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4)WATER IN NATURE
(8.4.1)Water is distributed on Earth
as a solid, liquid and gas.
(8.4.1a) Define the terms solute,
solvent and solution.
(8.4.1b) Identify the importance of
water as a solvent.
-
WATER
PHYSICAL PROPERTIES OF
WATER
Syllabus dotpoint
8.4.1i) Perform an investigation involving calculations of
the density of water as a liquid and a solid using:
Mass
Density=Volume
8.4.1ii) Analyse information by using models to account
for the differing densities of ice and liquid water.
Results
So what we should have found close to was the density of water is
approximately 1.0 g/mL (100 g of water/100 mL of water). The density of
ice is somewhere around 0.92 g/mL, less than the density of water. Our
density calculation for ice came out to be 21.0 g/23 mL, or 0.913 g/mL,
which was pretty close.
Objects such as ice, with a density of less than 1.0 g/mL, will float in water.
Objects with a density greater than 1.0 g/mL will sink in water.
Cool link to show the students densities:
https://www.youtube.com/watch?v=B3kodeQnQvU
Structure of Ice
Hydrogen Bonding
8.4.2 The wide distribution and importance of water on Earth is
a consequence of its molecular structure and hydrogen bonding
Syllabus Points
(8.4.2c) Describe hydrogen bonding between
molecules
(8.4.1iii) Plan and perform an investigation to
identify and describe the effect of antifreeze or salt on the boiling point of water
Explanations..
How do you think salt or antifreeze would affect the
boiling point of water?
Why?
http://www.youtube.com/watch?NR=1&v=aH2IbYs_XjY
Collecting data
Group
Saltwa
ter
Boiling
point
Distilled
water
boiling
point
Group
Saltwa
ter
boiling
point
Distilled
water
boiling
point
Syllabus dotpoints
8.4.1d) Outline the significance of the different states of water
on Earth in terms of water as:
-A constituent of cells and its role as both a solvent and a raw
material in metabolism.
-A habitat in which temperature extremes are less than nearby
terrestrial habitats.
-An agent of weathering of rocks both as a liquid and solid.
-A natural resource for humans and other organisms.
Syllabus dotpoint
8.4.2a) Construct Lewis electron dot
structures of water, ammonia and hydrogen
sulfide to identify the distribution of
electrons.
Bohr - 1912
Niels Bohr
+
-
Atom
AMMONIA:
Chemical formula
H2O
NH3
METHANE:
CH4
Syllabus dotpoint
8.4.2b) Compare the molecular structure of
water, ammonia and hydrogen sulfide, the
differences in their molecular shapes and in
their melting and boiling points
Syllabus dotpoint
Syllabus dotpoint
Surface tension
Water molecules at the surface of a
beaker, are not surrounded by other water
molecules in the same way as those
molecules in the centre of the beaker.
- Surface tension results from the
molecules on the surface of water (or any
liquid) having an overall attractive force
downwards into the rest of the water. This
downwards force creates a tension on the
surface of the water, so that it behaves like
a tightly stretched skin.
Water has a high surface tension
because of its ability to form many
hydrogen bonds.
Viscosity
The viscosity of a liquid is a measure
of its resistance to flow.
When a liquid flows the molecules slide over one another. If the
molecules have strong intermolecular attractions and are long and thin
and easily tangle the liquid will have a high viscosity, e.g. tar and
honey. If the molecules have weak intermolecular attractions and are
smaller then liquid has a low viscosity.
Viscosity decreases as temperature rises.
Gases have the lowest viscosity.
Viscosity relates directly to the strength of the forces between
molecules and the size of the molecules. These forces determine how
easily the molecules move past each other.
The viscosity of water is greater than many other similar liquids, e.g.
Video links
Surface tension:
http://video.mit.edu/watch/surface-tension-8413/
Viscosity:
https://www.youtube.com/watch?v=U_AnRyIxDhs
https://www.youtube.com/watch?v=977wNbFiYlc
https://www.youtube.com/watch?v=3KU_skfdZVQ
Ionic Compounds
Most ionic compounds are soluble in water
One example is sodium chloride (NaCl) which is a
soluble ionic compound which we will look at the
particle changes during dissolution.
At room temperature and standard pressure, NaCl has
a solid crystalline structure. When introduce into
liquid it looses its crystalline structure. This is because
NaCl dissociates to form Na+ and Cl- ions.
Molecular Compounds
The solubility of a molecular compound in water depends
on its polarity
Polar Molecular compounds:
Polar molcules generally souble in water
Are electrostatically attracted to the water molecules and
surrounded, resulting in dissolution. For example sucrose:
What happens:
As you can see in the picture on the last slide, sucrose
contains many O-H groups. Just like the O-H group in
water, the O-H groups in surcrose are polar and hence;
1. The O form the O-H groups will form hydrogen bonds
with the H+ from water.
2. The H+ from the O-H groups will form hydrogen bonds
with the O from water.
. When crystalline sucrose is dissolved in water, the
inthermolecular forces of sucrose are overcome by
hydrogen bonding to water
. Link:
http
Hydrogen Chloride
Hydrogen chloride is a covalent molecular gas it is very
soluble in water.
Hydrogen chloride molecules ionise when dissolved in
water:
Syllabus dotpoints
8.4.3a) Explain changes, if any, to particles and
account for those changes when the following types of
chemicals interact with water:
A covalent network structure substance such as silicon
dioxide.
A large substance with large molecules, such as
cellulose or polyethylene.
Large molecules
An example of a polymer found in nature is
cellulose:
Questions:
What is an ionic compound?
What is a covalent network molecule?
What is a polymer?
What causes these substances to be soluble or in
soluble???? Write a page worth to explain why they are
insoluble or soluble and explain what each of them are and
give me examples.
Summary picture