Air and water

Adriana Lpez Torres

Chemical Test

Test chloride and copper

Treatment of the water supply in

terms of filtration and chlorination
Water is purified by filtration, sedimentation and the
addition of chlorine

Uses of water in industry and in

home
Water in home

Composition of air
Air is a mixture of gases.
contains 79% nitrogen
contains 20% oxygen
contains 1% other gases (includingOxyge
n
argn, carbn dioxide and wter
(20%)
vapour)

Argon
(1%)

Nitrogen
(79%)

Normal components of our

atmosphere
Nitrogen - 78.1%
Oxygen 20.9%
Evrything else 0.07%
noble gases (krypton, xenn, argn, helium)
methane
sulfur dioxide

Effect of common pollutants on

buildings and on health
BUILDINGS
The partuculate matter
causes damage to buildings
The corrosion is enhanced
It causes cracks and fading
of pointed surface
Particulatess accumulate on
the soil and reduces fertility of soil

HEALTH

Destilation of liquid air

Prensence of oxides of nitrogen in

car engines
Car exhaust fumes are a major source of air pollution,
Carbon monoxide, sulfur dioxide, oxides of nitrogen and
unburnt hydrocarbons are present in car exahust fumes.

Primary Nutrients
Nitrogen-, phosphorus- and potassium-containing
fertilisersare considered primary nutrients.
Nitrogen-produce Green leafy growth
Phosphorus- flowers and fruit production
Potassium- priovide diesease resistance

Over the last several hundred thousand years, CO2 levels varied in tandem with the glacial cycles. During warm "interglacial" periods, CO2
levels were higher. During cool "glacial" periods, CO2 levels were lower. [2] The heating or cooling of Earths surface and oceans can cause
changes in the natural sources and sinks of these gases, and thus change greenhouse gas concentrations in the atmosphere. [2] These
changing concentrations are thought to have acted as a positive feedback, amplifying the temperature changes caused by long-term shifts
in Earths orbit. [2]

Carbon dioxide
Carbon dioxide is the primary greenhouse gas that is
contributing to recent climate change. CO2 is absorbed and
emitted naturally as part of the carbon cycle, through plant
and animal respiration, volcanic eruptions, and oceanatmosphere exchange. Human activities, such as the
burning of fossil fuels and changes in land use, release large
amounts of CO2, causing concentrations in the atmosphere
to rise.

Ammonia prosses

 Some notes on the conditions

The catalyst
The catalyst is actually slightly more complicated than pure iron. It has potassium hydroxide added to it as a promoter - a substance that increases its efficiency.
The pressure
The pressure varies from one manufacturing plant to another, but is always high. You can't go far w rong in an exam quoting 200 atmospheres.
Recycling
At each pass of the gases through the reactor, only about 15% of the nitrogen and hydrogen converts to ammonia. (This figure also varies from plant to plant.) By continual recycling of the unreacted nitrogen and hydrogen, the overall conversion is about 98%.

Explaining the conditions

The proportions of nitrogen and hydrogen
The mixture of nitrogen and hydrogen going into the reactor is in the ratio of 1 volume of nitrogen to 3 volumes of hydrogen.
Avogadro's Law says that equal volumes of gases at the same temperature and pressure contain equal numbers of molecules. That means that the gases are going into the reactor in the ratio of 1 molecule of nitrogen to 3 of hydrogen.
That is the proportion demanded by the equation.
In some reactions you might choose to use an excess of one of the reactants. You would do this if it is particularly important to use up as much as possible of the other reactant - if, for example, it was much more expensive. That doesn't apply in this case.
There is always a down-side to using anything other than the equation proportions. If you have an excess of one reactant there will be molecules passing through the reactor which can't possibly react because there isn't anything for them to react w ith. This wastes reactor space - particularly space on the surface of the catalyst.

The temperature
Equilibrium considerations
You need to shift the position of the equilibrium as far as possible to the right in order to produce the maximum possible amount of ammonia in the equilibrium mixture.
The forw ard reaction (the production of ammonia) is exothermic.

According to Le Chatelier's Principle, this w ill be favoured if you low er the temperature. The system w ill respond by moving the position of equilibrium to counteract this - in other w ords by producing more heat.
In order to get as much ammonia as possible in the equilibrium mixture, you need as low a temperature as possible. However, 400 - 450C isn't a low temperature!
Rate considerations
The low er the temperature you use, the slower the reaction becomes. A manufacturer is trying to produce as much ammonia as possible per day. It makes no sense to try to achieve an equilibrium mixture which contains a very high proportion of ammonia if it takes several years for the reaction to reach that equilibrium.
You need the gases to reach equilibrium within the very short time that they w ill be in contact with the catalyst in the reactor.
The compromise
400 - 450C is a compromise temperature producing a reasonably high proportion of ammonia in the equilibrium mixture (even if it is only 15%), but in a very short time.

The pressure
Equilibrium considerations

Notice that there are 4 molecules on the left-hand side of the equation, but only 2 on the right.
According to Le Chatelier's Principle, if you increase the pressure the system will respond by favouring the reaction which produces few er molecules. That will cause the pressure to fall again.
In order to get as much ammonia as possible in the equilibrium mixture, you need as high a pressure as possible. 200 atmospheres is a high pressure, but not amazingly high.
Rate considerations
Increasing the pressure brings the molecules closer together. In this particular instance, it will increase their chances of hitting and sticking to the surface of the catalyst w here they can react. The higher the pressure the better in terms of the rate of a gas reaction.
Economic considerations
Very high pressures are very expensive to produce on two counts.
You have to build extremely strong pipes and containment vessels to w ithstand the very high pressure. That increases your capital costs when the plant is built.
High pressures cost a lot to produce and maintain. That means that the running costs of your plant are very high.
The compromise
200 atmospheres is a compromise pressure chosen on economic grounds. If the pressure used is too high, the cost of generating it exceeds the price you can get for the extra ammonia produced.

The catalyst
Equilibrium considerations
The catalyst has no effect whatsoever on the position of the equilibrium. Adding a catalyst doesn't produce any greater percentage of ammonia in the equilibrium mixture. Its only function is to speed up the reaction.
Rate considerations
In the absence of a catalyst the reaction is so slow that virtually no reaction happens in any sensible time. The catalyst ensures that the reaction is fast enough for a dynamic equilibrium to be set up w ithin the very short time that the gases are actually in the reactor.

Separating the ammonia

W hen the gases leave the reactor they are hot and at a very high pressure. Ammonia is easily liquefied under pressure as long as it isn't too hot, and so the temperature of the mixture is lowered enough for the ammonia to turn to a liquid. The nitrogen and hydrogen remain as gases even under these high pressures, and can be recycled.

CARBON
CYCLE

 All living things are made of carbon. Carbon is also a part of the ocean, air, and even rocks.
Because the Earth is a dynamic place, carbon does not stay still. It is on the move!
In the atmosphere, carbon is attached to some oxygen in a gas called carbon dioxide.
Plants use carbon dioxide and sunlight to make their own food and grow. The carbon
becomes part of the plant. Plants that die and are buried may turn into fossil fuels made of
carbon like coal and oil over millions of years. When humans burn fossil fuels, most of the
carbon quickly enters the atmosphere as carbon dioxide.
Carbon dioxide is a greenhouse gas and traps heat in the atmosphere. Without it and other
greenhouse gases, Earth would be a frozen world. But humans have burned so much fuel
that there is about 30% more carbon dioxide in the air today than there was about 150
years ago, and Earth is becoming a warmer place. In fact, ice cores show us that there is
now more carbon dioxide in the atmosphere than there has been in the last 420,000 years.