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Ethomeen C12
and CO2 Foam in
Sandpack:
2
Chen, Y. et al., 2013. SPE-154222-
1% C12 in brine
(22% TDS):
Na+: 71720 ppm
Ca2+: 21060 ppm
Mg2+: 3063 ppm
Cl-: 156777 ppm
4
Differential scanning
calorimetry (DSC)
and thermal
gravimetric analysis
(TGA) shows the
surfactant is stable at
T<150 C
DSC
150
C
Lack of water!
Thermal Stability of
Ethomeen C12
Oxygen
!
Adsorption of C12 on
Potential Formation Minerals
(Cui, et al., 2014, SPE169040-MS)
10
CO2 should be
saturated with
water before
injected
90% foam
quality
12
Influence of Salinity
Salinity can stabilize foam by increasing the packing
density of surfactants on water-gas interface and destabilize
foam by decreasing the electric repulsion of double layers in
film plateau.
Disjoining pressure can be utilized to explain the salinity
influence.
The increases with electrolyte
13
Salinity: Stabilization
Salinity in synthetic brine is favorable for C12 and
CO2 foam strength.
Salinity in synthetic brine is around the optimal
salinity
14
15
16
17
Thank you.
We acknowledge financial support from the Abu Dhabi
National Oil Company (ADNOC), and the Petroleum
Institute (PI), U.A.E and partial support from the US
Department of Energy (under Award No. DEFE0005902)
19
Backup
20
Isobaric Heating
1200 psi, 82
C
Joule-Thomson
Expansion
14 .5psi, 15 C
*Good plant design and operation for onshore carbon capture installations and onshore pipelines, Energy21
Institute, 2010 09,
Purple asterisks
and line display
the linear relation
between IEP and
log10(pCO2))
22
Calcite-H2O-CO2 System
9 species were constrained by 5 reactions in 3 phases.
Reaction
Equilibrium Constant
-log10
(K) at 25 C
10
8.42
8.42
1.47
1.47
6.35
10.33
10.33
14.0
14.0
23
Isoelectric Calcium
Concentration
At a fixed T and zero zeta potential,
the freedom degree is 1.
the isoelectric pH* is determined by
the partial pressure of CO2 as well.
log()= -1.71
pH*+11.2
The
isoelectric calcium
concentration is used to
determine the zeta potential:
1.E+00
1.E-01
1.E-02
Ca2+ Concentration
(mol/L)
1.E-03
1.E-04
1.E-05
0
50
100
150
200
Partial Pressure of CO2 (atm)
250
24
Sand
Solvent
2
2
2
Calcite
Calcite
Calcite
Water
Brine
Brine
2
2
Dolomite
Dolomite
Water
Water
(atm)
2
2
Dolomite
Dolomite
Brine
Brine
Activity at Zeta
Activity in Test
Potential=0 (mol/L)
(mol/L)
-4
4.710-4
-4
4.710
4.710-4
-4
3.1610
3.1610-4
#
#
-4
3.1610
3.1610-4
#
#
0
0
0 -4
#
#6.3110-4
6.3110
-4
6.3110
6.3110-4
#
#
-3
5.610-3
0
-1
-1
5.010
-1 2.210-1
5.010 2.210
-3
-3
3.210
-3 3.310-3
3.210 3.310
-1
-1
5.010
5.010-1 2.210
2.210-1
25
in DI
water
in brine
26
Surface Chemistry
X-ray Photoelectron
Spectroscopy (XPS) indicates
(Ma, et al., 2013)
Adsorption of C12 on
Silica
Na+ doesnt affect the
adsorption.
Multivalent cations, i.e.,
Mg2+, Ca2+ and Al3+, can
reduce the adsorption.
The effectiveness for
adsorption reduction
depends on the cations
type.
Al3+ (mol/L)
Ca2+ (mol/L)
Mg2+(mol/L)
Na+ (mol/L)
DI
0
0
0
0
in DI water
in NaCl
in MgCl2
Adsorption at the plateau (mg/m2)
NaCl
0
0
0
5.08
MgCl2
0
0
1.69
0
in Brine
Brine+AlCl3
Brine
0
1.5110-3
5.2510-1 5.2510-1
1.2610-1 1.2610-1
3.12
3.12
28
Magnesiu
m
Adsorption Reduction (mgL)/(m2mol)=10-3 (mgm)/mol
Calcium
Aluminiu
m
29
Adsorption of C12 on
Silica
Na+ doesnt affect the
adsorption.
Multivalent cations, i.e.,
Mg2+, Ca2+ and Al3+, can
reduce the adsorption.
The effectiveness for
adsorption reduction
depends on the cations
type.
Al3+ (mol/L)
Ca2+ (mol/L)
Mg2+(mol/L)
Na+ (mol/L)
DI
0
0
0
0
in DI water
in NaCl
in MgCl2
Adsorption at the plateau (mg/m2)
NaCl
0
0
0
5.08
MgCl2
0
0
1.69
0
in Brine
Brine+AlCl3
Brine
0
1.5110-3
5.2510-1 5.2510-1
1.2610-1 1.2610-1
3.12
3.12
30
Adsorption
type.
Adsorption in NaCl solution is used as a reference for zero
adsorption reduction, i.e., , because of the same ionic strength
as other electrolyte.
31
32
Salinity:
Destabilization
33
Mineral Dissolution
The carbonate mineral was dissolved in DI water and CO2.
The sufficient divalent cations, i.e., Ca2+ and Mg2+, are
suggested to be added in brine.
34
35
pH in Foam Flooding
Bromocresol Green
(BCG): pH<3.1 yellow,
pH=3.1-4.1 green,
pH>4.1 blue in the
presence of C12.
The measured pH in
foam flooding was 3.14.1, which is consistent
with calculated
equilibrium pH=4.0
Ethomeen C12 is watersoluble during CO2 foam
flooding.
36
10
3
TPV
1000
3
TPV
1000
70% Foam
Quality
Apparent Viscosity / cp
100
co80% Foam
injection / cp *=65.72
Apparent Viscosity
Quality cp
100
*=139.98 cp
10
1
co50% Foam
injection
*=118.30 cp
Quality
Apparent Viscosity / cp
100
1000
10
3
TPV
0.5
1.5
2.5
TPV
3.5
4.5