If we envision a house or room in a house or other enclosed
space as a simple box, then we can construct a simple mass-
balance model to explore the behavior of the indoor air quality as a function of infiltration of outdoor air, indoor sources and sinks, and linkage to the outdoor air. If we assume the contents of the box are well mixed, then Rate of pollutant increase in box= rate of pollutant entering box from outdoors + rate of pollutant entering box from outdoors - rate of pollutant leaving box by leakage to outdoors - rate of pollutant leaving box by decay GASEOUS POLLUTANS
ABSORPTION
Control devices base on the principle of absorption
attempt to transfer the pollutant from a gas to a liquid phase. The dissolution may or may not be accompanied by a reaction with an ingredient of the liquid. -is a diffusion process wherein the pollutant gas moves from point of higher concentrations to points of lower concentration. The removal of the pollutant gas takes place in three steps. 1. Diffusion of the pollutant gas to the surface of the liquid 2. Transfer across the gasliquid interface (dissolution) 3. Diffusion of the dissolved gas away from the interface into the liquid
COUNTERCURRENT FLOW- is the process where the
gas and liquid in opposite direction. Is mass transfer process in which the gas is boded to a solid. The relation between the amount of pollutant adsorbed and the the equilibrium pressure at constant temperature is called in ADSORPTION ISOTHERM.
COMBUSTION- when the contaminant in the gas steam is
oxidizable to an inert gas, combustion is a possible alternative method of control. Typically, CO and hydrocarbons fall into this category. Both direct flame combustion by afterburners and catalytic combustion have been used in the commercial applications. Systems fall into two brad categories: nonregenerative and regenerative. In nonregenerative systems the reagent used to remove the sulfur oxides from the gas steam is used and discarded. In regenerative systems reagent is recovered and reused. In terms of the number and size of systems installed , nongenerative systems dominate. Almost all nitrogen oxide air pollution results from combustion processes. They are produced from the oxidation of nitrogen bound in the fuel, from the reaction of the molecular oxygen and nitrogen in the combustion air at temperatures above 1600k, and from the reaction of nitrogen in the combustion air with hydrocarbon radicals. PREVENTIONS 1.Minimizing operating temperatures 2.Fuel switching 3.Low excess air 4.Flue gas recirculation 5.Lean combustion 6.Staged combustion 7.Low nitrogen oxide burners 8. Secondary combustions 9.water-steam injection CYCLONES are quite efficient for particles larger than 10 micrometers. Conversely, they are not very efficient for particles 1 micrometer or less in diameter. Thus, they are employed only for course dusts. Some applications include controlling emission of wood dust, paper filters and buffing fibers. LIQUID SCRUBBING. When the particular matter to be collected is wet, corrosive, or very hot, the fabric filter may not work. Liquid scrubbing might. Typical scrubbing applications include control of emission of tale dust, phosphoric acid mist, foundry cupola dust, and open bearth steel furnace fumes.