Unit 5: Chemical Kinetics

Day 7: Kinetics Lab

Warm Up
Absorbance = 3.5E-3*(Conc.) + 0.2
Use the equation above to solve for
concentration in the table below
ABSORBANCE CONCENTRATION
(mol/L)
0.87
0.75
0.43
Warm Up 2-23
Absorbance = 3.5E-3*(Conc.) + 0.2

Hint: Rearrange Equation

ABSORBANCE CONCENTRATION
(mol/L)
0.87
0.75
0.43
Warm Up 2-23
Absorbance = 3.5E-3*(Conc.) + 0.2

Hint: Rearrange Equation

ABSORBANCE CONCENTRATION
(mol/L)
0.87
0.75
0.43
Agenda
Review Design and Procedure
Finish Lab

Looking Ahead
Mon 2/27: Mr. Melton will be here
AP Chemistry Review Questions
WebAssign
Book Problems
Wed 3/1: End of Class - Unit 6 Quiz
TAKE OUT: Part A: Rate of
Reaction of CV+ with NaOH

SHARE: With your lab partner

TIME: 3 MINUTES
 Kinetics of Crystal Violet
Fading

BIG IDEA:
The more color,
the more
concentrated,
the more
absorbance.
Absorbance =
Concentration
Kinetics of Crystal Violet Fading
Guided Inquiry Design and Procedure
Part A
CV+ + OH- CVOH

What percent of OH- ions will remain at the end

of a reaction if the initial concentrations of
each reactant were equal (1:1 ratio)? (1:1000)?
Kinetics of Crystal Violet
Fading
Review:

CV+ + OH- CVOH

purple colorless

Rate = k[CV+]m [OH-]n

Kinetics of Crystal Violet
Fading
Rate Law:
Rate = k [CV+]m
where k = k [OH-]n
The constant k is a new pseudo rate constant.
The new pseudo rate law is valid when the
concentration of OH- ions is much greater than the
concentration of CV+ ions. Under these conditions,
the [OH-] term in the original rate law will not
change much over the course of the reaction and
may be treated as a constant in the rate equation.
Part B: Procedure Outline
1. NaOH conc. needs to be changed, not CV +, so that the
effect on k can be calculated and the order of reaction
with respect to OH- determined
2. Colorimeter must be zeroed with a blank, equal volumes
0.01 M NaOH and water
3. To make 10 mL of 0.01 M NaOH, measure 5.0 mL of 0.02
M NaOH in a serological pipet and
4. Clean the pipet with small portions of crystal violet
solution. Measure 10 mL of 25 uM crystal violet
solution
5. After the absorbance vs. time data are recorded, the
absorbance values need to be converted into
concentration, then separate data columns for ln[CV +]
and 1/[CV+] need to be created and analyzed to
determine k for the new concentration of NaOH, 0.01 M.
Part B: Procedure Outline
1. After the absorbance vs. time data are recorded, the
absorbance values need to be converted into
concentration, then separate data columns for ln[CV+]
and 1/[CV+] need to be created and analyzed to
determine k for the new concentration of NaOH, 0.01
M.