All You Can Cram In 3

Hours
Chem 6C Edition
Stressed-Out Charlie Lin
And Miles whose last name I
cant spell

If all else fails, since its a multiple choice

exam, make one of these magical things.

Testimony: Ive had the same one since

high school and its gotten me through
exams, GREs, SATs, and pretty much
everything... Including the exam I took this
morning!
*Multiple
choice answer pencil, roll pencil and see what bubble you should fil

***Results may vary

*****If you are loud rolling a pencil you may or may not be removed from the testing prem

Transition Metals
Naming
Itll be a salt so name cation first then
anion
The cation or anion will be a complex to
name a complex:
Take all the ligands and put them by their
greek name alphabetically.

Q5: What is the correct name for

[Co(NH3)5Cl](NO3)2?

Reactions
Q4: Which of the following
coordination compounds will form a
precipitate when treated with an
aqueous solution of AgNO3?
a) [Cr(NH3)3Cl3]
b) [Cr(NH3)6]Cl3
c) [Cr(NH3)Cl]SO4
d) Na3[Cr(CN)6]
e) Na3[CrCl6]

Shapes
4 Primary shapes
Octahedral
6 ligand attachment points groups

Tetrahedral
Square Planar
Linear
2 Ligand attachment points

Isomers
Geometric
Enantiomers

Maybe skip :P
Which of the following compounds is
chiral?
[Cr(en)2Cl2]+ with cis Cl
[Cr(en)2(NH3)2]3+ with trans NH3
[Cr(en)3]3+
[Cr(en)Cl2(NH3)2]+ with cis Cl and cis NH3
http://www.nobelprize.org/nobel_prizes/
chemistry/laureates/2001/illpres/game.h
tml

Crystal Field Theory

D-orbital splitting
When 6 identical ligands attached to transition
metal ion to form octahedral complex
T2g orbitals
Eg orbitals

Paramagnetic
Unpaired electrons and can be magnetized by
external field

Diamagnetic
No unpaired electrons and cannot be magnetized
with external magnetic field

Which of the following is

paramagnetic?
a) Zn(H2O)62+
b) Co(NH3)63+
c) Ni(CN)42- (square planar)
d) Mn(CN)63Pg 1015 for low spin/high spin chart

26-34
Some of the first complexes
discovered by Werner in the 1890s
had the empirical formulas given
below. Also are the number of
chloride ions per formula unit
percipitated by the addition of Ag+
(aq).Empirical
Explain
these Number
observations.
Formula
of Cl- per
formula unit
percipitated by Ag+ (aq)
PtCl2*4NH3

PtCl2*3NH3

PtCl2*2NH3

 Chapter 26-70) Excess Pb2[Fe(CN)6]

(s) was equilibrated at 25C with an
aqueous solution of NaI(aq). The
equilibrium concentrations of I-(aq)
and [Fe(CN)6]4-(aq) were found by
chemical analysis to be 0.57 M and
0.11 M, respectively. Estimate the
value of Ksp of Pb2[Fe(CN)6](s). The Ksp
of PbI2(s) is 9.8x10-9 M3.

 Chapter 26-52) Predict the number of

unpaired electrons in
[Rh(NH3)6]3+ (low spin)
[FeF6]3 [Ir(H2O)6]3+ (low spin)

Buffers (21-20)
Describe how you would prepare
200.0 mL of a pH = 4.00 buffer
solution from a solution of 0.150 M
lactic acid, CH3CHOHCOOH (aq), and
a solution of 0.100-M barium
hydroxide, Ba(OH)2 (aq). Take the
pKa of lactic acid to be 3.86.

 Chapter 21-90) What is the pH of the

solution that results from the
addition of 25.0 mL of 0.200 M
KOH(aq) to 50.0 mL of 0.150 M
HNO2(aq)?

 Chapter 21-72)A 0.550 gram sample

of butyric acid is dissolved in 100.0
mL of water and titrated with 0.100
M NaOH(aq) to the equivalence
point. The volume of base consumed
is 62.4 mL. Calculate the molecular
mass of butyric acid, which has one
acidic proton per molecule.

Titrations
Suppose that 15.0 mL of 0.15 M
(C2H5)2NH (Kb 6.90 x 10-4) is titrated
with 0.10 M HCI.
What is the pH after the addition of 15.0
mL of 0.10 HCl?
Calculate the pH at the midpoint.
Calculate the pH at the equivalence
point.
What is the pH if 1.5 mL of HCl is added
past the equivalence point?

 Chapter 22-88) Calculate the

equilibrium chloride ion
concentration in a solution made by
mixing 50.0 mL of 1.00 M sodium
chloride with 50.0 mL of 1.00 M
mercury(I) nitrate at 25C.

Solubility (M3 4&6)

Calculate the concentration of free
iron ion (in molarity) in a 1.0 L
solution of 6.0 M NaCN after adding
FeCl2 to get 0.35 M FeCl2. Kf of
(Fe(CN)64-) = 1.0 x 1035
How many moles of CaF2 will dissolve
in 3.0 liters of 0.050 M NaF solution?
(Ksp for CaF2 = 2.0 x 10-10)

Qualitative Analysis

Entropy
Few notes:
S=0 if reaction is reversible
S>0 for a spontaneous process if its S system
+ Ssurroundings
S is a state function.

Calculate the entropy of vaporization of

mercury at room temperature, given the
following information: Cpm (liquid) = 27.97
J/mol*K, Cpm (gas) = 20.80 J/mol*K, Hvap =
58.96 kJ/mol at Tb = 356.7 C.

 Chapter 22-82) The equilibrium

constant for the equation

Is Kf = 0.500 M-1 at 25C. Calculate

the solubility of Zn(OH)2(s) in a 0.10
M NaOH solution at 25C.

 Chapter 23-84) The ClapeyronClausius equation can be used to

calculate the equilibrium vapor
pressure of a solid by writing Hsub in
place of Hvap. Given that Hsub =
25.2 kJ/mol for CO2(s) and that PCO2 =
1.0 x 102 kPa at -78.6C, calculate
the equilibrium vapor pressure of
CO2(s) at -100.0C.

 Chapter 23-82) Given that

for Br2(g) at 25C, calculate the
vapor pressure of bromine at25C.

Redox
How to determine whether youre in
an acidic or basic environment
If its a metal ion thats not group 1 or if
its already an acid its probably in an
acidic environment
If its a metal oxide, metal hydroxide, or
an anion then its probably in a basic
environment

 Balance the following equation.

Cr(OH)3 (s) + ClO (aq) > CrO42 (aq) +
Cl2(g)

 Chapter 24-66) A 3.651 gram sample of a lanthanum

sulfate ore is dissolved in nitric acid, and the
lanthanum precipitated as La(IO 3)3(s) by the addition
of 40.00 mL of 0.1105 M KIO 3(aq). When an excess of
KI(aq) is added to the acidified filtrate, I 2(s) results
from the reaction of the remaining IO -3(aq), as given
by

If it requires 12.65 mL of 0.0650 M Na 2S2O3(aq) to

react with this I2(s), according to

Calculate the mass percentage of La 2(SO4)3(s) in the

sample.

 Chapter 24-60) Peroxyidsulfate,

S2O82-(aq), is a strong oxidizing agent
that can oxidize Mn2+ (aq) to MnO4(aq); Cr3+ (aq) to Cr2O72-(aq); and V4+
(aq) to V5+(aq). Excess reagent can
be destroyed by boiling the solution
after oxidation is complete. Balance
the equation

Electrochemistry
Which of the following is characteristic
of the anode in an electrolysis cell?
a) It is where reduction occurs.
b) It attracts negative ions.
c) It receives electrons from the wire.
d) It may gain weight during
electrolysis.
e) More than one of the above is
correct.

 Chapter 25-72) An oxide cell,

involving Ag2O(s)Ag(s) cathode is
used to power a wristwatch. The cell
is estimated to last 1000 hours while
drawing a current of only 0.10 mA.
Calculate the mass of silver metal
that will be produced over the
lifetime of the cell.

 Chapter 25-52) An electrochemical

cell is set up so that the reaction
described by the equation
occurs. At 25C the measured cell
voltage is 2.03 V. Calculate the value
of Grxn.

Kinetics

Reaction Rates
Zero Order
First Order
Second Order
Half Lives

Chapter 17-60) A sample of radioactive

Na128I is injected into a patient as
part of radioiodine treatment of a
thyroid condition. If the sample has
an activity 10,000 disintegrations per
minute at 8 AM, the time of injection,
what is the activity at 2 PM the same
day? The half-life of iodine-128 is
25.00 minutes.

Chapter 17-54) A reaction of importance in the

formation of smog is that between ozone and
nitrogen monoxide described by
The rate law for this reaction is
Rate of reaction=k[O3][NO]
Given that k=2.99x10-5 M-1s-1 at 310 K, calculate the
initial reaction rate when [O3] and [NO] remain
essential constant at the values [O 3]0=2.0x10-6 M and
[NO]0=6.0x10-5 M, owing to continuous production
from separate sources. Calculate the number of
moles of NO2(g) produced per hour per liter of air.

18-32
The enzyme catalase catalyzes the
decomposition of H2O2 to H2O (l) and
O2 (g). Use the following data,
determine the value of Rmax and
Km, the Michaelis-Menten constant.
[H2O2]0/mmol
*L-1

1.0

2.0

5.0

R/mmol*L-1*s-1

1.38

2.67

6.00

Chapter 18-63) A suggested

mechanism for the reaction
described by
Is 1.
2.
The assumption here is that [NO3] is
governed by steady state kinetics.
Derive the rate law.

 Chapter 18-58) The reaction

has the following proposed reaction
mechanism

Determine the rate law.

 The enzyme catalase catalyzes the

decomposition of H2O2 to H2O (l) and
O2 (g). Use the following data,
determine the value of Rmax and
Km, the Michaelis-Menten constant.

[H2O2]0/mmol
*L-1

1.0

2.0

5.0

R/mmol*L-1*s-1

1.38

2.67

6.00

 The enzyme catalase catalyzes the

decomposition of H2O2 to H2O (l) and
O2 (g). Use the following data,
determine the value of Rmax and
[H O ] /mmol 1.0
2.0
5.0
Km, the Michaelis-Menten
constant.
*L
2
-1

2 0

R/mmol*L-1*s-1

1.38

2.67

6.00