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An atom is the smallest unit quantity of an element that can exist on its own or
can combine chemically with other atoms of the same or another element.
Composed of protons, neutrons and electrons.
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element symbol
atomic number
ISOTOPES
Same number of protons and electrons but different mass numbers.
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EXAMPLE
Calculate the value of Ar for naturally occurring chlorine if the distribution of
isotopes is 75.77% and 24.23% . Accurate masses for and are 34.97 and
36.97.
SOLUTION
The relative atomic masses of chlorine is the weighted mean of the mass
numbers of the two isotopes.
isotopes is 69.2% and 30.8% ; accurate masses are 62.93 and 64.93.
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QUANTUM THEORY
Development of quantum theory took place in two steps; in the older
theories, the electron was treated as a particle. In more recent models, the
electron is treated as a wave, hence wave mechanics.
A quantum of energy is the smallest quantity of energy that can be emitted
(or absorbed) in the form of electromagnetic radiation (Planck-1901).
The energy, E, is given by:
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and n is an integer 3, 4, 5,
The various series in atomic H emission spectrum
Series
Region
Lyman
1 2,3,4, .
UV
Balmer
2 3,4,5, .
Visible
Paschen
3 4,5,6, .
IR Brackett
4 5,6,7,
. IR
Pfund
5 6,7,8, .
IR
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If we apply the Bohr model to the hydrogen atom, the radius of each allowed
circular orbit can be determined from the equation:
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WAVE MECHANICS
WAVE NATURE OF ELECTRONS
de Broglie (1924) if light composed of particles and showed wave-like
properties, the same should be true for electrons and other particles.
Proposed wave-particle duality and stated that classical mechanics with the
idea of wave-like properties could be combined to show that a particle
with momentum, mv possesses an associated wave of wavelength, .
a nucleus and only one electron, e.g. 1H, i.e. hydrogen-like system.
Equation may be represented in several forms, but the following equation is
appropriate for motion in the x direction.
=0
=0
ATOMIC ORBITALS
THE QUANTUM NUMBERS n, l and ml
The principal quantum number, n, is a positive integer with values lying
between the limits 1 n ; arise when the radial part of the wavefunction is
solved.
Two more quantum numbers, l and ml , appear when the angular part of the
wavefunction is solved.
The quantum number l is called the orbital quantum number and has allowed
values of 0, 1, 2, . , (n-1). Its value determines the shape of the atomic
orbital and the orbital angular momentum of the electron.
The value of the magnetic quantum number, ml , gives information about the
directionality of an atomic orbital and has integral values between +l and l.
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2
p
3
d
4
f
..
g ..
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ELECTRON SPIN
Two more quantum numbers required to specify the spatial distribution of an
electron in an atom and are related to spin.
Spin is described by two quantum numbers, s and ms.
Spin magnetic quantum number, ms takes only two values, + and -
NODES
Orbitals are best expressed in terms of spherical polar coordinates.
The positions where the wavefunction passes through zero are called nodes.
There are two types of nodes, radial nodes occur where the radial
component of the wavefunction passes through zero and angular nodes
occur where the angular component of the wavefunction passes through
zero.
An orbital with quantum numbers n and l, in general has n l - 1 radial nodes.
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ml
No. of orbitals
AO designation
1s
2s
-1, 0, 1
3s
-1, 0, 1
-2,-1,0,1,2
An orbital is fully occupied when it contains two electrons which are spinpaired; one electron has a value of ms = + and the other, ms = -.
Atomic orbitals are regions of space where the probability of finding an
electron about an atom is highest.
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The s Orbitals
s orbitals are spherically symmetric.
As n increases, the s orbitals get larger and the number of nodes increase.
A node is a region in space where the probability of finding an electron is zero.
1s
2s
3s
4s
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The p Orbitals
There are three p-orbitals px, py, and pz which lie along the x-, y- and z- axes of
a Cartesian system.
Correspond to allowed values of ml of -1, 0, and +1.
The orbitals are dumbbell shaped and as n increases, the p orbitals get larger.
All p orbitals have a node at the nucleus.
pz
px
2p
py
pz
px
py
3p
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