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Measures for the Safe

Removal, Collection and


Disposal of Harmful Antifouling Systems
Edward Kleverlaan
IMO-Technical Officer

Bangkok, Thail

Introduction
Issues - general
Article 5 of the
AFSC
Look at :

Removal techniques
Collection
techniques
Disposal / Treatment
methods

Summary
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Shipyard facilities

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Shipyard facilities:
Activities of concern
Vessel repair and

maintenance
Fueling
Painting
Paint stripping
Public access and
recreation
Building/grounds
maintenance
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Chemical storage
and handling
Ship liquid
discharges
Ship breaking
Cargo handling

Shipyard facilities:
potential sources of
contaminants
Underground and
Older facilities
above ground
storage tanks
Chemical storage
Spills and leaks
Solid waste

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through which
seepage can occur
Non-maintained
facilities

Shipyard facilities: potential


discharges
Hazardous waste
Anti-fouling systems
Biocides

Solid Waste

Dry and liquid bulk

Bilge Water
Ballast Water
Cleaning agents
Nutrients

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Liquid waste
Hydro blast streams
Anti-fouling outwash

Storm water
discharge

Fuel and hydraulic


leaks

Oil
Sewage
Particulate matter
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Types of coatings
Pesticide based:

TBT
Copper
Arsenic
Mercury
PCBs

Pesticide free
Silicone
Epoxy

Ablative

Self-polishing

Non-ablative
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ARTICLE 5 - Waste
Materials
.a Party shall take

appropriate measures in
its territory to require that
wastes from the application
or removal of anti-fouling
system controlled in Annex
1 be collected, handled,
treated, and disposed of in
a safe and environmentally
sound manner to protect
human health and the
environment

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Main AFSC Issues


Increased paint

removals/overcoats by
AFSC ban of use of
TBT by September 2008

Worker Health issues:

Increased (gases, dust,


aerosols)

Problems with removal

of fouling organisms,
paint residues, paint
chips, and grit increase

Handling and long term


disposal of hazardous
substances

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1.1 Bio-fouling

Biofoulants The actual biofoulant


organisms can pose a threat of
pollution from:

TBT or other pesticide contamination


Increased Biological Oxygen Demand
(BOD) if dumped in the sea
Non-Indigenous Species

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1.2 Contaminated dust and


particles
Cleaning of vessel

bottoms creates
dust and paint
particles whatever
the coating
Need to contain the
dust
Need to treat the
wastes produced
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1.3 Contaminated water


Contaminated water
must be contained
Sumps
Berms

Contaminated water
must be treated

Treatment systems can be


expensive and complex
But basic solids control is
not expensive

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Examples of poor collection


and treatment

Lack of proper containment during antifouling paint


removal can result in deleterious substances being
released into the aquatic environment.

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1.4 Aerosols, dust and grit


Environmental health issues
Contact, breathing

Safety of Workers
Spray, grit

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2 Best Management
Practice
Definition: Good
Housekeeping

conduct everyday
activities in a more
ecologically-sound
and safe manner:
keeping pollutants
out of surface waters
and ground waters,
and, recognizing that
total containment
and recovery is not
always practical.

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2.1 Best Management


Practices
BMPs fall into two general groups:
Source-control (e.g., vessel shrouding,
sweeping, covering waste piles, and
bermed storage for wastes and paints)
and
Collection, filtration and treatment (e.g.,
hull washwater settling tanks and filters)
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2.1 Main Techniques


Removal techniques
Scraping
Blasting
Grit
Water

Collection

Techniques
Sumps
Berms

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2.1.1 Hull Biofoulant Removal

The primary processes for removal

of hull biofoulants are scraping and


pressure washing.
Hand Scraping using large flatbladed scrapers, generally has a slow
production rate, and is only suited for
working on small areas

Mechanical Scraping Many types of


mechanical scrapers have been
developed that clean the hull down to
the surface of the coating
Bangkok, Thail
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2.1.2 Hull Biofoulant Removal


Pressure Washing

Low-Pressure (<1,000 psi) Water

Washing useful in removing


slime and other low adhesion
biofoulants
High-Pressure (1,000 5,000 psi)
Water Washing is very effective in
removing low and high adhesion
biofoulants
Pressure Washing with Chemical
Additives increases the
effectiveness of biofoulant removal

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2.1.3 Management of
Biofouling Waste
Removed fouling organisms should be

collected for disposal


Sweep, vacuum , biofouling organisms
and deposit in containers for disposal
Do not allow biofouling organisms to sit
around the yard in containers it could
cause heath problems and attract pests

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2.2.1 Paint Removal


Dry Abrasive Blasting
Sand abrasives are generally considered to have

the highest emission rates of particulate matter


Slag abrasives
Furnace Slag (possible PAH Contamination)
Smelter Slag (possible Metal Contamination)
Mineral abrasives, such as garnet, are mined and
processed into abrasives
Metallic abrasives include iron and steel shot and
grit
Alternative types of abrasives
glass abrasive
dry-ice

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2.2.2 Blasting Grit media


choice
Some rules-of-thumb for media
selection:

Choose the least aggressive media. This will


result in less wear and lower equipment
maintenance expense.
Use the smallest media particle size - more
effective. More impacts per second will yield
a faster process.
Find the lowest blast pressure. This offers
the benefits of energy savings in reduced
compressed air requirements, as well as
less wear and lower maintenance costs.
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2.2.3 Blasting Types - 1


Compressed Air Dry Abrasive Blasting

process has highest pollutant emission


rates, particulate released directly to the air,
and the abrasive is not reused

Slurry Blasting uses water instead of air as

the medium to accelerate the abrasive. air


emissions greatly reduced due to the
water-curtain effect, the pollutants not
eliminated, but transferred from one media
(air) to another (water)

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2.2.3 Blasting Types - 2


Open-Loop Dry Abrasive Blasting processes abrasive is reused outside loop.

Depending upon type of abrasive being used and


the use of an abrasive cleaning process prior to
reuse, the particulate emission rates can be
significantly decreased or increased.

Closed-Loop Dry Abrasive Blasting processes


continuously contain both the abrasive and
the particulate emissions with the blasting
system.

Lowest emission rates of dry abrasive systems


and prevents contamination of the dry-dock floor
with spent abrasive
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2.2.4 Management of spent


grit

Avoid spent abrasive and dust to re-suspend in the air


by wind, or transport by runoff to the surface waters.

Reduce the amount of pollutants that reach the

environmental media of concern by increasing the


cleaning frequency to remove accumulated abrasive
and dust prior to exposure to rainfall and/or other
sources of runoff.

Covered Dumpsters/Bins Covering dumpsters and

bins being used to store spent abrasive prior to


transport to a storage or containment area prevents
the re-suspension of dust.

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2.2.5 Reduce and recycle


spent grit

Clean all deck surfaces of spent grit (by

sweeping, brushing, shovelling and


vacuuming) prior to submersion.
Clean and collect spent grit from yard areas
at the end of the work shift
Filter or provide collectors around yard
drains to prevent flushing of spent grit into
the storm water runoff or sewer system
Recycling of spent abrasive for use as an
aggregate material in the production of
asphalt and cement clinker.
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2.3.1 Management of Paint


Chips (TBT)
Difficult to separate grit from paint
chips
Continuous cleaning of the yard
surface and containment of the
waste paint will help reduce
contamination of the water.

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2.4 Waste Water


Water management is probably the

largest waste stream


Recovery and reuse of water can have
a significant reduction on pollution
loadings
Percent recovery of liquid waste
stream (volume of water used/volume
of water disposed)
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2.4.1 Collection of Hull Waste Water


Collect hull washwater and remove all visible
solids before discharging to a sewer or
receiving waters. Inspect and clean all sumps,
filters and/or screens regularly
Avoid any high pressure washing of hull unless
prior clean-up of the dock floor, lift platform, or
yard surface is completed.
Various treatment systems are available to
remove the contaminants from hull washwater.
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2.4.2 Collection of Hull Waste


Water
Option 1 - Very Low concentrations of suspended
solids and/or organics (e.g. storm water),

collected wastewater can be pumped and disposed of


directly into the sanitary sewer system.

Option 3- If the volume of wastewater is relatively

small and contains a high concentration of solids,


the wastewater can be directly processed by a
mechanical filter system.

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2.4.3 Collection of Hull Waste


Water
Option 2 - usually applicable to ship and boat building
and repair facilities with large volumes of wastewater
containing high concentrations of solids.
An engineered holding settling tank system is an important
component of the treatment system. The settling tank is
designed to remove most of the solids.
After treatment, the clarified effluent or overflow from the
holding/settling tank can be discharged into the sewer
system.
The settled sludge can be further processed by dewatering
through a mechanical filter and then disposed of at an
approved facility.

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Waste Water Treatment

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Travel Lift System

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Marine Railway System

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Drydock

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2.4.3 Add On Controls for


drydocks
Drydock/ground liquid
barriers

impervious barrier, may be


temporary or permanent,
prevents contact of the waste
stream with the ground or
floor of the drydock, contains
the waste stream until it can
be removed

Filter System/Barrier

barrier that filters the waste


stream as it flows from the
drydock

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2.5 Treatment Technology


No off-the-shelf technology that will reduce
TBT levels in water to below safe-levels (less
than 30-50 parts per trillion, ie 50ng/l)
Unproven technology such as Dissolved Air
Floatation, and Activated Carbon Adsorption
are the best candidates to destroy TBT in waste
streams
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2.6 Alternates
Alternative processes include the use
of oxidizers (hydrogen peroxide and
ozone) and the use of UV light to
degrade TBT in wastewaters
Heat agitation and organic solvents
to separate TBT from water are also
used.
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2.7 Treatment with


activated sludge
TBT

will attach to organic material and bind


loosely.
Treats

up to 20 tonnes of effluent per hour.


Concentrating the TBT into a small volume of oil
which can be safely incinerated or re-used.
Industrial

waste streams from shipyards have


measured TBT levels as high as 480,000 ng/L,
which is known to be sufficient to kill the
bacteria in activated sludge (Argaman et al,
1984)
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2.8 Floating Treatment Plant


System developed
in 1999
Waste separation
and carbon treatment
TBT < 50 ng/l

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3.1 Summary Removal


Methods

Removal of paint and fouling

organisms can be performed in a


number of ways

Abrasive Grit
High pressure Hydroblasting
Ultra high pressure Hydroblasting
Mechanical removal (scraping)

What is the best way?


Ultra high pressure is currently
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Thail
recommended

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3.2 Summary
Treatment/Disposal
Waste treatment is possible at high
cost
Treat to the level that can be
achieved practically and
economically
Good housekeeping is the key to
waste reduction.
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3.3 Summary
Contamination Sources

Fouling organisms- living and dead


Paint Chips
Grit
Spraying

Reduction of waste and treatment


Use Best Management Practice for source
reduction, collection and treatment
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4 Summary
REMEMBER

Keep it practical and safe for workers


Containment: primary step in waste management
Recycling: further step in reduction of waste and
overall cost for treatment/disposal
Untreated hazardous waste TBT and other
biocidal paint chips: special waste to land sites or
treated by purpose built systems

THANK YOU

Bangkok, Thail

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