Beruflich Dokumente
Kultur Dokumente
Env-E-503
Dr.Amir Farooq
Skeletal Fluorosis
Dental Fluorosis
Pathological Effects of Heavy Metals on Humans
METALS PATHOLOGICAL EFFECTS
Mercury Abdominal pain, headache, diarrhea, henolysis,
chest pain.
Lead Anemia, vomiting, loss of appetite, convulsions,
damage of brain, liver & kidney.
Arsenic Disturbed peripheral circulation, mental disturbance,
liver cirrhosis, hyper kurtosis, lung cancer, ulcers in
gastrointestinal tract, kidney damage.
Cadmium Diarrhea, growth retardation bone deformation,
kidney damage, testicular atrophy, anemia, injury of
central nervous system and liver, hypertension.
Copper Hyper tension, uremia, coma, sporadic fever
METALS PATHOLOGICAL EFFECTS
Barium Excessive salivation, vomiting, diarrhea,
paralysis, colic pain
Zinc Vomiting, renal damage, cramps
Bacteria
Viruses
Protozoa
Algae
Fungi
Worms
Tape Worm Hook Worm
The most common form Liver flukes make their Another common type of
that can be found in the home in the human body worm that can make its
human body. Pinworms where they attack the home in the human body is
live inside the colon but liver and make holes. the roundworm. Infected
leave to lay their eggs on They can survive for soil or fruits are the main
the outside of the host's decades. There is a wide method of transmission
body, typically at night in a variety of methods of to humans. Unlike most
location the host will becoming infected by a other worms, Roundworm
reflexively scratch, thus liver fluke, including eggs can find their way
transporting the eggs to eating contaminated from the intestines to
infect a new person, or food, or drinking other organs where they
reinfect the host. contaminated water can do major damage.
Round Worm Found Way to Eye
Human Botfly larvae
SEWAGE FLOW / QUANTITY
Where;
P = Population in thousand.
M = Peak Factor
VARIATIONS IN SEWAGE FLOW (Cont.)
The raw sewage must be treated prior its disposal in water body
Degree of treatment depends upon following consideration
Purposes of Treatment
a) Physical Characteristics
Solids Determination
Total Solids
TS = Suspended Solids (SS), Settle-able Solids and the Diss. Solids
Determine by evaporating a known volume or weight of sewage
sample and weighing the residue.
Expressed in mg/l.
Settle-able Solids help in selection of treatment process design and
operation.
Volatile Solids(VSS)
Fresh sewage has a slightly ---------oily odour, which does not have
objectionable smell.
Gives objectionable smell when the sewage become septic releases
Hydrogen Sulphide (H2S).
Temperature
Colour
Fresh sewage has a grey colour
As sewage becomes septic the colour changes to
black.(Decomposition of OM)
b) Chemical Characteristics
1. Inorganic chemicals.
2. Gases
3. Organic
1. Inorganic Chemicals
i. pH.
ii. Acidity,
iii. Alkalinity
iv. Chlorides,
v. Nitrogen and
vi. Sulfur
vii. heavy metals
i) pH
Indicates acidic or alkaline condition of water.
Expressed on a scale ranging from 0 to 14, Common logarithm of the
reciprocal of the hydrogen ion concentration.
Plays an important role in WWT & Operation of treatment plant.
ii) Acidity
Acidity of WW is a measure of its capacity to neutralise bases.
Acidity in water may be caused by the presence of uncombined carbon
dioxide, mineral acids and salts of strong acids and weak bases.
Acidity in WW may due to addition of industrial discharges
It is expressed as mg/l in terms of calcium carbonate.
iii) Alkalinity
Alkalinity is a measure of capacity WW to neutralise acids.
It is expressed as mg/l in terms of calcium carbonate. Forms include
(a) hydroxide alkalinity,
(b) carbonate alkalinity,
(c) hydroxide plus carbonate alkalinity,
(d) carbonate plus bicarbonate alkalinity, and
(e) bicarbonate alkalinity,
Alkalinity is an important parameter in evaluating the optimum
coagulant dosage.
Ordinary sewage is slightly alkaline.
Treatment of wastewater require alkaline conditions.
iv) Chlorides
Sources - Human and animal urine.
High concentrations indicate addition of industrial WW in the sewage.
v) Nitrogen
Nitrogen in wastewater may exist in five (05) forms
a) Ammonia Nitrogen (free ammonia due to decomposition of
organic matter.)
b) Ammonia Nitrogen (Albuminoid which is measure of
decomposable Proteins)
c) Organic Nitrogen
d) Nitrates
e) Nitrites
N & P (Nutrients) - essential to the growth of protista and plants.
Nitrogen data - evaluate biological treatability of WW.
To control algal growth in receiving waters,
Removal of N in wastewater prior to its discharge is desirable.
vi) Sulfur
S-2 + 2H H2S
vii) Heavy Metals
Metals having specific gravity ___ time the water are called
heavy metals.
Major source - Industrial effluents
Heavy metals have adverse health effects on human and
animals.
2. Gases
Bacteria Fungi
Viruses Algae
Protozoas Worms
Microorganisms
1) Director Method
2) Dilution methods
1) Direct Method
T = 5 days
Lt = 154 mg/l
L = ?
K = 0.1 day-1
We have
Lt = L(1-e-Kt)
154 = L( 1-e-5x0.1)
L = 391 mg/l
Now for 3days BOD
Lt=3 = 391(1-e-3x0.1) = Lt=3 = 101 mg/l
2) Chemical Oxygen Demand (COD):
Advantages :
The raw sewage must be treated prior its disposal in water body
Degree of treatment depends upon following consideration
Purposes of Treatment
Screening
Mixing
Flocculation
Sedimentation
Floatation
Elutriation
Vaccum Filtration
Heat transfer and drying
2. Unit processes
Treatment units
3. Secondary Treatment
Done through biological processes
(remove organic solids)
a) Trickling Filters
b) Activated Sludge Process
c) Oxidation Ponds
Types of screens
There are two types of screens
i) Bar Screen or Racks
These can be further of two types
a) Manually / Hand Cleaned (For small STP)
b) Mechanically Cleaned (For large STP
ii) Mesh Screen /Fine Screens
(Not for sewage but for industrial WW i.e for uniform particle sizes)
Contd..
Figure: A Typical view of Bar Rack Screen
Screening - Design Consideration
Parameter Types of Screen
Manually Cleaned Mech. Cleaned
Bar width(mm) 6 15 mm 6 15 mm
(1/4 5/8) (1/4 5/8)
Bar Spacing (mm) 25 -50 15 75
Approach Velocity (m/s) 0.3 0.6 0.6 1.0
Velocity should not be more than 1 m/Sec to avoid Excessive Head
Loss and should not less than 0.6 m/Sec to avoid Sedimentation in
Screen Chambers
Slope <300 >750
Length Approachable
Location Before pumps Before pumps
Number of Screens 02 02
Surface Area perpendicular to 2 times the area of
flow sewer
Screened material (m3/m3 flow) 1.6x 10-6 1.5x10-6
Nature of Screened material Contaminated
Disposal of Screened Material Landfill or Incineration
c) Comminutors
Grit Chambers are used to remove the inert inorganic particles (sand,
metal fragments and eggshells etc) from sewage having size 0.2mm or
larger and specific gravity equal or more than 2.65
Purposes
i. To protect moving mechanical equipment from abrasion and
abnormal wear.
ii. To avoid heavy deposition in pipelines, channels and conduits.
iii. To avoid frequent cleaning of digesters to remove excessive
deposition
Design Considerations
Parameters Value
Velocity (m/s) 0.25 0.3
Detention Time (Sec) 40 60
Length (m) 10 20
Cleaning Intervals (Weeks) 2
Velocity Control Through Proportional Flow Weir OR
Sutro Weir
Figure- A Schematic View of
Example
Assuming suitable design criteria, design a horizontal flow type
Grit chamber for a proposed sewage treatment plant expected to
treat 60,000 m3/day maximum flows. The estimated average and
minimum sewage flows are 45,000 m3/day and 15000 m3/day
respectively. The flow through velocity of 0.3 m/sec is to be
controlled by proportional weir.
Solution
Assume provision of two channels
Q 60000 m3/day / 2 30000 m3/day 0.35 m3/s
a) Calculate x-Sectional Area
Area Q/v = 0.35 / 0.3 = 1.16 m2
b) Calculate Length of Channel
Assume detention time of 60 sec moving with velocity of 0.3 m/s
for this flow in GC
L = Vxt (S= vt) = 0.3 x 60 = 18.0 m
Add 10 % additional length for inlet and outlet structures
L 18 = 1.8 = 19.8 m = 20 m
c) Calculate depth of channel
Assuming the width of each channel as 1.5 m
D= Area /width = 1.16 / 1.5 = 0.77 m = 0.8 m
Add 10 % additional length for inlet and outlet structures
D (total) Net depth + Free board + depth for grit collection
0.8 + 0.3 + 0.2 (assume) = 1.3 m
d) Calculate net Volume of capacity
V = LxB xD
18 x 1.5 x 0.8 = 21.6 m3
Check for Vol of tank
V = Q x t = 30000 x = 20.8 m3
60/(60x0600x24)
So provide 21.6 m3
Check for SLR
SLR = Q peak / As 30000 / (18 x 1.5) = 1111.11 m3 / m2-day
= 1112.0 m3 / m2-day
Check for vs
Vs = 0.012 m/s (slightly less but acceptable)
e) Skimming Tank
Vs = g (ps p)d2
18
Where p = The mass density of fluid (M/L3)
Vs = terminal settling velocity (L/T) G = Acceleration due to gravity (L/T2)
ps = the mass density of particles (M/L3) = Absolute viscosity of the liquid (M/LT)
Assumptions
Example:
A floating stick travels a distance of 15 m in 30 seconds in a reactor
tank having 2.0 m width and 1.5 m depth. Determine the flow and
flow through velocity.
Solution:
Distance travelled, L = 15.0 m
Time taken, t = 30 s
As Flow through velocity, Vh = L/t (distance / time)
= 15/30 = 0.5 m/s
Flow of wastewater, Q = Ax x Vh (Area X Velocity)
= 2.0 (m) x 1.5 (m) x 0.5 (m)
= 1.5 m3/s
Example: Assuming the diameter of a clarifier to be 20 m and the
wastewater flow rate is 10.0 MLD. Calculate the detention time and
surface loading rate of the clarifier having a wastewater depth of 2.5.
Solution: The Surface area of the Clarifier is given by
2
As = 4
202
= = 314.16 2
4
Now, surface loading rate,
SLR =
3 3
1010 ( )
=
314.16 (2 )
(As 10 MLD = 10 * 103 m3/day, volume of the tank, V=Qxt
As, detention time, t =
Or t = (As V = As*D)
(314.16 (2 ) 2.5 ()
= 3
= 0.07854 day
10103 ( )
= 1.885 hours 1.9
Example
Assuming a hydraulic loading rate of 25.0 m3/m2-d, determine
the surface area and diameter of a basin treating 0.5 MLD flow of
wastewater.
Solution: wastewater flow, Q = 0.5 MLD
= 0.5 x 106 L/d
= 0.5 x 106 x 103 m3/d
= 500 m3/d
Now, surface area of the reactor, As =
3
m
5003 2/d
= m m
25 / d
420
As, Diameter of tank, D =
= 5.046 m
= 5.0 m (say)
Detention Time
Example:
A treatment unit is 1.5 m wide, 20 m long and has a wastewater depth
of 2.0 m in it. If the wastewater flow through the tank is 0.5 m3/s.
Calculate the detention time.
Solution:
Flow of wastewater, Q = 0.5 m3/s (given)
= 0.5 m3/s x 60 (s/min)
= 30 m3/min
The volume of treatment unit, V = 1.5 x 20 x 2.0
= 60 m3
As, Detention Time, t = V/Q and V = Q x t
= 60 (m3)/ 30 (m3/min)
=2.0 min
Sedimentation Tanks
i) Rectangular Tanks
ii) Circular Tanks
iii) Square Tanks
Rectangular Tanks
Horizontal flow pattern. WW flows along the long axis.
Minimizes the effects of inlet and outlet disturbances.
Design basis
Sr.No. Parameter Value
i) Design flow Average Daily Flow
ii) Settling Velocity of Particles 0.3 0.7 mm/s
iii) Surface Overflow Rate(SOR) 25 40 m/day
iv) Detention Time (DT) 1.5- 2.5 hour
v) Depth 2-5 m
vi) Maximum Length 30 m
vii) L : W (ratio) 4:1
viii) Depth 25m
viii) Weir Loading Not more than 120 m3/m.day
vix) Sludge Accumulation 2.5 Kg wet solids / m3 flow
Secondary Sedimentation Tank
i) Design Flow Average Daily Discharge
ii) SOR 30-40 m/day
iii) Detention Time (DT) 2 3 hours
iv) Depth 2.5 5 m
Circular Tank
Square Basin
DT V/Q
V(vol) = 30 x 15 x 4 m3 1800 m3
Also
SOR = Q/WL
Q = SOR x WL = 24 x 15x30 m3/day 10800 m3/day
DT = V/Q = 1800 / 10800 day 0.1667 day
DT = 4 hours
Inlets and outlets
Careful design is important to assure reasonable
performance of ST.
Inlets
Advantages of proper design
3
( )
Weir Overflow Rate = SLR =
()
Example:
A rectangular sedimentation tank has a length of 10.0 m and a width
of 5.0 m. For the flow of 1.0 MLD. Calculate the weir loading rate.
Solution:
Normally in a rectangular tank the wastewater flow is along the
length of the tank, so the weir overflow will be over the width of tank.
Thus, in this case, the weir length is 5.0 m.
= 200.0 m3/m-d
ii) Septic Tanks
These are Primary Sediments basin
Provided in houses with water supply and too low housing density to
allow soakage pits
A minor degree of solid destruction may occur due to anaerobic
digestion. Units are ordinarily sized to provide detention time of 24 hours
at average daily flow.
Usually made of concrete but steel and fibreglass are used.
The effluent is offensive and potentially dangerous.
Effluent needs further treatment (additional process or soil disposal
Ave. BOD ranged from 120 270 mg/l & Ave. SS from 44 69 mg/l.
De-sludging is required after 1 to 3 years.
Two Compartment ST (Better performance in SS & Pathogen removal)
Septic tanks are more expensive than other on-site WWT system
Significance :
Lt t
= -K
dL/dt dt
L0 to
Where
Lt = Organic Matter remaining at time t ie. Remaining BOD at time t
Lo = Original Concentration of Organic matter i.e. Ultimate BOD
ln Lt / Lo = -Kt
Lt = Lo e kt ----------I
Let y be the concentration of OM (BOD) consumed upto time t
Then
y = Lo Lt
Putting from (i)
y = Lo - Lo e kt
y = Lo (1- e kt) ie
BOD Consumed = Ultimate BOD ( 1- e kt)
Also
t = Time in days
K = BOD reaction rate constant and
K = Its value for domestic sewage is 0.23 per day at 20 0C
1) Director Method
2) Dilution methods
1) Direct Method
T = 5 days
Lt = 154 mg/l
L = ?
K = 0.1 day-1
We have
Lt = L(1-e-Kt)
154 = L( 1-e-5x0.1)
L = 391 mg/l
Now for 3days BOD
Lt=3 = 391(1-e-3x0.1) = Lt=3 = 101 mg/l
2) Chemical Oxygen Demand (COD):
Advantages :
The 5-days BOD of the sewage is 276 mg/l. The ultimate BOD
of the sewage is reported to be 380 mg/l. At what rate the
sewage sample was oxidized
Sol.
T = 5 days
Lt = 276 mg/l
L = 380 mg/l
K = ?
We have
Lt = L(1-e-Kt)
276 = 380( 1-e-5K)
0.726 = ( 1-e-5K) = e-5K = 0.274
Log10 0.274 = -5K K = 0.112 day-1
Example
If the 5 days BOD of the sewage is 154 mg/l, what would be its 3 day BOD. Take
K=0.1day-1
Sol.
T = 5 days
Lt = 154 mg/l
L = ?
K = 0.1 day-1
We have
Lt = L(1-e-Kt)
156 = L( 1-e-5x0.1)
L = 225 mg/l
Now for 3days BOD
Lt=3 = 225(1-e-3x0.1) = Lt=3 = 112 mg/l