Beruflich Dokumente
Kultur Dokumente
THRM 110B
The Property of Entropy
THRM110B
8.
8.1
Entropy
The Property Entropy
Q
T
0
b
2
THRM110B
3
THRM110B
Recall
heat cannot by itself pass from a cold to a hot body. (Clausius)
Kelvin-Planck
THRM110B
The suffix int. rev is added as a reminder that the relation only holds for
an internally reversible process. The unit of S is kJ/K and s is (kJ/kg.K).
Notice the parallelism between the definitions of E and S.
6
THRM110B
7
THRM110B
THRM110B
9
THRM110B
10
THRM110B
11
12
THRM110B
Tds du pdv
Tds dh vdp
13
THRM110B
s 2 s1
cv dT
v2
R ln
T
v1
and
s 2 s1
c p dT
T
p2
R ln
p1
14
THRM110B
15
THRM110B
THRM110B
16
17
THRM110B
THRM110B
18
dS
dt
isolatedsystem
S isolatedsystem 0 .
19
THRM110B
The inequality holds for irreversible processes and the equality holds for
reversible processes. Note that for an isolated system the heat interaction
and work interactions outside the system boundary are zero.
The term isolated system is treated here as a single system comprising a
system together with its surroundings.
Another way of stating the principle is that: the entropy of an adiabatic
closed system always increases or, in the limiting case of a reversible
process remains constant. This statement is more general than stating an
isolated system since the latter includes W = 0 as a criteria. An isolated
system is a special case (W = 0)of an adiabatic closed system.
0
20
THRM110B
21
THRM110B
THRM110B
22
Since the heating of the block and the cooling of the reservoir are
internally reversible because no dissipation of energy takes place within
the system, the amount of heat transferred is represented by the area
beneath the path of each TS diagram. The two areas must be equal (Q is
the same) so the lower temperature of the block requires that
S block S reservoir
23
24
THRM110B
25
THRM110B
26
27
THRM110B
28
THRM110B