Beruflich Dokumente
Kultur Dokumente
Chapter 7- 1
+ + + + + + + +
+ + + + + + + +
+ + + + + + + +
ion cores
Covalent Ceramics
(Si, diamond): Motion hard.
-directional (angular) bonding
Ionic Ceramics (NaCl):
Motion hard.
-need to avoid ++ and -neighbors.
Chapter 7- 2
DISLOCATION MOTION
Produces plastic deformation,
Depends on incrementally
breaking
Ifbonds.
dislocations don't move,
deformation doesn't happen!
Plastically
stretched
zinc
single
crystal.
Chapter 7- 3
BondsareCompressed
BondsareStretched
WHYisthereastressfield?
Atomstrytorelaxbytryingtoachieve
theirpositionsforthecaseiftherewas
notadislocationinthevicinity!
Chapter 7-
Chapter 7-
HallPetchEquation:
grain A
yield o k yd1/2
Chapter 7- 7
yield o k yd1/2
grain size, d (mm)
y ie ld (M Pa )
200
0.75mm
10-1
10-2 5x10-3
150
ky
100
1
50
0
0
12 16
impurity
C
B
D
Impurity generates local shear
at C and D that opposes disl
motion to the right.
Chapter 7- 11
COMPRESSIVE
TENSILE
TENSILE
Chapter 7COMPRESSIVE
Chapter 7-
Impurity Segregation
Impurities tend to
segregate at energetically
favorable areas around
the dislocation core and
partially decrease the
overall stress field
generated around the
dislocation core.
However, when stress is
applied more load is
needed to move
dislocations with impurity
atoms segregated to its
core !
Chapter 7-
Strengthening by Alloying
impuritiestendtoconcentrateatdislocationsto
reducemobilityofdislocationincreasestrength
Chapter 7-
400
300
200
0 10 20 30 40 50
wt. %Ni, (Concentration C)
Yie ld s tre n g th (M Pa )
Te n sile stre n g th (M Pa )
60
0 10 20 30 40 50
wt. %Ni, (Concentration
y ~C
1/2
Chapter 7- 12
3. PRECIPITATION STRENGTHENING
Hard precipitates are difficult to shear.
Ex: Ceramics in metals (SiC in Iron or Aluminum).
precipitate
Large shear stress needed
to move dislocation toward
precipitate and shear it.
Side View
Top View
S
Slipped part of slip plane
1
y ~
S
Dislocation
advances but
precipitates act as
pinning sites with
spacing S.
Chapter 7- 13
SIMULATION:
PRECIPITATION STRENGTHENING
View onto slip plane of Nimonic PE16
Precipitate volume fraction: 10%
Average precipitate size: 64 b (b = 1 atomic slip
distance)
Chapter 7- 14
APPLICATION:
PRECIPITATION STRENGTHENING
Internal wing
structure on
Boeing 767
Aluminum is
strengthened with
precipitates formed
by alloying.
1.5m
Chapter 7- 15
Room temperature
deformation.
-Forging
-Drawing
force
die
die
A o blank
Ad Ao
Ad
tensile
force
die
force
-Rolling
roll
Ao
roll
-Extrusion
Ao
Ad
force
container
ram
billet
container
die holder
extrusion
Ad
die
Chapter 7- 16
Dislocations entangle
with one another
during cold work.
Hence Dislocation
motion becomes more
difficult.
Dislocation density (d)
Carefully prepared sample:
0.9 m
d ~ 103 mm/mm3
Heavily deformed sample:
d ~ 1010 mm/mm3
Chapter 7- 17
DISLOCATION-DISLOCATION TRAPPING
Dislocation generate stress.
This traps other dislocations.
Red dislocation
generates shear at
pts A and B that
opposes motion of
green disl. from
left to right.
Chapter 7- 20
Chapter 7-
Stress
Temperature Dependence of
S tre s s (M P a )
800
600
-200C
polycrystalline iron
-100C
400
25C
200
0
0
0.1
0.2
0.3
Strain
0.4
0.5
3 . disl. glides past obstacle
2. vacancies
replace
atoms on the
disl. half
plane
obstacle
1. disl. trapped
by obstacle
Chapter 7- 23
ANNEALING
SOFTENNG OF COLD WORK METALS by HEATING
3
Annealing
stages
100
300
600
500
700 60
tensile strength
50
500
40
30
400
ductility
300 R
ec
ov
Re
c
er
y
20
ry
st
a
lli
Gr
ai
n
za
t
io
n
ductility (%EL)
Gr
ow
th
Chapter 7- 24
RECOVERY
(Annihilation of dislocations and vacancies)
Scenario 1
Results from
diffusion
extra half-plane
of atoms
atoms
diffuse
to regions
of tension
extra half-plane
of atoms
Dislocations
annihilate
and form
a perfect
atomic
plane.
Scenario 2
3. Climbed disl. can now
move on new slip plane
2. grey atoms leave by
vacancy diffusion
allowing disl. to climb
1. dislocation blocked;
cant move to the right
R
4. opposite dislocations
meet and annihilate
Obstacle dislocation
Chapter 7-
RECRYSTALLIZATION
New crystals nucleate and grow to consume the coldworked structure, i.e., dislocations due to cold work will
disappear.
0.6 mm
0.6 mm
New crystals
nucleate after 3 sec.Chapter 7- 26
at 580C.
FURTHER RECRYSTALLIZATION
All cold-worked crystals are consumed.
0.6 mm
After 4
seconds
0.6 mm
After 8
seconds
Chapter 7- 27
Rate of Recrystallization
E
logR logt logR0
kT
B
logt C
T
note : R 1 / t
start
1
TR
50%
finish
log t
HotworkaboveTR
ColdworkbelowTR
Smallergrains
strongeratlowtemperature
weakerathightemperature
NoStrainhardeningoccurs
TR~0.3Tm0.7Tm
TRdependson%CW Chapter 7Decreasewithincreasing%CW
GRAIN GROWTH
At longer times, larger grains consume smaller ones.
To reduce the Grain boundary area (and therefore energy)
0.6 mm
0.6 mm
After 8 s,
580C
After 15 min,
580C
n~ 2
grain diam.
at time t.
d d Kt
n
n
o
elapsed time
coefficient dependent
on material and T. Chapter 7- 28
SUMMARY
Dislocations are observed primarily in metals and
alloys.
Strength is increased by making dislocation motion
difficult.
Particular ways to increase strength are to:
--decrease grain size
--solid solution strengthening
--precipitate strengthening
--cold work
Heating (annealing) can reduce dislocation density
and increase grain size to soften the cold worked metal.
Chapter 7- 29