Beruflich Dokumente
Kultur Dokumente
CHEMICALS:
Acetone
Water
EXPERIMENTAL PROCEDURE:
Prepare a mixture of 250 ml acetone and 60 ml water in a 500 ml
beaker.
S.NO TIME TEMPERATURE (C) REMARKS S.NO TIME TEMPERATURE (C) REMARKS
TOP BOTTOM TOP BOTTOM
1 10:38 34 34 HEATER ON 19 12:42 73 81 CUT 7
2 10:43 35 36 20 12:47 68 80
3 10:48 49 43 21 12:53 72 81
4 10:53 53 47 CONDENSATI
22 13:42 80 92
ON START
23 13:49 78 88 CUT 8
5 10:58 57 50 CUT 1
24 13:54 84 90
6 11:03 59 56
7 11:07 61 57 CUT 2 25 14:01 86 94 CUT 9
8 11:12 60 58 26 14:08 84 92
9 11:17 60 58 27 14:13 87 94 CUT 10
10 11:20 62 59 CUT 3 28 14:20 84 93
11 11:28 60 61 29 14:25 81 91
12 11:33 61 62 30 14:31 87 94
13 11:37 64 63 CUT 4
31 14:39 89 99 CUT 11
14 12:00 64 66 CUT 5
32 14:46 88 94
15 12:13 64 69
16 12:23 69 77 CUT 6 33 14:51 89 100
17 12:27 68 75 34 14:56 90 100 CUT 12
18 12:32 67 73 35 15:02 96 97 CUT 13
Analysis from Gas chromatograph:
S.NO. TEMPEARTURE DISTILLATE COMPOSITION RESIDUE COMPOSITION
(C) (%) (%)
WATER ACETONE WATER ACETONE
CALCULATIONS:
Antoine parameters:
A B C
Water 8.07131 1730.63 233.7912
Acetone 7.6313 15566.69 273.419
Total pressure: Ptot = 760 mm of Hg
Partial pressure at saturation temperature T from Antoine equation:
logPsat = A-B/(T+C)
Using Raoults law:
Xacetone = Yacetone* Ptot/Psat
T-x
T-y
vapor- liquid
equilibrium curve
x=y line
APPLICATIONS
LUBE OIL:
Lube oils are a blend of base oil and additives.
Typically lube oil contains 90% base oil (most often
petroleum fractions) and less than 10% additives.
RE-REFINING PROCESS
The re-refining process restores used lube oil to its original
condition as base oil. The lubricating properties of the oil are
not compromised by use or re-refining.
Re-refining is an energy efficient and environmentally beneficial method
for managing used oil. Instead of burning the used oil, which releases
harmful emission into the atmosphere, re-refining conserves the base oil.
EXPERIMENTAL PROCESS
UTILITIES:
Chiller
Cooling Tower
Vacuum pump
Vertical thin film evaporator
Thermic fluid ( Therminol) heater with circulation tank
STAGE 1:
DEHYDRATION ON VERTICAL THIN FILM EVAPORATOR
EXPERIMENTAL CONDITIONS
FEED: Used Oil
Thermic fluid temperature:120C ,Vacuum:300 mmHg, Shaft rotation: 300 Rpm
Typical internal accessories include trays, packing, liquid distributors, redistributors, collectors, bed limiters, mist eliminators.
I.TRAYS
II.PACKINGS
Trays and packing are installed in the column for efficient vapour liquid contact.
TYPES OF VAPOUR-LIQUID CONTACT
EQUIPMENT
TRAYS PACKINGS
Tray columns can handle wide range Packed are more suitable for low
of gas and liquid flow rates. capacity operations
Trays are used for fouling liquid and For separating heat sensitive
for liquids with solid deposition, materials packed columns are useful.
even the tray is blocked up, it is
easier to clean it and manholes can
be provided over the plate.
A good packing material is one that provides a high surface area per volume
The material of construction must provide a high liquid flow capacity through
it to ensure a uniform liquid layer (good wettability) as well as good
resistance to pressure .
STRUCTURED PACKING:
Saddle-Rings N-Rings
STRUCTURED PACKING RANDOM PACKING
Useful for times when we dont have Used if the packing is a consumable/
a lot of pressure drop to play with wearable packing that needs
.e.g ; vacuum service. replacing regularly.
It has more number of stages per It is cheaper, but will contain voids
packed height, which reduces the which may reduce structural
total height of the column required, performance. Also it has less number
thus reducing the cost of material in of stages per packed height, thus
construction. increasing the height of the column.
LIQUID DISTRIBUTORS AND REDISTRIBUTORS
Packing whether random or structured, serves the basic purpose of
providing intimate contact between vapor and liquid in mass
transfer operations. But for effective and efficient performance of
packing some peripherals are needed.
1.Pressure distributors
2.Gravity Distributors: a) Weir Type b)Orifice Plate Type
CHANNEL TYPE DISTRIBUTOR BAFFLE TYPE DISTRIBUTOR SPIRAL TYPE DISTRIBUTOR
For large columns and heavy duty distillation columns, the static
weight of packed bed combined with liquid column is quite high.
Strong construction of packing support is needed.
BED LIMITERS
VANE TYPE