Universidad Autnoma de Baja

California
Facultad de Ciencias Qumica e
Ingeniera
Campus Tijuana
Reglas Heursticas (21-24)
Diseo de Procesos
Ivan Octavio Lopez Cerpa
Matricula 290077
Grupo 271
Profa. Ana Isabel Ames Lpez

Heuristic 21
To remove a highly exothermic heat of reaction, consider the use of
excess reactant, an inert diluent, or cold shots. This affect the
distribution of chemicals and should be inserted early in process
synthesis.

Para eliminar un calor de reaccin altamente exotrmico, considere el

uso de un exceso de reactivo, un diluyente inerte o tomas fras. Esto

afecta a la distribucin de productos qumicos y se debe insertar en la
sntesis temprana del proceso.

Heuristic 22
For less exothermic heats of reaction, circulate reactor fluid to an

external cooler, or use a jacketed vessel or cooling coils. Also

consider the use of intercoolers between adiabatic reaction stages.

Para calores de reaccin menos exotrmicos, circular el fluido del

reactor para un enfriador externo, o utilizar un recipiente

enchaquetado o serpentn de enfriamiento. Tambin considere el uso
de refrigeradores intermedios entre etapas de reaccin adiabticas.

Adiabatic Reaction Temperature

Heat and Material Balance Table
Stream ID

From

B1

To

B1

P hase

VAP O R

VAP O R

Substream: MIXE D
Mole Flow

lbmol/hr

CO

1.000000

H2

2.000000

0.0

0.0

1.000000

CH 3O H

0.0

Total Flow

lbmol/hr

3.000000

1.000000

Total Flow

lb/hr

32.04216

32.04216

Total Flow

cuft/hr

1176.965

2363.065

Temperature

77.00000

77.00000

P res sure

psia

14.69595

2.427121

1.000000

1.000000

0.0

0.0

Vapor Frac
Liquid Frac
Solid Frac

0.0

0.0

Enthalpy

Btu/lbmol

-15839.71

-86400.89

Enthalpy

Btu/lb

-1483.019

-2696.475

Enthalpy

Btu/hr

-47519.13

-86400.89

Entropy

Btu/lbmol-R

8.370343

-27.37661

Entropy

Btu/lb-R

.7836871

-.8543933

Dens ity

lbmol/cuft

Dens ity

lb/cuft

Average MW
Liq Vol 60F

cuft/hr

2.54893E-3 4.23179E-4
.0272244

.0135595

10.68072

32.04216

2.573741

.6460983

Heat and Material Balance T able

Stream ID

From

B1

To

B1

Phase

VAPOR

VAPOR

Subst ream: MIXED

Mole Flow

lbmol/hr

CO

1.000000

0.0

H2

2.000000

0.0

0.0

1.000000

CH3OH
T otal Flow

lbmol/hr

3.000000

1.000000

T otal Flow

lb/hr

32.04216

32.04216

T otal Flow

cuft/hr

1176.965

1881.147

T emperature

77.00000

2115.465

Pressure

psia

14.69595

14.69595

Vapor Frac

1.000000

1.000000

Liquid Frac

0.0

0.0

Solid Frac

0.0

0.0

Ent halpy

Bt u/lbmol

-15839.71

-47519.13

Ent halpy

Bt u/lb

-1483.019

-1483.019

Ent halpy

Bt u/hr

-47519.13

-47519.13

Ent ropy

Bt u/lbmol-R

8.370343

-4.033126

Ent ropy

Bt u/lb-R

.7836871

-.1258694

Density

lbmol/cuft

Density

lb/cuft

Average MW
Liq Vol 60F

cuft/hr

2.54893E-3 5.31591E-4
.0272244

.0170333

10.68072

32.04216

2.573741

.6460983

Excess Reactant

Curva Proporcion de Reactivos Vs Temperatura de Reaccion

2200
2100

TEMP

2000
1900
1800
1700

Temp F

1600
1500
1400
1300
1200
1100
1000
900
800
700
600

6
Proporcion de Reactivos NH2/NCO

10

Dodecane diluent

Heuristic 23
To control temperature for a highly endothermyc heat of reaction

consider the use of excess reactant, an inert diluent or hot shots. This
afect the distribution of chemicals and should be inserted early in
process synthesis.

Para controlar la temperatura de un calor de reaccin altamente

endotrmico, considere el uso de un exceso de reactivo, un diluyente

inerte o tomas calientes. Esto afecta a la distribucin de productos
qumicos y se debe insertar en la sntesis temprana del proceso.

Heuristic 22
For less endothermic heats of reaction, circulate reactor fluid to an

external heater, or use a jacketed vessel or heating coils. Also

consider the use of interheaters between adiabatic reaction stages.

Para calores de reaccin menos endotrmicos, circular el fluido del

reactor para un calentador externo, o utilizar un recipiente

enchaquetado o serpentn de calentamiento. Tambin considere el uso
de calentadores intermedios entre etapas de reaccin adiabticas.