Beruflich Dokumente
Kultur Dokumente
Chapter 24
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24.1
Classification of Hydrocarbons
24.1
Alkanes
Alkanes have the general formula CnH2n+2 where n = 1,2,3,
only single covalent bonds
saturated hydrocarbons because they contain the
maximum number of hydrogen atoms that can bond with the
number of carbon atoms in the molecule
CH4
C2H6
C3H8
methane
ethane
propane
24.2
24.2
n-pentane
CH3 H
2-methylbutane
CH3 H
CH3 H
2,2-dimethylpropane
24.2
Alkane Nomenclature
1. The parent name of the hydrocarbon is that given to the
longest continuous chain of carbon atoms in the molecule.
CH3
CH3
1
CH2
2
CH2
3
CH
4
CH2
5
24.2
CH4
methane
CH3
methyl
CH2
6
CH3 4-methylheptane
7
Alkane Nomenclature
24.2
Alkane Nomenclature
3. When one or more hydrogen atoms are replaced by other
groups, the name of the compound must indicate the
locations of carbon atoms where replacements are made.
Number in the direction that gives the smaller numbers for
the locations of the branches.
CH3
CH3
1
CH
2
CH2
3
CH2
4
CH3
5
CH3
2-methylpentane
CH3
1
CH2
2
CH2
3
CH
4
CH3
5
4-methylpentane
24.2
Alkane Nomenclature
4. Use prefixes di-, tri-, tetra-, when there is more than one
alkyl branch of the same kind.
CH3
1
CH3
CH3
CH
CH
CH2
CH2
CH3
2,3-dimethylhexane
CH3
CH3
1
CH
2
CH2
4
CH2
5
CH3
6
CH3
3,3-dimethylhexane
24.2
Alkane Nomenclature
5. Use previous rules for other types of substituents.
CH3
1
Br
NO2
CH
CH
CH3
4
2-bromo-3-nitrobutane
Br
CH2
1
NO2
CH2
2
CH
3
CH3
4
1-bromo-3-nitrobutane
24.2
CH
C2H5
CH2
CH
4
CH2
5
CH2
6
CH2
7
CH3
8
2-methyl-4-ethyloctane
What is the structure of 2-propyl-4-methylhexane?
C2H5
CH3
1
CH
2
CH3
CH2
3
CH
4
CH2
5
CH3
6
24.2
Alkane Reactions
Combustion
CH4 (g) + 2O2 (g)
Halogenation
light
Cl2 + energy
Cl + Cl
Cl + H
H
H
C + Cl
H
H + HCl
H
Cl
C
H
Cl + Cl
24.2
achiral
chiral
24.2
Cycloalkanes
Alkanes whose carbon atoms are joined in rings are called
cycloalkanes. They have the general formula CnH2n where n =
3,4,
24.2
Cycloalkanes
24.2
Alkenes
Alkenes have the general formula CnH2n where n = 2,3,
contain at least one carbon-carbon double bond
also called olefins
CH
CH2
CH2
CH3
CH3
CH
1-butene
Cl
Cl
C
Cl
H
C
cis-dichloroethylene
CH3
2-butene
C
H
CH
C
Cl
trans-dichloroethylene
24.2
24.2
Alkene Reactions
Cracking
C2H6 (g)
Pt
catalyst
CH2
Addition Reactions
CH2
CH3
CH2
CH2Br
CH2Br (g)
CH2Br (g)
24.2
Alkynes
Alkynes have the general formula CnH2n-2 where n = 2,3,4,
contain at least one carbon-carbon triple bond
CH
CH2
1-butyne
CH3
CH3
CH3
2-butyne
Production of acetylene
CaC2 (s) + 2H2O (l)
24.2
Alkyne Reactions
Hydrogenation
CH
CH (g) + H2 (g)
CH2
CH2 (g)
Addition Reactions
CH
CH2
CH
CHBr
CH
CHBr2
CHBr (g)
CHBr (g)
CHBr2 (g)
24.2
Aromatic Hydrocarbons
H
H
C
C
C
H
H
C
C
C
C
C
C
24.3
aminobenzene
NH2
Cl
chlorobenzene
3
4
nitrobenzene
Br
Br
NO2
Br
Br
1,2-dibromobenzene
1,3-dibromobenzene
24.3
Br
H
+ Br2
H
FeBr3
catalyst
+ HBr
H
CH2CH3
H
+ CH3CH2Cl
H
H
H
H
AlCl3
catalyst
+ HCl
H
H
H
24.3
24.3
24.4
enzyme
H2SO4
CH3CH2OH (g)
alcohol dehydrogenase
CH 3CHO + H2
24.4
H2SO4
catalyst
CH3OCH3 + H2O
24.4
H C H
H C CH3
H3C C CH3
formaldehyde
acetaldehyde
acetone
24.4
24.4
24.4
CH3CH2NH2 + HCl
RNH3+ + OH-
CH3CH2NH3+Cl-
24.4
24.4
Crude Oil