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THE IDEAL GAS

LAW
Rivera, John Mark
Cabanting, Ernz

Padilla, Carmella Joice


Galicha, Calixto Abian

Rabonga, Jhon Mark

Viterbo, Kim Harold

Alcanzare, Io Samm

Zabala, Emerson

Pinoon, Romeo Jose

Ibrahim, Rijal

Castulo, Kane Matthew

Abad, Alexandra

IDEAL GASES
It

does not condense into a liquid


when cooled.
obeys totally the ideal gas law
over its entire P-V-T range
molecules have negligible
intermolecular attractive forces
and they occupy a negligible
volume compared with the
container volume.

In reality, there are no gases that


fit these definitions perfectly. We
assume that gases are ideal to
simplify our calculations.

IDEAL GAS EQUATION


It

is the approximate equation of


state of any gas, and becomes
increasingly exact as the
pressure of the gas approaches
zero.

PV=nRT

PV=nRT
Where:
P = pressure
n = number of
moles
V = volume
T = temperature
J
L atm
R = gas constant
which is

8.314

K mole

0.08206

K mole

Pressure
Defined as force divided by the area
to which the force is applied.
The greater the force acting on a
given area, the greater the pressure
1 bar is the standard pressure
Temperature
- The property that indicates the
direction of the flow energy through
a thermally conducting, rigid wall.

The Kelvin-temperature scale


Lord Kelvin all
temperature/volume plots
intercepted the tc axis at
-273.15C).
Kelvin termed this absolute 0
the temperature where the
volume of an ideal gas is 0 and
all thermal motion ceases!

The temperature scale


T (K) = [ tc (C) + 273.15C] K/C
Freezing point of water: tc = 0 C; T
= 273.15 K
Boiling point of water: tc = 100 C; T
= 373.15 K
Room temperature: tc = 25 C; T =
298 K
NOTE tc = C; T (K) = K NO DEGREE
SIGN

Standard Temperature and


Pressure (STP)
Temperature - 0.00 C = 273.15 K
Pressure - 1.000 atm
The volume occupied by 1.000 mole
of an ideal gas at STP is 22.41 L!

Standard Ambient Temperature and


Pressure
Temperature - 25.00 C = 273.15 K
Pressure - 1.000 bar (105 Pa)
The volume occupied by 1.000 mole
of an ideal gas at SATP is 24.78 L!

Recall:

V 1/P; Boyles law


V T; Charles and Gay-Lussac's law
V n; Avogadros law
P T; Amontons law

BOYLES LAW
The

gas volume/pressure
relationship
The volume occupied by the gas
is inversely proportional to the
pressure
V 1/P
note temperature and the amount of
the gas are fixed

BOYLES LAW
V

1/P

CHARLES AND GAY-LUSSACS LAW


Defines

the gas
volume/temperature relationship.
V T (constant pressure and
amount of gas)
Note T represents the
temperature on the absolute
(Kelvin) temperature scale

CHARLES AND GAY-LUSSACS LAW

V
(-273C = 0 K)

Absolute Zero

t / C

AVOGADROS PRINCIPLE
The

volume of a gas at constant


T and P is directly proportional to
the number of moles of gas
V n => n = number of moles
of gas

AMONTONS LAW
The

pressure/temperature
relationship
For a given quantity of gas at a
fixed volume, P T, i.e., if we
heat a gas cylinder, P increases!

FIN

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