Beruflich Dokumente
Kultur Dokumente
ADVANCED TRANSPORT
PROCESSES /
TRANSPORT PHENOMENA
5. Mass Transport
Lesson 26: Diffusion through a Spherical
Stagnant Gas Film
Course Outcomes
CLO Explain the theoretical aspect of
1
momentum,
mass
and
energy
transport
CLO Apply
mathematical
and
numerical
2
methodology in analyzing momentum
transfer problem
CLO Apply
mathematical
and
numerical
3
methodology in analyzing heat transfer
problem
CLO Apply
mathematical
and
numerical
4
methodology in analyzing mass transfer
problem
CLO Analyze and solve transport phenomena
5
using Computational Fluid Dynamics (CFD)
Semester May
2013
Lesson outcomes
At the end of the lesson the student should be able to
Lesson 26. Solve the problem of diffusion through a stagnant
spherical gas film.
Assumptions
B is stagnant
NB=0
Boundary conditions
At r=r1 xA=x A1
At r=r2 xA=x A2
N Az J Ar x A N Ar N Br
(1)
Since B is stagnant
N Ar J Ar x A N Ar
N Ar cDAB
dx A
x A N Ar
dr
(2)
Rearranging (2)
N Ar
cDAB dx A
1 x A dr
(3)
Rate of
Rate of
rate of production of A
0
mass of A in mass of A out by reaction
4 r 2 N Ar r r 2 N Ar
r r
(4)
r 2 N Ar r r 2 N Ar
r
r r
(5)
d 2
(r N Ar ) 0
dr
(6)
Integrating (6)
r 2 N Az c1
(7)
cDAB dx A
r
c1
1 x A dr
2
dx A
c
12 dr
1 xA r
(8)
1 x A2
1 1
cDAB ln
c1
1 x A1
r1 r2
(9)
cDAB
1 x A2
cDAB
c1
ln
(1 / r1 ) (1 / r2 ) 1 x A1
(10)
Since c1=(1/r2) NAr from (7) , we get the molar flux equation to be
N Ar
1 x A2
cDAB
2
ln
r [(1 / r1 ) (1 / r2 )] 1 x A1
(11)
NB: Note that for gasses it is common to give the partial and total
pressure together with temperature, rather than concentration in
such cases (11) can be changed as follows
10
P
RT
xA
pA
P
xB
pB
P
N Ar
P p A2
PDAB
2
ln
r RT [(1 / r1 ) (1 / r2 )] P p A1
(12)
11
1 xA
1 1
c1
cDAB ln
1 x A1
r1 r
(13)
1 1
r1 r
1 xA
1 x A2
ln
ln
1 x A1 1 1 1 x A1
r r
1 2
Simplifying (14) we get
1 x A 1 x A2
1 x A1 1 x A1
(14)
(1 / r1 ) (1 / r )
(1 / r1 ) (1 / r2 )
(15)
12
P p A P p A2
P p A1 P p A1
(1 / r1 ) (1 / r )
(1 / r1 ) (1 / r2 )
(15)
N Ar
1 x A2
cDAB
2
ln
r [(1 / r1 ) (1 / r2 )] 1 x A1
(11)
13
1 x A2
4cDAB
WA
ln
[(1 / r1 ) (1 / r2 )] 1 x A1
(16)
P p A2
4PDAB
WA
ln
RT [(1 / r1 ) (1 / r2 )] P p A1
(17)
14
Lesson outcomes
Lesson 26. Solve the problem of diffusion through a spherical
stagnant gas film.
15