he Blast Furna

What is a Blast Furnace?

The purpose of a blast furnace is to

reduce and convert iron oxides into
liquid iron called "hot metal".
The blast furnace is a huge, steel stack
lined with refractory brick.
Iron ore, coke and limestone are put
into the top, and preheated air is
blown into the bottom.
 Why does Iron have to be extracted
in a Blast Furnace???

Iron can be extracted by the blast furnace because it

can be displaced by carbon.
This is more efficient method than electrolysis
because it is more cost effective
The fact that iron-oxide can be reduced by carbon
along with the abundance of iron-oxide in earths crust
(4th most abundant element), makes iron so
economical
 The Method
Three substances are needed to enable to extraction of iron from its ore. The combined
mixture is called the charge.
Iron ore, haematite - Fe2O3 often contains impurities such as sand (SiO2)
Limestone (calcium carbonate).
Coke - mainly carbon
The charge is placed in the blast furnace. The blast furnace is around 30 metres high and
lined with fireproof bricks. Hot air is blasted through the bottom.
 Principle reactions of iron-making

Oxygen in the air reacts with coke to give carbon dioxide:

C(s) + O 2(g) CO2(g)

The limestone breaks down to form carbon dioxide:

CaCO3(s) CO2 (g) + CaO(s)

Carbon dioxide produced in 1 + 2 react with more coke to produce

carbon monoxide:

CO2(g) + C(s) 2CO(g)

The carbon monoxide reduces the iron in the ore to give molten iron:

3CO(g) + Fe2O3(s) 2Fe(l) + 3CO2(g)

The limestone from 2, reacts with the sand to form slag (calcium silicate):

CaO(s) + SiO(s) CaSiO3(l)

Other slag forming reactions also occur

IRON MAKING IS THUS A REDUCTIVE PROCESS

 Sections of a blast furnace
Main sections are (from bottom to top)
Hearth
Bosch
Stack
Charging is done through the top
The tuyeres through which hot air is blasted are
situated at the joining of bosch and hearth
A slaghole and a taphole is provided at the
hearth
 Outline of operation
The burden is charged in layers
One layer comprises coke and the other one is iron ore+flux
and so on
A bed of coke is maintained in the tuyere region all the time
The hot air blasted through the tuyeres, reacts with the coke,
burning them, and produces carbon monoxide
This zone experiences the highest temperature (1800-2000 C)
because combustion takes place here
The hot gases generated rise through the furnace and gives
up its sensible heat to the charge that is filling the stack
column
 Outline of operation
As the gas rises its temperature drops because its heat is
taken away by the charge.
A temperature gradient is created, and so the temperature is
highest at the tuyere region and lowest at the top
The alternately charged burden thus, experiences different
temperatures depending on where it is located in the
furnace
The level of the entire burden periodically drops as metal
and slag are tapped from the bottom
This means that burden charged at the top (where T is low)
gradually experiences higher T as it drops periodically
 Outline of operation
When it drops sufficiently and the temperature is suitable, iron-oxide
reduction begins
As it drops further the ore is eventually fully reduced to metallic iron and
thereafter picks up some extra carbon (carburization this also lowers the
melting point of solid iron)
At some point the temperature is high enough to cause melting and the
metallic drops trickle through the bed of coke and so does the liquid slag,
which has formed by now
The molten liquids finally settle at the hearth where slag and metal forms
separate layers due to their specific gravity being different
The coke that was charged from the top does not take part in any significant
reaction until it reaches the tuyere region
Here it joins the coke bed already present and serves to replenish it, which is
continually burning
Detailed reactions (see figure on next page)

Logical order of reactions (Note: these reactions DO NOT occur

in the same place. They occur in different parts but reaction
products of one reaction may take part in another one)
1. Burning of coke
2. Reduction, carburization and melting of iron oxides by gas
produced in 1
3. Decomposition of limestone by heat generated from 1
4. Slag formation by reactants made available from 2 and 3
5. Slag dissociation (reverse of 4)
6. Reduction reactions made possible because of 5
7. Impurity pick up due to reactions in 6
1. Iron ore + limestone sinter
2. Coke
3. Elevator
4. Feedstock inlet
5. Layer of coke
6. Layer of sinter pellets of ore and limestone
7. Hot blast (around 1200 C)
8. Removal of slag
9. Tapping of molten pig iron
 About the stoves
Something that increases the thermal efficiency of the furnace greatly is the use of gas
coming out of the furnace itself (Blast burnace gas-BFG)
This gas contains some percentages of unburnt CO (~20%), and so can be used as a fuel
This gas is burnt inside the cowper stoves (which works like regenerators) heating them
up
Once heating is complete, BFG is shut off and fresh air is then passed through the hot
stoves
This heated air is then sent to the furnace which we have referred to as the hot blast
before
When the T of the stove drops too much fresh air is shut off and fuel is passed again
Thus one stove cannot continuously supply hot air, because it works in a cyclic heating-
cooling operation
In fact three or more stoves are generally required because the time it takes to heat up
one stove is not the same as the time it takes to cool it
So two stoves would be inadequate and a third would be needed