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INGREDIENTS :
PROTECTIVE
AGENTS
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Introduction
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: Tensile strength
I n SBR, NBR, CR
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Fatigue
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Crazing
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Frosting
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Discolouration,
cracking
Hardening or softening
Degradation
occurs at
Surface only
Throughout
Effect of
unsaturation
Diene only
Effect of cure
system
No effect
Temperature
Rate enhances
Strain level
I ncreases crack
growth
No effect
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3.
Degree of cure:
I n NR and I R, overcure gives higher degradation.
I n synthetic rubbers like SBR, CR overcure improves
resistance to oxidative degradation.
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R. + O2 ------------->
ROO.
3.
4.
5.
RO. + RH ----------->
ROH + R.
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ROO. +
AH -------------> RH + A.
AH ------------> ROOH + A.
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O3
>C=C<
O3
>C
>C + OO(1)
C<
>C=O
O---O
>C
C<
O
(2)
I t is believed that the antiozonant reacts either with the (1) Zwitter
ion or the (2) Ozonide formed to make an inert protective film which
every time when broken, is repaired by formation of fresh film
produced by the reaction of rubber, ozone and antiozonant
(protective film theory).
The other concept (Scavenger theory) is that the antiozonant reacts
with ozone at a much faster rate than ozone reacts with the double
bond of rubber.
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Common
Chemical name
abbreviation
I PPD
6 PPD
77 PPD
DPPD
TMQ
SP
Styrenated Phenol
ODPA
BPH
BHT
MBI
2 - Mercaptobenzimidazole
MMBI
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Classsification of Antidegradants
Physical
Protectants
Chemical Protectants
Parrafin wax
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Functions of waxes
Waxes brings out the antioxidants and antiozonants
to the surface of the compound for giving the surface
protection.
Paraffin Wax or MC Wax without addtion of
antioxidants and antiozonants can only give static
ozone protection to rubber products.
For dynamic ozone protection to rubber products
Waxes along with antioxidants and antiozonants are
required .
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MBI and MMBI have given good results in steam aging of diene rubbers.
Rubbers with hydrolysable groups like EVA, AU are preferabily protected
with Carbodimides, all the ester grades are prestabilised.
Food and drug application: IPPD, DPPD, ODPA , BHT, SP, BPH,
are all approved by FDA
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