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4-1
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Figure 4.2
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Figure 4.3
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PLAN: We have to relate the information given and the number of moles of
ions present when the substance dissolves in water.
SOLUTION: (a) (NH4)2SO4(s)
5.0 mol (NH4)2SO4 x
H2O
2NH4+(aq) + SO42-(aq)
2 mol NH4+
1 mol (NH4)2SO4
4-6
continued
(b) CsBr(s)
Cs+(aq) + Br-(aq)
78.5 g CsBr x
(c) Cu(NO3)2(s)
H2O
mol CsBr
212.8 g CsBr
Cu2+(aq) + 2NO3-(aq)
mol Cu(NO3)2
7.42 x 1022 formula units x
6.022 x 1023 formula units
Cu(NO3)2
35 mL ZnCl2 x
1L
103 mL
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Zn2+(aq) + 2Cl-(aq)
(d) ZnCl2(aq)
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Figure 4.4
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Figure 4.6
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PLAN:
Write ions
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2F-(aq) + Sr2+(aq)
(b) NH4ClO4(aq) + NaBr (aq)
SrF2 (s)
NH4Br (aq) + NaClO4(aq)
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SOLUTION: One mole of H+(aq) is released per mole of nitric acid (HNO3)
HNO3(l)
H2O
H+(aq) + NO3-(aq)
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Write balanced molecular, total ionic, and net ionic equations for
each of the following acid-base reactions and identify the spectator
ions.
4-16
continued
SOLUTION:
(a) Sr(OH)2(aq) + 2HClO4(aq)
Sr(ClO4)2(aq) + 2H2O(l)
2H2O(l)
BaSO4(s) + 2H2O(l)
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BaSO4(s) + 2H2O(l)
BaSO4(s) + 2H2O(l)
Figure 4.7
Start of titration
Excess of acid
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An acid-base titration.
Point of
neutralization
Slight excess of
base
PLAN:
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SOLUTION:
NaOH(aq) + HCl(aq)
1L
NaCl(aq) + H2O(l)
= 0.03332 L NaOH
103 mL
0.03332 L x 0.1524 M
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= 0.1016 M HCl
Figure 4.8
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Figure 4.9
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PLAN:
The O.N.s of the ions in a polyatomic ion add up to the charge of the
ion and the O.N.s of the atoms or ions in a compound add up to zero.
SOLUTION:
(a) ZnCl2. The O.N. for zinc is +2 and that for chloride is -1.
(b) SO3. Each oxygen is an oxide with an O.N. of -2. Therefore, the
O.N. of sulfur must be +6.
(c) HNO3. H has an O.N. of +1 and each oxygen is -2. Therefore,
the N must have an O.N. of +5.
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Figure 4.10
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Figure 4.11
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PROBLEM: Identify the oxidizing agent and reducing agent in each of the following:
(a) 2Al(s) + 3H2SO4(aq)
Al2(SO4)3(aq) + 3H2(g)
Pb(s) + CO2(g)
2H2O(g)
PLAN: Assign an O.N. for each atom and see which atom gained and which atom
lost electrons in going from reactants to products.
An increase in O.N. means the species was oxidized (and is the reducing
agent) and a decrease in O.N. means the species was reduced (is the
oxidizing agent).
SOLUTION:
+1 +6 -2
+3 +6 -2
Al2(SO4)3(aq) + 3H2(g)
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continued
+2 -2
+2 -2
+4 -2
Pb(s) + CO2(g)
+1 -2
2H2O(g)
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Figure 4.12
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Figure 4.13
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Figure 4.14
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(a) Combination
3Mg(s) +
+2 -3
N2(g)
Mg3N2(aq)
(b) Decomposition
+1 -2
H2O2(l)
2H2O2(l)
1
O (g)
2 2
2H2O(l) + O2(g)
H2O(l) +
or
+2 +5 -2
Al(s) + Pb(NO3)2(aq)
2Al(s) + 3Pb(NO3)2(aq)
+3 +5 -2
Al(NO3)3(aq) + Pb(s)
2Al(NO3)3(aq) + 3Pb(s)
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