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2. Honey adulteration
Honey Authenticity
PPP-Indien/Quality Control.
QSI 2013
QSI 2012
1. Honey origin
Honey Authenticity
QSI 2013
pro
information about geographical and botanical origin with one single test
furthermore overview about possible fermentation, adulteration, contamination etc.
con
only performable by staff with considerable experience
does not work for filtered honey (or mixtures of filtered and unfiltered honeys)
Honey Authenticity
QSI 2013
pro
besides determination of origin additional information about toxic heavy metals
con
large databases are required for evaluation
at least 20 different elements necessary complex statistical evaluation
strong impact on the composition of elements by nearby industry
expensive test due to costly instrumentation
Honey Authenticity
QSI 2013
pro
-
con
large databases necessary (difficult to available)
expensive test due to costly instrumentation
Honey Authenticity
QSI 2013
2. Honey adulteration
Honey Authenticity
QSI 2013
Honey adulteration
Addition of sugars to honey
Feeding of sugars to bees
Addition of pollen
Addition of filtered honey
Honey Authenticity
QSI 2013
pro
covers all sugars from C4-plants, e.g. corn ( high fructose corn syrup) and sugar
cane
foreign sugars are quantified accurately (limit: 7 %)
AOAC Official Method 998.12, worldwide approved and accepted
sugars from C3-plants could be detected, too (example: rice syrup, beet sugar)
con
sugars from C3-plants detectable in higher amounts, but no quantification possible
Honey Authenticity
QSI 2013
2007
70,00%
2008
60,00%
2009
50,00%
2010
40,00%
30,00%
20,00%
10,00%
0,00%
Honey Authenticity
2011
2012
2011
2010
2009
2008
2012
2007
</=7
>7
QSI 2013
10
Honey Authenticity
QSI 2013
11
pro
some syrups mixed of C3 and C4 can possibly be detected
con
determination of pure C4- or C3-sugars not possible
Results honey study QSI: 13C-results of single sugar fractions differ considerably in
freshly collected acacia nectars high natural variations possible
Honey Authenticity
QSI 2013
12
pro
many information with one single test
con
all indications mentioned above can occur naturally in honey, depending on the type
confirmation required
no quantification of foreign sugar
Honey Authenticity
QSI 2013
13
pro
covers all starch-based syrups, independent from carbon isotopes
sensitive test, detection limit about 0.1 - 1 % added syrup (BUT: such low amounts
could possibly not be technically avoidable after feeding the bees)
con
no quantification possible due to high variations of oligosaccharides in different syrups,
depending on the origin and the treatment of the syrup
Honeydew honeys contain oligosaccharides naturally, which need to be distinguished
Honey Authenticity
QSI 2013
14
QSI 2013
15
QSI 2013
16
QSI 2013
17
Starch-based syrup
Honey Authenticity
QSI 2013
18
Honey Authenticity
QSI 2013
19
pro
high specific test, substance only occurs in beet sugar syrup
positive findings even when inverted beet sugar is added to honey
con
no quantification possible due to high variations of the marker substance in different
syrups, mainly depending on the treatment of the syrup
Honey Authenticity
QSI 2013
20
(SM-
pro
high specific test, substance only occurs in rice syrup
con
no quantification possible due to high variations of the marker substance in different
syrups, mainly depending on the treatment of the syrup
Honey Authenticity
QSI 2013
21
pro
-
con
depending on the soil conditions and treatment of the syrup, the amounts of arsenic
vary considerably unreliable results
Honey Authenticity
QSI 2013
22
pro
high specific test
con
no quantification of added sugar possible
if inversion is carried out in another way and/or if the enzyme is destroyed after
inversion negative results in spite of adulteration with beet sugar
Honey Authenticity
QSI 2013
23
pro
-
con
no quantification of added sugar possible
same as foreign invertase: if inversion is carried out in another way and/or if the
enzymes are destroyed after inversion negative results in spite of adulteration
Honey Authenticity
QSI 2013
24
QSI 2013
25
13
covers all sugars from C4-plants (cane, corn etc.) and even
possibly from C3-plants
Honey Authenticity
QSI 2013
26
Honey Authenticity
QSI 2013
27