Beruflich Dokumente
Kultur Dokumente
1
Introduction
Introduction 2
The ground begins to rumble, then shake. The hero of the film a lean
excowboy with a square jaw under his hat and a gorgeous brunette on his
arm reaches out to brace himself against his horse. A smile creases his face
as the rumbling grows louder. Suddenly, a gush of black goo spurts into the air
and splashes down on him, his side-kick and his best gal. They dance with
ecstasy until the music swells and the credits start to roll. Why is our hero so
happy? Because hes rich! After years of drilling dry holes in every county
between the Red River and the Rio Grande, he finally struck oil.
Paul R. Robinson
Introduction 3
What is petroleum ?
In oceans:
Dead animals and plants sank to the bottom
of the ocean.
Buried under sediments of sand and mud.
Layers increase in thickness with time.
Temperature and pressure increase.
Causing the change to sedimentary rocks.
Introduction- History 22
History
An example is the kerosene lamp and the depletion of
other sources of fuel for lighting such as whale oil.
Introduction- History 23
Discussion
Discussion 24
Characterization of crude oil
The ultimate goal of oil processing is turning it
into useful products such as fuel, lubricants and
polymers.
Crude oils with less than 1% sulfur are called low sulfur
(sweet) crudes, and those with more sulfur than 1% are called
high sulfur (sour) crudes.
34
Discussion- Characterization of crude oil- Bulk properties
6- Bubble point & Flash point
The bubble point is the temperature at which the liquid
hydrocarbon begins to boil and form vapor bubbles. It should
be the same as the dew point for pure components but for
mixtures it is different as boiling occurs on a range of
temperatures.
35
7- Fire point & Freeze point
The fire point is a temperature well above the flash point
where the products can catch fire easily.
The true boiling point curve is the boiling point of the oil
fraction versus the fraction of oil vaporized.
1- Paraffins: Alkanes such as methane, ethane, propane, etc. They are present
in large amounts in the crude oil.
8- Resins: Polynuclear aromatics with long side chains of paraffins and a small
ring of aromatics they are of high molecular weight. These compounds
also contain sulfur, nitrogen, and metals.
1- Volatile products
May be bottled in cylinders and sold or used as fuel.
Propane LPG
Butane LPG
Light naphtha
2- Light distillates
Gasoline used as motor fuel.
Heavy naphtha used in petrochemical industries
Kerosene use for lighting, cleaning, tractor fuel and jet fuel
3- Middle distillates
Diesel fuel used as fuel in diesel engines and as lubricant.
Benzene
Heating oils
Gas oils
4- Fuel oils
Marine diesel
Bunker fuels (used for ships)
5- Lubricating oils
Use to reduce friction and hence wear in moving parts.
Motor
Spindle
Machine oils
6- Waxes
Food and paper coating industry
Pharmaceutical uses
7- Bitumen
Asphalt, used for paving roads.
Coke
78
The atmospheric tower
Before the crude enters the tower it is desalted then goes
through a network of heat exchangers and a fired heater
which pre-heats the feed to the desired temperature then
enter the tower just above the bottom of the tower.
The heat exchangers use the heat from the product streams
of the tower to heat the feed crude.
Products are collected at the top, bottom and the side of the
column.
82
Design and principle
Distillation is an equilibrium stage operation. In each stage
a liquid phase is contacted with a vapor phase, and mass
transfer occurs from vapor to liquid and vice versa.
When the vapor reaches the top it would have lost most of its
heavy hydrocarbons (HCs) and gained extra light HCs.
Hence the stream leaving the top will mainly have light HCs and the
stream at the bottom having mainly heavy HCs and the side streams
in between have intermediate boiling point HCs.
This is done using either trays or packing, both have the ability
to force the phases into close contact and giving the sufficient
time for the mass transfer to occur.
87
Design and principle
The product leaving from the top is called the overhead
product or the distillate, this can be a vapor or liquid
depending on the type of condenser.
The second is that below a certain reflux ratio the separation is impossible
no matter the number of trays due to the absence of liquid coming from
the top to mix with the vapor.
Therefore the refinery should operate between the minimum reflux and
the total reflux ratios.
The optimum reflux ratio that is practically employed is between 1:2 to 1:5
times the minimum reflux ratio.
The partial condenser only liquefies a part of the vapor. The liquid
produced is recycled to the column, and the vapor is the product stream.
Thus the composition of the vapor entering the condenser and the two
product streams will be different. Partial condensers are considered an
extra stage as they operate as an equilibrium separation stage.
In large columns side stream reboilers can be used to draw liquid off a
tray, heat it, then return the vapor-liquid mixture to the same or a
different tray.
If the feed is below its bubble point, heat should be added to raise the
temperature and allow it to vaporize.
This heat is provided by the condensing vapor rising through the column,
so this fed liquid condensed vapor thus decreasing the off product
produced. If the feed is as a superheated vapor, it will vaporize some liquid
so the liquid flow is decreased and the vapor flow is increased.
This is due to that inside the column the liquid and vapor are at the bubble
and dew points respectively so adding feed at a different temperature will
cause a disturbance in the amounts of gas and liquid present which will
change phases to give the required energy to change the temperature of
the feed to the dew or bubble points.
This allows for the utilization of the available column heat using the heat
exchanger network, and maintaining the stability of the vapor loading of
the column and maintaining the amount of liquid moving in the column.
103
Products of Atmospheric distillation
104
Products of Atmospheric distillation
Each of these products goes to a different unit to undergo further processing to
give the final product. Examples are
105
Atmospheric column schematic
Preheating,
desalting, tower,
side strippers,
pump arounds,
cooler, reboiler,
and products.
106
Vacuum distillation
107
Overview
The residue from atmospheric distillation is sent to a vacuum
distillation tower which recovers additional liquid at 0.7 to 1.5
psia (atmospheric pressure is 14.7 psia) and temperature
between 380-420oC.
108
Overview
Random packing and demister pads are used mostly instead
of trays.
Tis will reduce the need for increasing the temperature, which
can cause the decomposition of the hydrocarbons.
110
Types of vacuum distillation
Dry vacuum distillation: without the injection of steam. It
runs at a very low pressure (10-15 mmHg at the top) so
requires the use of a booster ejector before the first
condenser.
111
Types of vacuum distillation
112
Types of vacuum distillation
113
Types of vacuum distillation
Semi-wet vacuum distillation: is when only steam is injected
at the bottom of the column. A booster ejector is needed. It is
positioned upstream of the first overhead condenser and
designed to boost process pressure high enough to allow
condensation.
114
Definitions
LVGO: light vacuum gas oil.
115
Definitions
Noncondensables: compounds that can not be condensed by
the vacuum system. This is made from air entering from leaks,
noncondensables dissolved in the feed when stored in the
storage tank, and light hydrocarbons produced by cracking in
the furnace.
Slop cut and overflash: the two are the internal reflux coming
from the first tray above the feed inlet. Overflash is 3-5% of
the feed, is the section seen with the feed liquid to the
bottom of the column.
116
The vacuum tower
The atmospheric residue is sent directly to the vacuum tower,
it is sometimes stored at 150oC to ensure its viscosity.
117
The vacuum tower
In wet vacuum distillation, the furnace banks are often
equipped with dilution steam injection to limit the
temperature thus reduce coking.
118
The vacuum tower
If it is required to increase the value of the gas oil or if the
downstream units require special initial cut point, three cuts
are drawn off from the column.
An MVGO and HVGO which are the feed for the downstream
units.
119
The vacuum tower
120
Description of the column
The vacuum column has two main targets the first is the
recovery of light hydrocarbons from the atmospheric residue
and the preparation of feed for the following units.
121
Preparing the feed for catalytic units
1- Column without a fractionation zone
If no end or initial point requirement for the vacuum distillate.
Configuration:
One or two wash zones fed by internal reflux of the HVGO
draw tray.
A heat exchanger zone above the HVGO side draw tray.
A heat exchanger zone above the HVGO side draw tray.
122
Preparing the feed for catalytic units
Configuration
The feed for this zone is made up of internal reflux under
HVGO.
If better values are desired for the gas oil in the feed then a
fractional zone is installed between the LVGO and the MVGO
offtakes.
123
Preparing the feed for catalytic units
124
Preparing the feed for catalytic units
Configuration
In some cases the solution of two stage vacuum distillation
can be used to obtain very heavy cuts.
The first tower is dry and the second is wet. The bottom of the
first tower supplies the feed for the second.
125
Vacuum distillation design to give lube oils
126
Vacuum distillation design to produce bitumen
127
Choosing the type of vacuum distillation
128
Technology
129
Packing and distributors
Fractionation and heat exchanger zones are equipped with
packing to curb pressure drop.
130
Packing and distributors
This type of packing is more expensive and more effective and
is mainly used in fractionation zones.
It is today being used for all the column above the wash
zones. The wash zones can be equipped with less
sophisticated grates.
131
Vacuum pumps and ejector- condensers
132
Vacuum pumps and ejector- condensers
133
Vacuum pumps and ejector- condensers
134
Vacuum pumps and ejector- condensers
135
Vacuum pumps and ejector- condensers
136
Vacuum pumps and ejector- condensers
137
Vacuum pumps and ejector- condensers
138
Vacuum pumps and ejector- condensers
139
The whole tower with the vacuum system
140
Products of the vacuum distillation unit
141
Products of the vacuum distillation unit
1- Multiple gas oils.
Sent to the hydrotreating unit.
2- Vacuum residue:
Blended to give asphalt and heavy fuel oil.
Further processing. Thermal treatment or solvent extraction.
142
Vacuum distillation summary
Configuration
Reduced pressure to allow for lower temperatures.
No reboiler.
Under vacuum.
144
Cracking
145
Overview
Cracking is the process (chemical reaction) where large high
boiling point hydrocarbons are broken cracked into smaller,
lighter molecules.
146
Overview
Cracking units are an essential component in the refinery:
Allows the economic use of the heavy and sour crude oils
when burned during cracking.
147
Thermal cracking
148
Thermal cracking
Thermal cracking followed by the separation using physical
differences (distillation).
The products are usually naphtha, gas, gas oil, and thermal
cracked residue.
149
Thermal cracking
The operating temperature is about 450-500oC.
150
The process
Products (Residue) from the atmospheric and vacuum column
are used.
The C4 and lighter streams from the fractionator are sent for
further processing usually alkylation.
152
The process
The thermally cracked gasoline and naphtha from the
fractionator are sued for gasoline blending.
153
The process
154
Coking
155
Coking
A sub category of a variant of thermal cracking is coking.
156
Coking
The main uses of petroleum coke:
Fuel.
Manufacture of anodes for electrolytic cell.
Direct use as chemical carbon source for manufacture of
elemental phosphorus, calcium carbide.
Manufacture of electrodes for use in electric furnace .
Manufacture of graphite
157
Delayed coking
The delayed coking process was developed to minimize
refinery yields of residual fuel oil.
158
Delayed coking
Gradual evolution of refineries lead to that heaters were
designed to raise the feedstock temperature above the coking
temperature without significant coke formation in the
heaters.
159
Delayed coking
160
Delayed coking
The higher the outlet temperature of the furnace the greater
the tendency to produce shot coke.
And the shorter the time before the furnace tubes have to be
decoked.
161
The process
Hot fresh liquid feed is fed to the fractionator two to four
trays above the bottom vapor zone.
162
The process
These vapors; afterbeing fed to the fractionator are passed
through the quench trays.
Quench trays are trays where the fresh feed is mixed with the
gasses from the reactor.
There are usually 2-3 trays above the feed trays which are
below the gas oil draw tray.
163
The process
Steam and vaporized light ends are returned from the top of
the gas oil stripper to the fractionator 1-2 trays above the gas
oil draw tray.
Eight to ten trays are between the gas oil draw and the
naphtha draw (column top).
164
The process
165
Coke removal
The coke drum is continuously being filled during service to a
safe margin from the top.
166
Coke removal
After isolation, the empty drum is steamed to remove the
hydrocarbon vapors.
167
Coke removal
The hydraulic system, is a number of high pressure (13800 to
31000 kPa) water jets which are lowered into the coke bed on
a rotating drill stem.
A small whole in diameter is first cut all the way through the
bed from the top to the bottom using a special jet.
This is done to allow the main drill stem to enter and allow
the movement of coke and water through the bed.
168
Coke removal
The bulk of the coke is then cut from the drum, usually
starting at the bottom.
169
Coke removal
A newly developed technique called chipping is now used to
remove the coke from the surge drum.
170
Coke removal
The coke which falls from the drum is often collected directly
in railroad cars.
171
Coke removal
172
Operation
The coke drums are filled and emptied and filled on time
cycles.
Usually 2 drums are present one for reaction and the other
for releasing coke.
173
Operation
The table shows time schedules for the different stages of
operation of the unit.
174
Operation
The capacity can be increased by operating in shorter cycle
times.
175
Operation
176
Flexicoking
177
Flexicoking
The feed to flexicoking can be any heavy oil such as vacuum
residue, coal tar or sand bitumen.
178
Flexicoking
The coke recycle thus provides the sensible heat and heat of
vaporization for the feed.
180
Flexicoking
The coke is stripped with steam in a baffled section at the
bottom of the reactor to prevent the reaction products, other
than coke, from being entrained with coke leaving the reactor.
181
Flexicoking
182
Flexicoking
Coke flows from the coke heater to a third fluidized bed in the
gasifier where it is reacted with air and steam to give a fuel
gas product consisting of CO, hydrogen, carbondioxide, and
nitrogen.
183
Flexicoking
184
Flexicoking
This gas flows from the top of the gasifier to the bottom of the
heater where it is used to fluidize the heater bed.
185
Flexicoking
The system can be designed and operated to gasify about 60-
97% of the coke product from the reactor.
186
Flexicoking
The coke fines collected in the wet scrubber plus the purge
coke from the heater represent the net coke yield and contain
all of the metal and ash components of the reactor feedstock.
This gas has a much lower heating value than natural gas, so
modifications to boilers an furnaces may be necessary for
efficient combustion.
187
Fluid coking
188
Fluid coking
Fluid coking is a simplified version of flexicoking.
189
Fluid coking
Therefore only two fluid beds are used in a fluid coker; a
reactor and a burner which replaces the heater.
190
Fluid coking
Also the coke gas can be used to displace liquid and gaseous
hydrocarbon fuels in the refinery heaters.
And does not have to be used only in boilers as the case with
fluid coke.
191
Yields from Flexicoking and Fluid coking
The products from Flexicoking and fluid coking are the same
as those from the delayed coking except for the amount of
reactor coke product which is burned or gasified.
Thus the coke yield from fluid coking will be about 75-80% of
the coke yield from a delayed coker.
192
Visbreaking
193
Visbreaking
Visbreaking is relatively, mild thermal cracking operation.
194
Visbreaking
Refinery product of heavy fuel oils can be reduced by 20-35%.
195
Visbreaking
Long paraffinic side chains attached to aromatic rings are the
main cause of high pour points and viscosities for paraffinic
base residues.
196
Visbreaking
The degree of viscosity and pour point reduction is a function
of the composition of the residues which are fed to the
visbreaker.
197
Visbreaking
The properties of the cutter stocks used to blend with the
visbreaker tars also have an effect on the severity of the
visbreaking operation.
198
Visbreaking
The oil fraction is soluble in propane.
199
Visbreaking
The main reactions that occur during visbreaking are:
200
Visbreaking
The severity of the visbreaking operation can be expressed in
several ways:
201
Visbreaking
In the US the severity is expressed as the volume % product
gasoline in a specified boiling range.
202
Visbreaking
There are two types of visbreaking operations, coil and
furnace cracking and soaker cracking.
203
Visbreaking
Coil cracking uses higher furnace outlet temperatures 473-
500oC and reaction times from 1 to 3 minutes.
The product yields and properties are similar, but the soaker
operation with its lower furnace outlet temperatures ahs the
advantages of lower energy consumption and longer run
times before having to shut down to remove coke from the
furnace tubes.
204
Visbreaker
205
Visbreaking
Run times are in the range of 3-6 months for furnace
visbreakers.
206
Soaker visbreaker
207
Coil visbreaker
208
Coil visbreaker
209
Soaker visbreaker
210
Process
The feed is introduced into the furnace and heated to the
process temperature.
211
Process
In soaker cracking operation the feed leaves the furnace at
425-440oC.
212
Process
In furnace cracking, fuel consumption accounts for nearly 80%
of the operating cost.
213
products
The properties of the products of visbreaking change with the
conversion and the characteristics of the feedstocks.
214
products
215
products
216
Fluid Catalytic cracking
217
Overview
Catalytic cracking is the most important and widely used
process in the refineries for converting heavy oils into
gasoline and lighter products.
218
Overview
Fluid catalytic cracking (FCC) operates at high temperature
and low pressure conditions and employs a catalyst.
219
Overview
The cracking process produces coke as a side product which
remains on the catalyst surface and lowers its activity.
220
The process
The FCC process employs a catalyst in the form of very fine
metallic particles about 70 micrometers.
221
The process
There are two types of FCC units
The first is side by side type, where the reactor and the
regenerator are separate vessels adjacent to each other.
222
The process
223
The process
Until 1965 most units were a discrete dense phase fluidized
catalyst bed in the reactor.
224
The process
The fresh feed and recycle streams are preheated by heat
exchangers or a furnace and enter the unit at the base of the
feed riser where they are mixed with the hot regenerated
catalyst.
The heat from the catalyst vaporizes the feed and raises its
temperature to the reaction temperature.
225
The process
226
The process
The cracking reactions start when the feed contacts the hot
catalyst in the riser and continues until the oil vapors are
separated from the catalyst in the reactor.
227
The process
228
The process
Part of the adsorbed hydrocarbons is removed by steam
before the catalyst is fed to the regenerator.
229
The process
The regenerator can be designed to operate to burn the cohe
on the catalyst to:
Either a mixture of carbon dioxide and carbon monoxide.
230
The process
The flue gas leaving the regenerator will have large amounts
of carbon monoxide which is burned to carbon dioxide in a CO
furnace (waste heat boiler).
231
The process
Newer units are design to burn the coke to CO2 in the
regenerator as they can burn to a much lower residual carbon
level on the regenerated catalyst.
232
The process
233
FCC
234
FCC
The products formed in catalytic cracking are the result of
primary and secondary reactions.
235
FCC
Advantages
High yields of gasoline.
236
FCC
FCC produces significant amounts of light gasses including
olefins.
237
New designs for fluidized bed catalytic cracking units
238
Cracking catalyst
Commercial cracking catalysts are divided to 3 classes:
Acid- treated natural aluminosilicates.
239
Cracking catalyst
The advantages of the zeolite catalysts are:
Higher activity.
240
Cracking catalyst
Lower coke yield.
241
Cracking catalyst
The high activity of zeolite cracking catalyst allows for shorter
residence time.
The nitrogen reacts with the acid centers on the catalyst and
lowers its activity.
242
Cracking catalyst
The metals deposit and accumulate on the catalyst and cause
a reduction in throughput.
This is due to the catalysis effect of the metal where the coke
is converted to carbon dioxide rather carbon monoxide.
243
Cracking catalyst
It is generally accepted that nickel has four times the effect on
catalyst selectivity as vanadium.
244
Cracking catalyst
Metals removal processes can be used to reactivate the
catalyst.
245
Catalytic hydrocracking
246
Overview
Hydrocracking was commercially developed to convert liginite
to gasoline.
247
Overview
The advantages of hydrocracking are
248
Overview
In a modern refinery catalytic cracking and hydrocracking
work as a team.
And the hydrocracker uses the more aromatic cycle oils and
coker distillates as feed. These streams resist catalytic cracking
even when the newly developed zeolites are used.
249
Overview
In addition to cycle oils and middle distillates, it is also
possible to use residual fuel oils and reduced crude as feed to
the hydrocracking unit.
250
Overview
There are two types of hydrocracking:
Those which operate on distilled feed (hydrocracking).
251
The reactions
There are hundreds of simultaneous reactions occurring in
hydrocracking. It is the general opinion that the mechanism of
hydrocracking is the mechanism of catalytic cracking with
hydrogen superimposed.
252
The reactions
253
The reactions
This shows that cracking and hydrogenation are
complementary.
254
The reactions
This heat causes an increase in temperature and an increase
in the rate of the reaction.
255
The process
Hydrocracking is usually carried out at temperatures between
290 and 400oC an pressures between 8275 and 13800 kPa.
256
The process
The hydrocracking catalyst is susceptible to poisoning by
metallic salts, oxygen, sulfur, and organic nitrogen compounds
present in the feedstocks.
257
The process
It is nectary to reduce the waster content of the feed to less
than 25 ppm, as at the temperatures required by
hydrocracking steam causes the crystalline structure of the
catalyst to collapse.
258
The process
The hydrocracking process may require one or two stages
depending on the process itself and the feed used.
259
The process
260
The process
The decision weather to use single or two stage system
depends on the size of the unit and the product desired.
For most feedstocks the use of a single stage will allow the
complete conversion of the feed to gasoline and lighter
products by recycling the heavier material to the reactor.
The next slide has the figure of the two stage system. The one
stage system will have the same flow sheet with the addition
of the recycle of the fractionation tower bottoms to the
reactor feed.
261
The process
262
The process
The fresh feed is mixed with the make up hydrogen and
recycle gas which also has a high hydrogen content and
passed through a heater then fed to the first reactor.
263
The process
This reactor is placed before the first hydrocracking reactor.
264
The process
265
The process
The hydrocracking reactors are operated at a temperature
that is sufficiently high to convert 40-50 vol% of the effluent
from the reactor.
266
The process
The liquid product from the separator is sent to a distillation
column.
And the light and heavy Naphtha, jet fuel, and diesel boiling
point range streams as liquid side streams.
267
The process
268
The process
The bottoms stream from the fractionator is mixed with thee
recycle hydrogen from the second stage and sent through a
furnace to the second stage rector.
269
The process
270
The process
Both the first and second stage reactors contain several beds
of catalyst.
Also this will allow for the redistribution of the feed and
hydrogen between the beds.
271
The hydrocracking catalyst
Most of the hydrocracking catalysts consist of a crystalline
mixture of silica-alumina.
272
The hydrocracking catalyst
The catalyst activity decreases with use, and reactor
temperatures are raised during a run to increase reaction rate
and maintain conversion.
The catalyst selectivity also changes with age, and more gas is
made and less naphtha is produced as the temperature is
raised to maintain the conversion.
273
The hydrocracking catalyst
Regeneration is done by burning off the catalyst deposits.
274
The hydrocracking catalyst
Almost all hydrocracking catalysts use silica- alumina as the
cracking base.
275
Hydroprocessing and Resid processing
276
Hydroprocessing and Resid processing
277
Hydroprocessing and Resid processing
Also the nickel and vanadium in the resid act as resid for the
formation of gas and coke.
278
Hydroprocessing and Resid processing
279
Hydroprocessing and Resid processing
280
Hydroprocessing and Resid processing
281
Hydroprocessing and Resid processing
282
Processing options
The types of processes can be classified as catalytic or non
catalytic.
283
Processing options
The types of processes can be classified as catalytic or non
catalytic.
284
Hydroprocessing
285
Hydroprocessing
The term hydroprocessing is used to represent the processes
used to reduce the boiling point range of the feedstock and to
remove impurities.
286
Hydroprocessing
In US refineries, hydroprocessing units are used to prepare
residual stream feedstocks for cracking and coking units.
287
Hydroprocessing
The heavy naphtha fraction of the products will be
catalytically reformed to improve octanes.
288
Fixed bed reactors
289
Fixed bed reactors
Most processes have fixed bed reactors and usually require
the units to shut down and the catalyst changed.
290
Fixed bed reactors
291
Fixed bed reactors
The low space velocities and high pressure limit the charge
rates to 4760-6360 M3/SD per train of reactors.
292
Fixed bed reactors
The guard reactors catalyst has large pore sized (150-200 A)
silica-alumina catalyst with a low level loading of
hydrogenation metals such as cobalt and molybdenum.
293
Fixed bed reactors
Typical pore sizes will be in the range 80-100 A.
294
The process
The heavy crude oil fed to the atmospheric distillation unit is
desalted to remove as much of the inorganic salt and
suspended solids.
295
The process
After filtration the resid is mixed with the recycle hydrogen.
296
The process
There is a significant reduction in the Conradson and
Ramsbottom carbons in the guard reactor.
297
The process
298
The process
The recycle hydrogen is separated and the hydrocarbon liquid
stream is fractionated in atmospheric and vacuum distillation
columns.
299
Expanded Bed Hydrocracking
300
Expanded Bed Hydrocracking
The term expanded bed or elbullated bed is given by HRI and
C-E Lummus to a fluidized bed type operation which utilizes a
mixture of liquids and gasses to expand the catalyst bed
rather than just gases.
301
Expanded Bed Hydrocracking Hi-oil
302
Expanded Bed Hydrocracking LC-fining
303
Expanded Bed Hydrocracking LC-fining
304
Expanded Bed Hydrocracking
The preheated feed, recycle and make up hydrogen are
charged to the first reactor of the unit.
305
Expanded Bed Hydrocracking
The product from the second reactor is passed through a heat
exchanger.
306
Expanded Bed Hydrocracking
The liquid stream at low pressure is sent to a rectification
column for separation into products.
307
Expanded Bed Hydrocracking
308
Expanded Bed Hydrocracking
The advantages of the ebullated bed reactor process are:
Also the small solid particles are flushed out of the reactor
and do not contribute to plugging or increasing in pressure
drop.
309
Expanded Bed Hydrocracking
The advantages of the ebullated bed reactor process are:
Because the unit runs all the time with an equilibrium activity
catalyst with a constant quality feedstock, and constant
operating conditions.
310
Expanded Bed Hydrocracking
It is necessary to recycle effluent from each reactors catalyst
bed into the feed of that reactor.
311
Expanded Bed Hydrocracking
This back mixing dilutes the reactants so slows down thee
rates of reactions compared to the fixed bed reactors.
312
Products from LC- fining cracking
313
Moving Bed Hydroprocessors
314
Moving Bed Hydroprocessors
This technology combines advantages of fixed bed and
ebullated bed hydroprocessing.
315
Moving Bed Hydroprocessors
This allows low activity high metal catalyst to be removed
from the reactor and replaced with fresh catalyst while on-
line.
316
Moving Bed Hydroprocessors
As there is no recycling of product from the reactor outlets to
the reactor inlet, the reactors operate in a plug flow
condition.
317
Moving Bed Hydroprocessors
318
Solvent Extraction
319
Solvent extraction
Solvent extraction is used to extract up to two thirds of the
vacuum reduced crude to be used as good quality feed for a
fluid catalytic cracking unit to convert it to gasoline and diesel
fuel blending stock.
320
Solvent extraction
Light hydrocarbons have reverse solubility curves.
321
Solvent extraction
A temperature can be selected at which all of the paraffins go
into solution along with the desired percentage of the resid
fraction.
322
Solvent extraction
At the critical temperature the oil plus resin portion will
separate from the solvent.
323
Solvent extraction
The solvent used is feedstock dependent.
324
Solvent extraction
Therefore, the choice of solvent is an economic choice.
325
Solvent extraction
The higher the molecular weight solvents give lower solvent
recovery cost.
326
Solvent extraction
Since 80-90% of the metals in the crude are in the
asphaltenes.
327
Solvent extraction
328
Summary of resid treatment
329
Summary of resid treatment
Thermal processes (delayed coking and Flexicoking) have the
advantage that the vacuum reduced crude is eliminated so
there is no residual fuel for disposal.
330
Summary of resid treatment
This coke may be very difcult to sell. The alternative is
to hydroprocess the feed to the coker to reduce the
coker feed sulfur level and make a low-sulfur coke.
331
Summary of resid treatment
A disadvantage is that the fuel gas produced is more than the
typical renery can use and energy of compression does not
permit it to be transported very far.
332
Summary of resid treatment
But the products are very aromatic and may require a severe
hydrotreating operation to obtain satisfactory middle distillate
fuel blending stocks.
Crude oils with high sulfur and metal levels will also have high
catalyst replacement costs.
333
Catalytic reforming and Isomerization
334
Catalytic reforming and Isomerization
335
Catalytic reforming and Isomerization
336
Catalytic reforming and Isomerization
337
Catalytic reforming and Isomerization
The table shows typical PONA analysis for the feed and
products of catalytic reforming.
338
Catalytic reforming and Isomerization
339
Catalytic reforming and Isomerization
340
Reactions
341
Reactions
In any series of complex reactions, side reactions occur which
produce undesirable products along with the main reaction
producing the desired products.
342
Reactions
Desirable reactions in a catalytic reformer all lead to the
formation of aromatics and iso-parafns:
Parafns are isomerized and to some extent converted to
naphthenes. The naphthenes are subsequently converted to
aromatics.
343
Reactions
Reactions leading to the formation of undesirable products:
344
Reactions
As the catalyst ages, it is necessary to change the process
operating conditions.
345
Reactions
There are four major reactions that take place during reforming:
Dehydrogenation of naphthenes to aromatics.
Isomerization.
Hydrocracking.
The rst two of these reactions involve dehydrogenation and will
be discussed together.
346
Dehydrogenation Reactions
347
Dehydrogenation Reactions
The dehydrogenation reactions are highly endothermic and
cause a decrease in temperature as the reaction goes on.
348
Dehydrogenation Reactions
The major dehydrogenation reactions are:
1- Dehydrogenation of alkylcyclohexanes to aromatics.
349
Dehydrogenation Reactions
The major dehydrogenation reactions are:
2- Dehydroisomerization of alkylcyclopentanes to aromatics.
350
Dehydrogenation Reactions
The major dehydrogenation reactions are:
3- Dehydrocyclization of paraffins to aromatics.
351
Dehydrogenation Reactions
The dehydrogenation of cyclohexane derivatives is much
faster than the dehydroisomerization and the
dehydrocyclization.
352
Dehydrogenation Reactions
Aromatics have higher liquid density than paraffins or
naphthenes with the same number of carbon atoms.
353
Dehydrogenation Reactions
The yield of aromatics is increased by:
High temperature (increases reaction rate but adversely
affects chemical equilibrium).
354
Isomerization reactions
355
Isomerization reactions
Isomerization of paraffins and cyclopentanes usually results in
lower octane products than conversion to aromatics.
356
Isomerization reactions
Isomerization reactions include:
1- Isomerization of normal paraffins to isoparaffins.
357
Isomerization reactions
Isomerization reactions include:
2- Isomerization of alkylcyclopentanes to cyclohexanes and
subsequent conversion to benzene.
358
Isomerization reactions
Isomerization yield is increased by:
Low pressure.
359
Hydrocracking Reactions
360
Hydrocracking Reactions
The hydrocracking reactions are exothermic and result in the
production of lighter liquid and gas products.
361
Hydrocracking Reactions
The major hydrocracking reactions involve cracking and
saturation of paraffins.
362
Hydrocracking Reactions
Hydrocracking yields are increased by:
High temperature.
High pressure.
363
Feed preparation
The active material in most catalytic reforming catalysts is
platinum.
364
Feed preparation
The hydrotreater employs a cobalt-molybdenum catalyst to
convert organic sulfur and nitrogen compounds to hydrogen
sulfide and ammonia.
These are then removed from the system with the unreacted
hydrogen.
365
Feed preparation
Hydrogen needed for the hydrotreater is obtained from the
catalytic reformer.
366
Catalytic reforming process
367
Catalytic reforming process
Reforming processes are classified as continuous, cyclic, or
semiregenerative depending upon the frequency of catalyst
regeneration.
368
Catalytic reforming process
As increased coke laydown and thermodynamic equilibrium
yields of reformate are both favored by low pressure.
369
Catalytic reforming process
The semi regenerative unit is at the other end of the
spectrum and has the advantage of minimum capital cost.
370
Catalytic reforming process
The cyclic process is a compromise between these extremes
and is characterized by having a swing reactor in addition to
those on-stream.
371
Catalytic reforming process
The catalyst in the replaced reactor is then regenerated by
feeding hot air to it to burn the carbon off the catalyst.
372
The process
The reforming semiregenerative process is typically a fixed
bed reactor.
373
Continuous reforming
374
Semi regenerative reforming
375
The process
To maintain the reaction rate, the gases are reheated before
being passed over the catalyst in the second reactor.
376
Semi regenerative reforming
377
The process
Several heaters can be used or one heater with several
separate coils.
378
The process
The reaction mixture from the last reactor is cooled and the
liquid products are condensed.
379
Operating conditions
The reformer operating pressure and hydrogen/feed ratio are
compromised among obtaining maximum yields, long
operating times between regeneration, and stable operation.
380
The process
The original reforming process is classified as a semi
regenerative type.
381
The process
And a spare reactor is provided so regeneration can be done
while on stream.
382
Reforming Catalyst
383
Reforming Catalyst
The reforming catalysts used today contain platinum
supported on an alumina base.
384
Reforming Catalyst
And chlorinated alumina provides acid sites for isomerization,
cyclization, and hydrocracking reactions.
385
Reforming Catalyst
In a high pressure process, up to 200 barrels of feed can be
processed per pound of catalyst before regeneration is
needed.
386
Reforming Catalyst
The activity of the catalyst decreases during the on stream
period and the reaction temperature is increased as the
catalyst ages to maintain the desired severity.
387
Reforming Catalyst
Catalysts for fixed bed reactors are extruded into cylinders
0.8-1.6 mm diameter with lengths about 5mm.
388
Reactor Design
389
Reactor Design
Fixed bed reactors used for semi regenerative and cyclic
catalytic vary in size and mechanical details.
390
Reactor Design
The reactors have an internal refractory lining which is
provided to insulate the shell from the high reaction
temperatures.
391
Reactor Design
This steel is used to resist hydrogen embrittelment.
392
Reactor Design
393
Reactor Design
The important feature of vapor distribution is to provide
maximum contact time with minimum pressure drop.
394
Reactor Design
The catalyst pellets are generally supported on a bed of
ceramic spheres about 30-40 cm deep.
395
Isomerization
396
Isomerization
The octane number of the LSR naphtha (C5 82oC) can be
improved by the use of an isomerization process.
397
Isomerization
In once through isomerization where thermodynamic
equilibrium is reached the octane number of naphtha
increased from 70 to 84.
398
Isomerization
Reaction temperatures of about 95-205oC are preferred to
higher temperatures.
399
Isomerization
The available catalysts used for isomerization contain
platinum on various bases.
400
Isomerization
The second type of catalyst used is the molecular sieve base,
and is reported to tolerate feeds saturated with water at
ambient temperature.
401
Isomerization
Catalyst life is usually 3 years or more for all these catalysts.
402
Isomerization
The actual product distribution is dependent upon the type
and age of the catalyst, the space velocity, and the reactor
temperature.
403
Isomerization
If the normal pentane in the reactor product is separated and
recycled, the product RON can be increased from 83 to 86.
404
Isomerization
Some hydrocracking occurs during the reactions, resulting in a
loss of gasoline and the production of light gas.
The amount of gas formed varies with the catalyst type and
age and is sometimes a significant economic factor.
405
Isomerization
406
Isomerization
The composition of the gas can be assumed to be 95 wt%
methane and 5 wt% ethane.
407
Isomerization
The process is very similar to LSR gasoline isomerization but a
feed deisobutanizer is used to concentrate the n-butane in
the reactor charge.
408
Isomerization
409
Isomerization operating conditions
410
Alkylation and Polymerization
411
Alkylation and Polymerization
The alkylation reaction is the addition of an alky group to any
compound.
412
Alkylation and Polymerization
The need for high-octane aviation fuels during World War II
acted as a stimulus to the development of the alkylation
process for production of isoparafnic gasolines of high
octane number.
413
Alkylation and Polymerization
The reactions occurring in both processes are complex and
the product has a rather wide boiling range.
414
Alkylation Reactions
415
Alkylation Reactions
In alkylation processes using hydrouoric or sulfuric acids as
catalysts, only iso-parafns with tertiary carbon atoms, such
as iso butane or iso pentane, react with olens.
416
Alkylation Reactions
With sulfuric acid it is necessary to carryout the reactions at
5to 21C or lower.
417
Alkylation Reactions
In both processes the volume of acid employed is about equal
to that of the liquid hydrocarbon charge.
418
Alkylation Reactions
Efcient agitation is needed to promote contact between the
acid and hydrocarbon phases to ensure high product quality
and yields.
419
Alkylation Reactions
At the same operating conditions, the products from the
hydrouoric and sulfuric acid alkylation process are quite
similar.
420
Alkylation Reactions
For both processes the more important variables are:
Reaction temperature.
Acid strength.
Isobutane concentration.
Olen space velocity.
421
Alkylation Reactions
The main reactions which occur in alkylation are the
combination of olens with iso parafns.
422
Alkylation Reactions
Another signicant reaction in propylene alkylation is the
combination of propylene with iso butane to form propane
plus isobutylene. The isobutylene then reacts with more iso
butane to form 2,2,4-trimethylpentane (isooctane).
423
Alkylation Reactions
The rst step involving the formation of propane is referred to
as a hydrogen transfer reaction.
424
Process Variables
The most important process variables are:
Reaction temperature:
Acid strength:
427
Alkylation Feedstocks
Olens and iso butane are used as alkylation unit feedstocks.
Butenes and propene are the most common olens used, but
pentenes are included in some cases.
428
Alkylation Feedstocks
Alkylation of pentenes is also considered as a way to reduce
the C5 olen content of nal gasoline blends.
429
Alkylation Feedstocks
Hydrocrackers and catalytic crackers produce a great deal of
the iso butane used in alkylation.
430
Alkylation Products
431
Alkylation Products
The products leaving the alkylation unit include the alkylate
stream.
And propane and normal butane that enter with the saturated
and unsaturated feed streams.
432
Alkylation Products
The product streams leaving an alkylation unit are:
C5+alkylate.
Tar.
433
Catalysts
434
Catalysts
Concentrated sulfuric and hydrouoric acids are the only
catalysts used commercially today for the production of high
octane alkylate gasoline.
435
Catalysts
As previously discussed, the desirable reactions are the
formation of C8 carbonium ions and the subsequent
formation of alkylate.
436
Catalysts
Therefore, the acid strengths must be kept above 88% by
weightH2SO4or HF in order to prevent excessive
polymerization.
437
Catalysts
Iso butane is soluble in the acid phase only to the extent of
about 0.1% by weight in sulfuric acid.
Olens are more soluble in the acid phase and a slight amount
of polymerization of the olens is desirable.
438
Catalysts
If the concentration of the acid becomes less than 88%, some
of the acid must be removed and replaced with stronger acid.
439
Catalysts
Unit inventory of hydrouoric acid is about 2540 lb acid per
BPD of feed.
440
Yields and Isobutane Requirements
441
Yields and Isobutane Requirements
Only about 0.1% by volume of olen feed is converted into tar.
This is not truly a tar but a thick dark brown oil containing
complex mixtures of conjugated cyclopentadienes with side
chains
442
Operating Conditions
443
Hydrofluoric Acid Processes
444
Hydrofluoric Acid Processes
Both the olen and isobutane feeds are dehydrated by
passing the feed-stocks through a solid bed desiccant unit.
445
Hydrofluoric Acid Processes
446
Hydrofluoric Acid Processes
The bottom product from the rerun column is a mixture of tar
and an HFwater azeotrope.
These components are separated in a tar settler (not shown
on the ow diagram).
447
Hydrofluoric Acid Processes
The reaction mixture is allowed to settle into two liquid layers.
The acid is then recycled and mixed with more fresh feed,
thus completing the acid circuit.
448
Hydrofluoric Acid Processes
A small slip-stream of acid is withdrawn from the settler and
fed to an acid rerun column to remove dissolved water and
polymerized hydrocarbons.
449
Hydrofluoric Acid Processes
The hydrocarbon layer removed from the top of the acid
settler is a mixture of propane, isobutane, normal butane, and
alkylate along with small amounts of hydrouoric acid.
450
Hydrofluoric Acid Processes
Although the ow sheet shows the fractionation of propane,
isobutane, normal butane, and alkylate to require three
separate fractionators.
451
Hydrofluoric Acid Processes
A normal butane product is taken off as a vapor several trays
below the feed tray and the alkylate is removed from the
bottom.
452
Hydrofluoric Acid Processes
453
Hydrofluoric Acid Processes
Good mixing is achieved in the reactor by using a recirculating
pump to force the mixture through the reactor.
454
Hydrofluoric Acid Processes
455
Hydrofluoric Acid Processes
In portions of the process system where it is possible to have
HFwater mixtures, the process equipment is fabricated from
Monel metal or Monel-cladsteel. The other parts of the
system are carbon steel.
456
Hydrofluoric Acid Processes
In portions of the process system where it is possible to have
HFwater mixtures, the process equipment is fabricated from
Monel metal or Monel-cladsteel. The other parts of the
system are carbon steel.
457
Hydrofluoric Acid Processes Yields
458
Alkylate Properties
459
Sulfuric Acid Alkylation Process
460
Sulfuric Acid Alkylation Process
There are two major processes that use sulfuric acid as
catalyst.
461
Sulfuric Acid Alkylation Process
Olen feed or a mixture of olen feed and isobutane feed is
introduced into the mixing compartments.
462
Sulfuric Acid Alkylation Process
In the Stratco, or similar type of reactor system, pressure is
kept high enough 310420 kPag to prevent vaporization of
the hydrocarbons.
In the first process, acid and iso butane enter the rst stage of
the reactor and pass in series through the remaining stages.
463
Sulfuric Acid Alkylation Process
Then the olen feed is mixed with the recycle isobutane and
introduces the mixture into the individual reactor sections.
464
Sulfuric Acid Alkylation Process
The remainder of the liqueed hydrocarbon is sent to a
depropanizer column for removal of the excess propane
which accumulates in the system.
465
Sulfuric Acid Alkylation Process
The acid is removed from the system for reclamation, and the
hydrocarbon phase is pumped through a caustic wash
followed by a water wash to eliminate trace amounts of acid
and then sent to a deisobutanizer.
466
Autorefrigeration sulfuric acid alkylation unit
467
Sulfuric Acid Alkylation Process
The efuent refrigeration process (Stratco) uses a single-stage
reactor in which the temperature is maintained by cooling
coils.
468
Stratco contactor
469
Sulfuric Acid Alkylation Process
Emulsion removed from the reactor is sent to a settler for
phase separation.
470
Sulfuric Acid Alkylation Process
The ashed gases are compressed and liqueed, then sent to
the depropanizer where LPG grade propane and recycle
isobutane are separated.
471
Sulfuric Acid Alkylation Process
A separate distillation column can be used to separate the n-
butane from the mixture or it can be removed as a side
stream from the deisobutanizing column.
472
Sulfuric Acid Alkylation Process yields and qualities
473
Polymerization
474
Polymerization
Propene and butenes can be polymerized to form a high-
octane product boiling in the gasoline boiling range.
475
Polymerization
But was supplanted by the alkylation process after World War
II.
476
Polymerization
And the product has a high octane sensitivity, but capital and
operating costs are much lower than for alkylation.
477
Polymerization Reactions
while iC4H8 reacts to give primarily diisobutylene, propene
gives mostly trimers and dimers with only about 10%
conversion to dimer.
478
Polymerization Reactions
The most widely used catalyst is phosphoric acid on an inert
support.
Sulfur in the feed poisons the catalyst and any basic materials
neutralize the acid and increase catalyst consumption.
479
Polymerization Reactions
Oxygen dissolved in the feed adversely affects the reactions
and must be removed.
480
The process
The feed, consisting of propane and butane as well as
propene and butene, is contacted with an amine solution to
remove hydrogen sulde.
481
The process
Finally, a small amount of water (350400 ppm) is added to
promote ionization of the acid.
482
The process
The propane and butane in the feed act as diluents and a heat
sink to help control the rate of reaction and the rate of heat
release.
483
The process
Gasoline boiling range polymer production is normally 9097
wt% on olen feed or about 0.7 barrel of polymer per barrel
of olen feed.
The next slide has the process flow diagram for the (Universal
oil products company (UOP) unit. And the following has the
operating conditions.
484
The UOP Unit
485
Operating Conditions
486
The process
Insitut Francais du Petrole licenses a process to produce
dimate (isohexene) from propene.
487
The process
Dienes and triple bonded hydro-carbons can create problems.
488
The Insitut Francais du Petrole Unit
489
Product Blending
490
Product Blending
Increased operating exibility and prots result when renery
operations produce basic intermediate streams that can be
blended to produce a variety of on-specication nished
products.
491
Product Blending
The objective of product blending is to allocate the available
blending components in such a way as to meet product
demands and specications.
492
Product Blending
For example, if a rener sells about one billion gallons of
gasoline per year (about 65,000 BPCD; several reners sell
more than that in the United States).
493
Product Blending
Inventories of blending stocks, together with cost and physical
property data are maintained in the computer.
494
Product Blending
To ensure that the blended streams meet the desired
specications, stream analyzers measuring the properties of
the product are needed.
495
Product Blending
Blending components to meet all critical specications most
economically is a trial-and-error procedure.
496
Product Blending
Optimization programs permit the computer to provide the
optimum blend to minimize cost and maximize prot.
497
Reid Vapor Pressure
498
Reid Vapor Pressure
The desired RVP of a gasoline is obtained by blending n-
butane with C5 193C naphtha.
499
Reid Vapor Pressure
The theoretical method for blending to the desired Reid vapor
pressure requires that the average molecular weight of each
of the streams be known.
500
Reid Vapor Pressure
Vapor pressure blending indices (VPBI) have been compiled as
a function of the RVP of the blending.
501
Reid Vapor Pressure
In equation form:
502
Blending component values for gasoline blending
503
Octane Blending
Octane numbers are blended on a volumetric basis using the
blending octane numbers of the components.
504
Octane Blending
Blending octane numbers are based upon experience and are
those numbers which, when added on a volumetric average
basis, will give the true octane of the blend.
505
Octane Blending
The formula used for calculations is:
506
Blending For Other Properties
There are several methods of estimating the physical
properties of a blend from the properties of the blending
stocks.
507
Blending For Other Properties
The Chevron Research Company has compiled factors or index
numbers for vapor pressures, viscosities, ash points, and
aniline points.
The table in the next slide is for the blending values of octane
improvers.
508
Blending values of Octane improvers
509
Blending For Other Properties
Viscosity is not an additive property.
510
Blending For Other Properties
It is usually true to a satisfactory approximation that the
viscosity factor (VF) of the blend can be easily calculated by a
simple equation.
In equation form:
511
Cost Estimation
512
Cost Estimation
All capital cost estimates of industrial process plants can be
classied as one of four types:
1. Rule-of-thumb estimates.
2. Cost-curve estimates.
4. Denitive estimates.
The capital cost data presented in this work are of the second
typecost-curve estimates.
513
1- Rule Of- Thumb Estimates
The rule-of-thumb estimates are, in most cases, only an
approximation of the order of magnitude of cost.
514
1- Rule Of- Thumb Estimates
Some examples are:
515
2- Cost- Curve Estimates
The cost-curve method of estimating corrects for the major
deciency in the previous method.
516
2- Cost- Curve Estimates
This relationship was reported by Lang, who suggested an
average value of 0.6 for the exponent (X).
517
Major Equipment Factor Estimates
Major equipment factor estimates are made by applying
multipliers to the costs of all major equipment required for
the plant or process facility.
518
3- Major Equipment Factor Estimates
519
4- Definitive estimates
Denitive cost estimates are the most time-consuming and
difcult to prepare but are also the most accurate.
520
4- Definitive estimates
The number of man-hours for each construction activity is
estimated.
521
Summary Form For Cost Estimates
522
Summary Form For Cost Estimates
The items to be considered when estimating investment from
cost-curves are:
523
1- Storage Facilities
Storage facilities represent a signicant item of investment
costs in most reneries.
524
1- Storage Facilities
Installed costs for tank-farms vary from $60 to $80 per
barrel of storage capacity.
525
1- Storage Facilities
Installed costs for butane storage ranges from $90 to $120 per
barrel, depending on size.
Costs for propane storage range from $100 to $130 per barrel.
526
2- Land And Storage Requirements
Each renery has its own land and storage requirements.
527
2- Land And Storage Requirements
As the land area required for storage tanks is a major portion
of renery land requirements.
528
2- Land And Storage Requirements
The 25 days of product storage is based on a three-week
shutdown of a major process unit.
529
3- Steam Systems
An investment cost of $150.00 per lb/hr of total steam
generation capacity issued for preliminary estimates.
530
3- Steam Systems
Total fuel requirements for steam generation can be assumed
to be 1200Btu (LHV) per pound of steam.
531
4- Cooling Water Systems
An investment cost of $150.00 per gpm of total water
circulation is recommended for preliminary estimates.
Special costs for water supply and blow down disposal are not
included.
532
4- Cooling Water Systems
The daily power requirements (kWh/day) for cooling water
pumps and fans is estimated by multiplying the circulation
rate in gpm by 0.6.
533
4- Cooling Water Systems
This is also a signicant item and should not be overlooked.
534
5- Other Utility Systems
Other utility systems required in a renery are electric power
distribution, instrument air, drinking water, re water, sewers,
waste collection, and others.
535
Offsites
Offsites are the facilities required in a renery which are not
included in the costs of major facilities.
536
Offsites
Obviously, the offsite requirements vary widely between
different reneries.
537
Offsites
538
6- Special Costs
Special costs include the following: land, spare parts,
inspection, project management, chemicals, miscellaneous
supplies, and ofce and laboratory furniture.
539
7- Contingencies
Most professional cost estimators recommend that a
contingency of at least 15% be applied to the nal total cost
determined by cost-curve estimates of the type presented.
540
Escalation
541
Escalation
All cost data presented in this book are based on U.S. Gulf
Coast construction averages for the year 1999.
542
Escalation
Items which increase costs include major factors:
1. Increased cost of steel, concrete, and other basic materials.
543
Escalation
Items which tend to decrease costs are basically all related to
technological improvements
544
Plant Location
545
Plant location
Plant location has a signicant inuence on plant costs.
546
Thank you
547