phenol
CH3CHO
Aldehyde
CH3COCH3
CH3COOH
Ketone
Carboxylic Acid
f. Types of Alcohol
Can you answer these questions
Draw 3 different types of alcohol with the formula
C4H10O
O-H
O-H
O-H
Primary
Secondary
Tertiary
No stopper
h. Elimination Reaction
Can you answer these questions
Write an equation for the reaction of butan-2-ol
with concentrated sulphuric acid
What type of reaction is this
Why can two different products form
CH3CH2CH(OH)CH3 CH3CH2CH=CH2 + H2O
Elimination
Can form but-1-ene or but-2-ene
i. Addition Polymerisation
Can you answer these questions
What are the product(s) of additional Polymerisation
What type of monomer produced an addition polymer
Addition polymerisation produces only a polymer,, no coproduct
Addition polymers come from alkene monomers
CH3
C=C
Cl
CH3
Cl
j. Reactions of Alkenes
Write equations for the reaction of ethene with
Bromine
HBr
k. Alcohol Reactions
How will ethanol and phenol behave when added to
Acidified Potassium Dichromate(VI) Ethanol oxidises
Concentrated sulphuric acid
Ethanol dehydrates
H-Br -
l. Electrophilic Addition
Write a mechanism for the reaction between Bromine and Ethene
What type of mechanism is this?
H
C=C
H
+
C C
H
Br
Br
Br
Electrophilic Addition
Carbocation
Br-
Br
H C
H
H
C
Br
m. Alkene structures
Can you answer these questions
Can you draw 5 structures with the formula C4H8
But-1-ene
Methylpropene Cyclobutane
Hydrogen Bonding
NH3
Polar
Polar
CH4
Non Polar
Stronger higher MP
Less dense
Elastic
Thermosetting
Much Stronger
end. Crystallinity
Can you answer these questions
What is meant by a crystalline area of a polymer
What effect does crystallinity have on properties
A crystalline area is where the chains are regularly packed,
There is stronger attraction here
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Questions on Atmosphere
b. Rates of Reaction
Can you answer these questions
What has to happen for a chemical reaction to take
place?
State 4 things that can sped up a chemical reaction
Molecules must collide with sufficient energy
Increase surface area, temperature, concentration or catalyst
c. Energy Profiles
Can you answer these questions
Draw an energy profile for an endothermic and an
exothermic reaction.
On the profiles, label the activation energy
E
e. Catalysts
Can you answer these questions
How does a catalyst speed up a chemical reaction?
Show this on the reaction profile
By Providing a reaction pathway needing less activation energy
E
f. Intermediates in Catalysis
Can you explain and illustrate the role of intermediated in
Homogeneous catalysis
In the Reaction A+ B products if the Catalyst is C then
The reaction is A _ C AC then AC +_ B Product + C
AC is the intermediate, it is the small dip in the catalised reaction
profile
Intermediate
g. Dynamic Equilibrium
If a reaction is in Dynamic Equilibium
What is meant by the term dynamic?
What is meant by the term equilibrium?
Dynamic, means continually going on
Equilibrium means the reaction is going forwards and
backwards at the same rate so there is no net change in
concentration
CO2 (aq) +
H2O (l)
Neon
j. ppm
Can you answer these questions
Carbon dioxide makes up 0.037% of the
atmosphere, what is this in Parts per million?
To turn % to ppm, multiply by 10000
k. Ozone
O
O
Destruction O3 O* +
O* + O2 O3
O2
O* + O* O2
p. CFCs
Can you answer these questions
Give 3 uses of CFCs
What 2 properties made them so useful?
Aerosols, fridges and solvents
p.Replacing CFCs
CFCs can be replaced by HCFCs, HFCs or alkanes
Explain what these three compounds are
Give an advantage of each one
Give a disadvantage of each one
Hydrochloroflurocarbon Hydrofluorocarbon
Hydrocarbon
Expensive
Flammable
q. Protection by Ozone
Can you answer these questions
How does the ozone layer protect us?
By absorbing UV light (in the process ozone is
destroyed, but more is formed)
ClO + O2
ClO + O Cl* + O2
s. Quantised Energy
Can you answer these questions
What is a quantum of energy?
What forms of energy in a molecule are quantised?
A quantum, is the smallest allowed amount of energy a particle can have
Electron energy levels, vibrations and rotations are all quantised
E = hf
v. Homogeneous Catalysis
Can you answer these questions
What two steps are needed for a homogeneous
catalyst to speed up a chemical reaction?
Catalyst joins to chemical forming an intermediate
Catalyst breaks off so it can react again
v. Greenhouse Effect
Can you answer these questions
Explain the causes of the greenhouse effect
What are some of the consequences of the
greenhouse effect?
Visible and ultra violet light passes through the atmosphere
and is re-emitted as infra red radiation.Carbon dioxide
molecules absorb infra red radiation and prevent it
escaping back into space.
Global warming, rise in sea levels, climate change
end. Radicals
Can you answer these questions
How are radicals formed?
Homolytic Fission
end. Halogenoalkanes
Can you answer these questions
Draw two structures of halogenoalkanes with 3
carbons and a bromine atom
CH3CH2CH2Br
CH3CHBrCH3
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