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The Dronfield School

Salters AS Chemistry
Summer Revision
By M Thomson

The first step to knowledge..


Is knowing what you know
..and what you dont know

Classifying your Knowledge..


Things you can do

Things you can do


already and dont
need much more
help with

Things you could do

Things you cant


do

understand but need


to learn a little more

Even with the


answer in front you
you, you cant do it

You now know


Thingseverything!!
you

Even the longest journey.

..must start with a single step

..we have about 50 steps

Navigation Page
Select the Unit you wish to study
Minerals to Elements
Polymer Revolution
Atmosphere
End Slides

Questions on Elements from the Sea

a. Concentration Calculations
Can you answer these questions
If you dissolve 1.00g of NaOH into 250cm3 of
solution, what is its molarity?
How many moles are there in 15cm3 of 0.2M
solution?
1g = 1/40 = 0.025 moles in 250 = 0.1 Moles in 1000 ie 0.1M

No of moles = volume x molarity / 1000 = 15 x 0.2/1000 = 0.003

a. Ionic Equations
Can you answer these questions
Write ionic equations for Silver with halide ions
Acid with alkali
Ag+(aq) + Cl- (aq) AgCl(s)

H+(aq)+ OH-(aq) H2O(l)

b. Titrations
Can you answer these questions
Can you give the details for doing a titration
If 25cm3 of sodium hydroxide are neutralised by
15cm3 of 0.15M sulphuric Acid
M

Moles of H2SO4 = 15 x 0.15/1000 = 0.00225

Equation H2SO4 + 2NaOH

M
O

0.00225

Na2SO4

+ 2H2O

0.0045 moles of NaOH in 25cm3

Molarity of NaOH = 0.0045 x 1000/25 = 0.18M (Sig Fig)

c. Electron Sub levels


Can you answer these questions
What are the sublevels found in each electron
shell, how many electrons can each sub level hold?
S holds 2, p holds 6, d holds 10
Order 1s 2s 2p 3s 3p 4s 3d 4p
Eg Br is 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p5
Dont forget the exceptions
Cu 4s1 3d10 Cr 4s1 3d5 and remove 4s before 3d

d. Writing Electron Configurations


Can you answer these questions
Can you write down the electron configurations of
Fe

1s2 2s2 2p6 3s2 3p6 4s2 3d6

Fe2+

1s2 2s2 2p6 3s2 3p6 4s0 3d6

Cr

1s2 2s2 2p6 3s2 3p6 4s1 3d5

Cu

1s2 2s2 2p6 3s2 3p6 4s1 3d10

e. Shapes of Molecules
Can you answer these questions
Draw a dot cross diagram for NH3
Describe the shape and bond angle of the molecule
H
Xo

xo

xo

N
xx

Shape Trigonal pyramid


Bond angle 107o

f. Polar Covalent Bonds


Can you answer these questions
What causes a bond to be permanently polar
Which is more polar C-Cl C-Br or C-I
Difference between electronegativity between the
atoms, one nucleus attracts the electron pair more
than the other
The C-Cl bond is the most polar

g. Intermolecular Bonds
Can you answer these questions
What sort of intermolecular bonds are there between
bromine molecules
What sort of intermolecular bonds occur between HBr
molecules
Br2 Instantaneous dipole induced dipole bonds
HBr Permanent dipole bonds

h. Sodium Chloride
Can you answer these questions
Draw a 3 dimensional structure of sodium chloride
Na+

Na+ Cl-

Cl-

Na+

Na+Cl-

Cl-

Na+ ClNa+

Cl-

Na+

Na+

Na+

Na+ Cl-

Cl- Cl-

Na+Cl- Cl-Na+

Cl-

Na+
ClNa+

i. Oxidation States
Can you answer these questions
What is the definition of Oxidation State
What is the oxidation state of Iodine in KIO3
The number of electrons lost by an atom when forming a
compound or ion

K+ O2- O2- O2- so its I +5

NB not 5+

i. Oxidation and Reduction


Can you answer these questions
In the equation below, can you assign oxidation
states to each element and say what is being oxidised
and what is reduced
2H2S + SO2 2H2O + 3S
+1 -2

+4 -2

Oxidised Reduced

+1 -2

j. Half and full equations


Can you answer these questions
Can you write half equations for: SO2 H2SO4
Can you write a half equation for MnO4- Mn 2+
Can you combine them into a full equation
SO2 + 2H2O

H2SO4 + 2H+ + 2e-

MnO4- + 8H+ + 5e- Mn2+ + 4H2O


5SO2 + 10H2O + 2MnO4- + 16H+ + 10e-

X5
X2

5H2SO4 + 10H+ + 10e- + 2Mn2+ + 8H2O

k. The Blocks of the Periodic


Table
Can you answer these questions
Can you label the blocks of the periodic table?

p
d

l. Ionisation Enthalpies
Can you answer these questions
Write en expression for the 1st and 2nd ionisation enthalpies of Mg
Explain why the 2ns IE for Mg is higher than the 1st and the 3rd is
much higher
Mg(g) Mg+(g) + eMg+(g) Mg2+(g) + eSuccessive IEs are always larger as you are removing an electron
from an increasingly positively charged ion
The 3rd IE of Mg is much higher as you are breaking into a new
shell which is closer to the nucleus and held more strongly

m. Properties of Halogens
Can you answer these questions
Can you describe the appearance of Cl, Br and I
What happens to their B.Ps
How does their solubility in water and hexane change
Yellow gas, red/brown liquid, black solid
Boiling points increase down group
Solubility decreases down group..more soluble in hexane

n. Manufacturing Chemicals
Compare the following Industrial reactions
The Haber Process making Ammonia
Fermentation of sugar to make alcohol
Haber Process Continuous needs high temperatures
Fermentation: Batch process, works at 40oC

o. Halogens Reacting with Halides


Can you answer these questions
Whats the difference between halogen and halide
Can you complete these equations
2KBr + Cl2

2KCl + Br2

KBr + I2

No reaction

o. Reactivity of the Halogens


Can you answer these questions
What happens to the reactivity as you go F-Cl-Br-I
Can you explain this trend
Reactivity decreases down group

As atoms get larger, they attract electrons less strongly and form
weaker covalent bonds

p. Silver Halides
Can you answer these questions
Can you write equations for sodium chloride,
bromide and iodide reacting with silver nitrate
Can you write them as ionic equations
Can you give the observations for each reaction
AgNO3(aq) + NaX(aq) AgX(s) + NaNO3(aq)
Ag+(aq) + X-(aq) AgX(s)
AgCl White precipitate, AgBr cream , AgI pale yellow

q. Health and Safety Issues


Can you answer these questions
Can you give the hazard symbols for corrosive,
toxic, flammable , oxidising and harmful
Can you state the safety precautions of each
hazard
Sensible answers involving protective clothing, goggles, breathing
apparatus etc

r. Uses of Chlorine and Bromine


Can you answer these questions
Can you give 2 uses of bromine
Can you give 2 uses of Chlorine
Bromine Flame retardents, pesticides, in oil recovery from wells
Sterilising water, making PVC etc

s/t. Naming Halogenoalkanes


Can you answer these questions
Can you name this compound
H Cl Cl Br H H
HCCCCCCH
H Cl H H H H
4-Bromo-2,2,3-trichloro hexane

u. Making a Halogenoalkane
Can you answer these questions
How can you make 1-chloropropane from
propan-1-ol?
React it with concentrated HCl

v. Purifying an Organic Liquid


Can you answer these questions
The 1-chloropropane prepared in the previous
slide is impure, state two steps in purifying it
Shake with water to remove water soluble impurities
then distil it

w. Halogenoalkane properties
What are the trends in the properties of
Chlorobutane, bromobutane and Iodobutane
Boiling points
Formation of radicals with UV light
Reaction with water, ammonia and hydroxide
Boiling points increase down group
They form radicals more easily down group (weaker bond)
They get more reactive down group

x. Nucleophilic Substitution
Can you answer these questions
What is meant by hydrolysis?
What is meant by substitution?
What is a nucleophile, give an example
What is a carbocation, draw the structure of one
Splitting of a molecule with water
When one group swaps with another
Nucleus lover something with some negative charge
A Carbon atom with 3 bonds and a positive charge

y. Nucleophilic Substitution
Can you answer these questions
Write a mechanism for the reaction between
sodium hydroxide and bromomethane
What is the product if ammonia is used instead?
H
Forms an amine -NH2

H
HO:-

C + Br H

z. Reactivity of Halogenoalkanes
Can you answer these questions
Which is more polar C-Cl C-Br or C-I

C-Cl

Which bond is stronger C-Cl C-Br or C-I C-Cl


Which is more reactive, the chloro, bromo or iodo
compound?
C-I as the bond is weakest

aa. Shapes of Molecules


Can you answer these questions
Show the bond angles in the molecule of ethanol

105o
109o
109o

end. Extracting Bromine


Can you answer these questions
In the flow diagram below, can you say what is
happening to the Bromine in each step:
Cl2

SO2

Cl2

NaBr >>>>>>> Br2 >>>>>>> HBr >>>>>>>> Br2


Oxidation

Reduction

Oxidation

Aa. Giant Covalent Structures


Can you answer these questions
Can you draw the structures of diamond, graphite
and SiO2

Diamond

Graphite

Silicon Dioxide

A a. Carbon and Silicon Dioxides


Can you answer these questions
Can you draw the structures of CO2 and SiO2 and
explain why they have different properties

CO2 Simple molecule with


double bonds and weak
attraction between
molecules

SiO2 Macromolecule strong


single bonds between all the
atoms

end. Hydrated Ions


Can you answer these questions
Why is water such a good solvent for ionic substances
Draw a hydrated ion of Na+ and ClBecause water is a permanently polar molecule

Na+

Cl-

end. Problems with Mineral


Extraction
Can you answer these questions
Can you name 3 environmentally problematic
byproducts from metal extraction and the problems
they cause
Waste material separated during purification
Sulphur dioxide acid rain
Carbon monoxide toxic to humans
Carbon dioxide.greenhouse gas

end. Vacuum Filtration


Can you answer these questions
Can you draw the apparatus for vacuum filtration

Buchner Funnel

end. Acid-Base Reactions


Can you answer these questions
Which is the acid and which the base in the
reaction below:
NH3 + H2O NH4+ + OH-

Base..accepts
Proton

AcidDonates
Proton

End Flow Diagrams


Can you answer these questions
Can you draw a flow diagram for making bread
Mix Flour water and yeast
Knead and place in tin,
leave to rise

Bake in Hot oven

Knead into a Dough

Leave somewhere
warm to rise
ENJOY!

end. Types of Reaction


Can you answer these questions
Can you classify each of these reactions
NaOH + HCl NaCl + H2O

Neutralisation

NaCl + AgNO3 AgCl + NaNO3

Precipitation

CuSO4 + Fe Cu + FeSO4

Redox

end. Extracting Metals


Can you answer these questions
What are the 3 major steps in extracting a metal
from its ore
Extract and purify the metal ore
Reduce the metal ore to the metal
Purify the metal

end. Acid Base Reactions


Can you answer these questions
What is the definition of an Acid?
What is the definition of a Base?
Acid = Proton Donor

Base = Proton Acceptor

Navigation Page
Select the Unit you wish to study
Elements from the Sea
Polymer Revolution
Atmosphere
End Slides

Questions on Polymer Revolution

a. Water
Can you answer these questions
Can you show the bonding and shape of water
Can you show the attraction between water molecules
H

H +

O
O -

H +

H
H
O
H

b. Intermolecular Attractions
What forms of attraction are there between
molecules of
Bromine

Instantaneous Dipole/Induced Dipole

HBr

Permanent dipole/permanent dipole

H2O

Hydrogen Bonding

Explain their BP Hydrogen bonding is strongest

c. Dissolving Polymers
Can you answer these questions
Dissolving polymers have OH groups, why does
this make them soluble?
If there are too many OH groups the polymer
becomes insoluble why is this?
OH Groups can hydrogen bond with water
If there are too many OH groups, they will hydrogen
bond with each other making the polymer insoluble

d. Naming Alkenes
Can you answer these questions
What is the name of this alkene
H

H H

CH3

HCCC=CCH
H H

H H
Hex-3-ene

e. Recognising Functional Groups


What functional groups are represented by
C2H5OH

Alcohol

C6H5OH

Phenol

CH3CHO

Aldehyde

CH3COCH3
CH3COOH

Ketone
Carboxylic Acid

f. Types of Alcohol
Can you answer these questions
Draw 3 different types of alcohol with the formula
C4H10O
O-H

O-H
O-H
Primary

Secondary

Tertiary

g. Heating Under Reflux


Can you describe the technique for heating under reflux

No stopper

h. Elimination Reaction
Can you answer these questions
Write an equation for the reaction of butan-2-ol
with concentrated sulphuric acid
What type of reaction is this
Why can two different products form
CH3CH2CH(OH)CH3 CH3CH2CH=CH2 + H2O
Elimination
Can form but-1-ene or but-2-ene

i. Addition Polymerisation
Can you answer these questions
What are the product(s) of additional Polymerisation
What type of monomer produced an addition polymer
Addition polymerisation produces only a polymer,, no coproduct
Addition polymers come from alkene monomers

i. Monomers and Polymers


Can you answer these questions
Can you predict the structure of the polymer
formed from this monomer:
H

CH3
C=C

Cl

CH3

Cl

j. Reactions of Alkenes
Write equations for the reaction of ethene with
Bromine

C2H4 + Br2 CH2BrCH2Br

HBr

C2H4 + HBr CH3CH2Br

Hydrogen (Name catalyst)


C2H4 + H2 C2H6
Water(Name catalyst)
C2H4 + H2O CH3CH2OH
Nickel

Concentrated sulphuric acid

k. Alcohol Reactions
How will ethanol and phenol behave when added to
Acidified Potassium Dichromate(VI) Ethanol oxidises
Concentrated sulphuric acid

Ethanol dehydrates

l. Additions and Electrophiles


Can you answer these questions
What is an addition reaction
What is an electrophile, give an example
A+ B C

Electron lover something with some positive charge


Eg

H-Br -

l. Electrophilic Addition
Write a mechanism for the reaction between Bromine and Ethene
What type of mechanism is this?
H

C=C
H

+
C C

H
Br

Br

Br

Electrophilic Addition

Carbocation

Br-

Br
H C
H

H
C
Br

m. Alkene structures
Can you answer these questions
Can you draw 5 structures with the formula C4H8

Trans and cis but-2-ene

But-1-ene

Methylpropene Cyclobutane

m. Cis and Trans (Z/E) Alkenes


Can you answer these questions
Can you say what type of isomerism this is
Why are the two forms different
Which form is more stable and why
Geometric Isomerism
The double bond cant rotate
The trans(E) form is more stable, methyl groups farther apart

n. Attractions Between Polymers


Can you state the intermolecular attractions between
the chains in
Instantaneous Dipole/Induced Dipole
Polyethene
Polychloroethene(PVC)
Polyhydroxyethene

Permanent dipole/permanent dipole

Hydrogen Bonding

o. Thermo and Thermosetting Plastics


Can you answer these questions
What is the difference between a thermoplastic
and a thermosetting plastic
Thermoplastics can be melted because there is only weak
attraction between the chain molecules
Thermosetting polymers will not melt because there are
covalent bonds cross linking the molecules

p. Infra red Spectra


Can you Identify the key peaks in the infra red spectrum of CH3COOH

q. The Fingerprint Region


Can you Identify the fingerprint region in the spectrum and say what it is
used for
Fingerprint region: Used for comparisons

end. Accidental Discoveries


Can you answer these questions
Why were the structures of early polymers
irregular and how were they improved
The polymerisation with an oxygen catalyst was a free radical
mechanism giving branched chains which do not pack together
closely, the use of better catalysts gave more regular structures

end.History of Addition Polymers


Can you answer these questions
Can you describe the discovery of polyethene
Can you explain how regular polymer structures
and conducting polymers were made
Made by accident when air (catalyst) leaked into ethene
which was then compressed and polymerised
Ziegler-Natta Calaylsts (Titanium chloride) allow regular
polymer structures
Conducting polymers were found to emit light

end. Polar Molecules


Can you answer these questions
Which of these molecules is/are polar
H2O

NH3

Polar

Polar

CH4
Non Polar

end. Structure and Properties


What effect will each of the following have on the
properties of a polymer
Making the chains longer

Stronger higher MP

Having side groups on the chains Less flexible


Having branched chains

Less dense

Making chains more flexible

Elastic

Cross linking chains

Thermosetting

Making structure more regular

Much Stronger

end. Crystallinity
Can you answer these questions
What is meant by a crystalline area of a polymer
What effect does crystallinity have on properties
A crystalline area is where the chains are regularly packed,
There is stronger attraction here

Navigation Page
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Elements from the Sea
Polymer Revolution
Atmosphere
End Slides

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Questions on Atmosphere

a. Carbon and Silicon Dioxides


Can you answer these questions
Can you draw the structures of CO2 and SiO2 and
explain why they have different properties

CO2 Simple molecule with


double bonds and weak
attraction between
molecules

SiO2 Macromolecule strong


single bonds between all the
atoms

b. Rates of Reaction
Can you answer these questions
What has to happen for a chemical reaction to take
place?
State 4 things that can sped up a chemical reaction
Molecules must collide with sufficient energy
Increase surface area, temperature, concentration or catalyst

c. Energy Profiles
Can you answer these questions
Draw an energy profile for an endothermic and an
exothermic reaction.
On the profiles, label the activation energy
E

d. Temperature and reaction Rate


Can you answer these questions
Sketch a graph showing the way temperature
affects reaction rate
Explain the shape of the graph you have drawn
Increasing the temperature
dramatically increases the
number of particles with
sufficient energy (activation
energy) to react

e. Catalysts
Can you answer these questions
How does a catalyst speed up a chemical reaction?
Show this on the reaction profile
By Providing a reaction pathway needing less activation energy
E

f. Intermediates in Catalysis
Can you explain and illustrate the role of intermediated in
Homogeneous catalysis
In the Reaction A+ B products if the Catalyst is C then
The reaction is A _ C AC then AC +_ B Product + C
AC is the intermediate, it is the small dip in the catalised reaction
profile
Intermediate

g. Dynamic Equilibrium
If a reaction is in Dynamic Equilibium
What is meant by the term dynamic?
What is meant by the term equilibrium?
Dynamic, means continually going on
Equilibrium means the reaction is going forwards and
backwards at the same rate so there is no net change in
concentration

h. Carbon Dioxide and Water


Can you answer these questions
Write an equation for carbon dioxide dissolving in
water
Write an equation for carbon dioxide reacting with
water
CO2(g) CO2 (aq)

CO2 (aq) +

H2O (l)

H+ (aq) + HCO3- (aq)

h.Le Chateliers Principle


For the Exothermic Reaction N2(g) + 3H2(g) 2NH3(g)
Describe and explain the effects on the equilibrium of
Increasing the concentration of the nitrogen
Increasing the temperature
Increasing the pressure
Moves equilibrium to right to lower [N2]
Moves equilibrium to left (to lower temperature of exothermic reaction)
Move equilibrium to right to lower pressure 4 mols of gas go to 3 mols

i. Composition of the Atmosphere


Can you answer these questions
What the the three major gases in the atmosphere
Name three gases found naturally in trace amounts
Name three pollutant gases
Nitrogen Oxygen Argon
Carbon Dioxide Krypton

Neon

Sulphur dioxide Nitrogen dioxide Methane

j. ppm
Can you answer these questions
Carbon dioxide makes up 0.037% of the
atmosphere, what is this in Parts per million?
To turn % to ppm, multiply by 10000

0.037 x 10000 = 370ppm

k. Ozone

O
O

Can you answer these questions


What is the structure of an ozone molecule
How is ozone formed in the atmosphere?
How is ozone naturally destroyed in the
atmosphere?
Formation O2 O* + O*

Destruction O3 O* +

O* + O2 O3

O2

O* + O* O2

l. Understanding Ozone Depletion


Can you explain how and where depletion of the ozone was first
noticed and what it was attributed to
The ozone depletion was notices near the north and south poled
by measuring infra red absorption of the bond in ozone. It was
immediately accepted that it was caused by chlorine radicals from
CFCs

m. Homolytic and Heterolytic Fission


Can you answer these questions
What happens in heterolytic bond fission?
What happens in homolytic bond fission?
What can cause homolytic fission?
Both electrons go to one atom
One electron goes to each atom
UV light or very high temperatures

n. Steps in a Radical Reaction


Can you answer these questions
What is the first step which forms the radicals
called?
Initiation
What name is given to the steps which spread the
chain reaction?
Propagation
What name is given to steps where 2 radicals join?
Termination

o. Alkanes reacting with Halogens


CH4 + Br2 CH3Br + HBr Free Radical Substitution (UV light)

Can you answer these questions


Give an overall equation for methane reacting with bromine
State the reaction conditions and name the mechanism
Give the 4 steps of the reaction naming each step
Explain why C2H6 and CH2Br2 form as byproducts
Br2 2Br*

Br* + CH4 CH3* + HBr

CH3* + Br2 CH3Br + Br*

Br* + Br* Br2

CH3* + CH3* C2H6

CH3Br + Br* CH2Br* + HBr

p. CFCs
Can you answer these questions
Give 3 uses of CFCs
What 2 properties made them so useful?
Aerosols, fridges and solvents

Unreactive and very volatile

p.Replacing CFCs
CFCs can be replaced by HCFCs, HFCs or alkanes
Explain what these three compounds are
Give an advantage of each one
Give a disadvantage of each one
Hydrochloroflurocarbon Hydrofluorocarbon

Hydrocarbon

None is ozone depleting


Expensive

Expensive

Flammable

q. Protection by Ozone
Can you answer these questions
How does the ozone layer protect us?
By absorbing UV light (in the process ozone is
destroyed, but more is formed)

q. Depletion of the Ozone Layer


Can you answer these questions
How do CFCs cause ozone depletion?
CFCs form Cl* radicals in the stratosphere
Cl* + O3

ClO + O2

ClO + O Cl* + O2

r. Missing the Ozone Hole


Why did the Americans at first miss the evidence for the hole in
the ozone Layer
They used satellites to measure the ozone concentrations
But they programmed the computers to reject any unusual results

s. Quantised Energy
Can you answer these questions
What is a quantum of energy?
What forms of energy in a molecule are quantised?
A quantum, is the smallest allowed amount of energy a particle can have
Electron energy levels, vibrations and rotations are all quantised

t. Energy and Molecules


Can you answer these questions
What effect does microwave radiation have on
molecules? Makes molecules rotate and heat up
What effect does Infra red radiation have on
bonds?
Makes bonds vibrate
What effect does ultra violet radiation have on
bonds?
Makes bonds break

u. Frequency and Energy of Radiation


Can you answer these questions
What is the link between the energy of radiation
and its frequency?

E = hf

v. Homogeneous Catalysis
Can you answer these questions
What two steps are needed for a homogeneous
catalyst to speed up a chemical reaction?
Catalyst joins to chemical forming an intermediate
Catalyst breaks off so it can react again

v. Greenhouse Effect
Can you answer these questions
Explain the causes of the greenhouse effect
What are some of the consequences of the
greenhouse effect?
Visible and ultra violet light passes through the atmosphere
and is re-emitted as infra red radiation.Carbon dioxide
molecules absorb infra red radiation and prevent it
escaping back into space.
Global warming, rise in sea levels, climate change

w.Greenhouse Gases and Global


Warming
What is the link between changes in Carbon dioxide levels in the
atmosphere and global temperatures
Carbon dioxide levels are
increasing, global
temperature levels are
rising, the two are
probably linked with the
CO2 level rise causing the
temperature rise

x. Controlling Global Warming


Can you answer these questions
What steps can be taken to reduce carbon dioxide
build-up?
Burn less fossil fuel
Replace trees that have been chopped down or increase
photosynthesis in the seas
Capture the CO2, solidify and store under the oceans

end. Radicals
Can you answer these questions
How are radicals formed?

Homolytic Fission

What conditions are needed

UV light, high temp

What are radicals like?

Have odd electrons

How do radicals react?

Chain reactions with


the first thing they hit

end. Halogenoalkanes
Can you answer these questions
Draw two structures of halogenoalkanes with 3
carbons and a bromine atom
CH3CH2CH2Br

CH3CHBrCH3

end. Effects of Radiation


Can you answer these questions
Given these data, predict whether you can get a
sun tan under water and behind glass:
Frequency of UV Radiation: 8-11 x 1014 Hz
Water Absorbs above 16 x 1014
Glass absorbs above 9 x 1014
Glass absorbs UV but water does not

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