Beruflich Dokumente
Kultur Dokumente
University of Parma, Department of Physics and Earth Sciences , Parco Area delle Scienze 7/a, 43124 Parma (Italy)
University of Milano-Bicocca, Department of Geological Sciences and Geotechnologies, Piazzale della Scienza 4, 20126 Milano (Italy)
Table 1:
analyzed samples, position of the main Raman
peak and X=Mg/(Mg+ +Fe2+) ratio obtained by
SEM-EDXS.
2+
2+
X0.9
= tremolite
0.5<X<0.9 = actinolite
X<0.5
= ferro-actinolite.
Wavenumber
(cm-1)
Mg /(Mg +Fe )
(from EDXS)
#1
671,41
0,81
#2
672,94
0,88
#3
672,95
0,87
#4
672,47
0,83
#5
669,30
0,76
#6
671,41
0,76
#7
672,76
0,85
#8
673,85
0,94
#9
674,05
0,96
#10
671,60
0,89
#11
673,50
0,94
#12
673,04
0,92
#13
673,87
0,95
#14
672,68
0,87
#16
674,75
1,00
#17
665,64
0,44
#18
672,54
0,85
#19
669,50
0,67
#20
671,94
0,85
#21
674,23
0,99
2+
2+
1-7
8-15
16-21
1
O
H
2
3
N.
2+
Wavenumber (cm-1)
600
674.4
500
3.
1061.3
1071.5
1030.2
931.9
751.1
416.4
333.0
351.4
0.0
100
394.5
223.8
233.5
251.3
200
370.1
300
179.2
Intensity(cnt)
400
0
200
300
400
500
600
700
1
RamanShift(cm )
800
900
800
900
1000
We verified the shift at low wavenumbers of the main peak with the increase of iron, performing a micrometric Raman
map on a zoned needle-shaped actinolite crystal coming from Alpe Rosso (Vigezzo Valley, Italy).
Micro-photo of a zoned actinolite crystal: the green
colour, increasing from left to right, is due to Fe ions.
Campolongo, Switzerland
671.8
700
600
947.5
742.1
514.7
349.1
371.1
391.5
413.3
436.1
100
156.9
174.7
200
929.6
300
223.5
Intensity(cnt)
400
105
69
0.8
.0
1028.4
500
0
200
300
400
500
600
700
RamanShift(cm1 )
1000
1100
References
1.Rong Wang and Wei-Shan Zhang, Application of Raman spectroscopy in the nondestructive analyses of ancient Chinese jades, J. Raman Spectrosc. 42, 1324 (2011)
2.T.-H. Chen, T. Calligaro, S. Pags-Camagna, M. Menu, Investigation of Chinese archaic jade by PIXE and -Raman spectrometry, Appl. Phys. A 79, 177 (2004)
3.A. Wang, P. Dhamelincourt, G. Turrell, Raman Microspectroscopic Study of the Cation Distribution in Amphiboles, Appl. Spectrosc. 42, 1441 (1988)