Beruflich Dokumente
Kultur Dokumente
Crystallization
• Crystallization is an important operation in the chemical
industry as a method of purification and as a method of
providing crystalline materials in the desired size range
• For control
1) Yield of crystal’s
2) Purity of crystal’s
3) Sizes and shapes of crystal’s
Theory of crystallization :
1) Super saturation of the solution
a) It can be done by three ways.
b) Heating the solution
c) Cooling the solution Salting out
2) Nucleation
This takes place in several steps.
During their random motion, the atoms/ molecules/ ions will come
closer to one another and forms aggregates called as CLUSTERS.
These clusters will combine to form an EMBRYO. In this stage only the
lattice formation begins.
This embryo’s combine to form NUCLEI. From nuclei crystals are
formed
3) Crystal Growth
Once the crystals are formed, nuclei formation stops and crystal
growth begins.
Crystallization
The crystallization process consists of two major events:
Nucleation
Is the step where the solute molecules dispersed in the solvent start
together into clusters
Reference:
Handbook of Industrial Crystallization
By Allan Myerson
Crystallizer Designing
Parameters
1) Retention time
2) Minimum Active Volume
3) Sizing
4) Height of Cylinder
5) Height of Cone
Equipment Sizing:
Calculation Flow Diagram
Retention time
𝐿50
𝜏=
3.67𝐺
Equipment Sizing:
Calculation Flow Diagram
Retention time
Minimum Active Volume
𝐿50
𝜏= 𝑉𝑅 = 𝜏𝑉14
3.67𝐺
Equipment Sizing:
Calculation Flow Diagram
Retention time
Minimum Active Volume
𝐿50
𝜏= 𝑉𝑅 = 𝜏𝑉14
3.67𝐺
Sizing
𝑉𝑅 = 𝑉𝑐𝑜𝑛𝑒 + 𝑉𝑐𝑦𝑙𝑖𝑛𝑑𝑒𝑟
𝜋 2
𝑉𝑅 = 0.1868𝐷3 + 𝐷 (1.5𝐷)
4
Equipment Sizing:
Calculation Flow Diagram
Retention time
Minimum Active Volume
𝐿50
𝜏= 𝑉𝑅 = 𝜏𝑉14
3.67𝐺
Height of Cone
𝐷 0.1𝐷
ℎ = tan 550 ( − )
2 2 Sizing
𝑉𝑅 = 𝑉𝑐𝑜𝑛𝑒 + 𝑉𝑐𝑦𝑙𝑖𝑛𝑑𝑒𝑟
𝜋 2
𝑉𝑅 = 0.1868𝐷3 + 𝐷 (1.5𝐷)
Height of Cylinder 4
ℎ = 1.5𝐷
Mechanical Engineering Design
The selected material for the crystallizer is (stainless steel
316) due to its high corrosion resistance.
• Shell Thickness
3
𝑡
𝑃𝑐 = 𝐾𝑐 𝐸
𝐷𝑜
• Tori spherical Head Thickness
𝑃𝑒
𝑒 = 4𝑅𝑠
𝐸
Mechanical Engineering Design
• Cone Thickness
3
𝑡𝑐𝑜𝑛𝑒
𝑃𝑐 = 𝐾𝑐 𝐸
𝐷𝐿
• Corrosion Allowance: 2 mm
Mechanical Engineering Design
𝑊𝑡 𝐻 𝑅
𝑆1𝑡 = 2 [𝑐𝑜𝑠𝛼 −𝐾1 + 6𝐾2 + (−𝐾3 + 6𝐾4 )
𝑡 𝑅 𝑡
𝑊𝑡 𝐻 𝑅
𝑆1𝑐 = [𝑐𝑜𝑠𝛼 −𝐾1 − 6𝐾2 + (−𝐾3 − 6𝐾4
𝑡2 𝑅 𝑡
Mechanical Engineering Design