Beruflich Dokumente
Kultur Dokumente
Jacek Chwast
jacek.chwast@ees.kuleuven.be
Geo-Instituut
23.01.2013
Measurement conditions
Netzsch STA 409 PC Luxx:
- T [25 1000 C]
- heating rate 10 C/min
- N2 atmosphere (60 ml/min)
- alumina crucibles
- simultaneous measurement of mass
change (TG) and heat flow (DSC)
- 1 analysis (25100025 C) = 3 hrs
furnace
microbalance
Measurement conditions
furnace
sample + reference
microbalance
T
G/m
g
D
T
G/(m
g/m
in
)
0
.0
0
0
[1
]
-0
.5
0
0
[1
]ce
m
I1
A4
d
.dsv
T
G
D
T
G
-1
.0
0
0
0
.0
-0
.1
-0
.1
-1
.5
0
0
O
n
se
t*: 4
2
9
.2C
-0
.2
-2
.0
0
0
-0
.2
-2
.5
0
0
[1]
1
0
0
.0
2
0
0
.0
3
0
0
.0
4
0
0
.0
5
0
0
.0
6
0
0
.0
7
0
0
.0
T
e
m
pe
ra
ture/C
8
0
0
.0
9
0
0
.0
-0
.3
1
0
0
0
.0
Sample compatibility
Requirements:
- no reaction with alumina crucible
- no expansion or creep during thermal decomposition
Compatible materials (KUL expertise):
- clays and other geological materials
- cements
- slags
Limitations:
- polymers can be hazardous, as they can foam at high
temperatures,
- compatibility assessment is necessary for new materials
5
sample composition
temperature range (max. 1000 C)
inert atmosphere
alumina crucible
Sample preparation
1) Sample form:
fine powders
compact solids
films, fibers
Analysis of results
Software: NETZSCH Proteus (Marsh procedure)
Quantification of portlandite (Ca(OH)2) content in cement
T
G/m
g
0
.0
0
0
D
T
G/(m
g/m
in)
[1]
-0
.5
0
0
[1
]ce
m
I1
A4
d
.d
sv
T
G
D
T
G
-1
.0
0
0
0
.0
-0
.1
-0
.1
-1
.5
0
0
O
n
se
t*: 4
2
9
.2C
-0
.2
-2
.0
0
0
-0
.2
-2
.5
0
0
[1]
1
0
0
.0
2
0
0
.0
3
0
0
.0
4
0
0
.0
5
0
0
.0
6
0
0
.0
7
0
0
.0
T
e
m
pe
ra
tu
re/C
8
0
0
.0
9
0
0
.0
-0
.3
1
0
0
0
.0
Analysis of results
Software: NETZSCH Proteus (Marsh procedure)
Quantification of portlandite (Ca(OH)2) content in cement
T
G
/m
g
[1
]c
e
m
I1
A4
d
.d
s
v
T
G
-1
.7
0
0
-1
.8
0
0
mass
loss
-1
.9
0
0
-2
.0
0
0
[1
]
-2
.1
0
0
4
0
0
.0
4
2
0
.0
4
4
0
.0
4
6
0
.0
T
e
m
p
e
ra
tu
re/C
4
8
0
.0
5
0
0
.0
Analysis of results
Software: NETZSCH Proteus (Marsh procedure)
Quantification of portlandite (Ca(OH)2) content in cement
T
G
/m
g
[1
]c
e
m
I1
A4
d
.d
s
v
T
G
-1
.7
0
0
-1
.8
0
0
-1
.9
0
0
-2
.0
0
0
[1
]
-2
.1
0
0
4
0
0
.0
4
2
0
.0
4
4
0
.0
4
6
0
.0
T
e
m
p
e
ra
tu
re/C
4
8
0
.0
5
0
0
.0
10
Analysis of results
Software: NETZSCH Proteus (Marsh procedure)
Quantification of portlandite (Ca(OH)2) content in cement
T
G
/m
g
[1
]c
e
m
I1
A4
d
.d
s
v
T
G
-1
.7
0
0
M
a
s
sL
o
s
s(M
a
rs
h
):
O
n
s
e
t:
4
3
1
.7C
In
fle
c
tio
n
:
4
4
0
.4C
M
a
s
sC
h
a
n
g
e
: -0
.2
5
8m
g
-1
.8
0
0
-1
.9
0
0
-2
.0
0
0
[1
]
-2
.1
0
0
4
0
0
.0
4
2
0
.0
4
4
0
.0
4
6
0
.0
T
e
m
p
e
ra
tu
re/C
4
8
0
.0
5
0
0
.0
11
13