Beruflich Dokumente
Kultur Dokumente
• Photo product quantum yield Xenon monochomater (300 nm) and characterize the products (azo
benzene and ferrioxalate standards characterise using HPLC)—All NO2-Bn systems
O
ON S CH
3
H
O
N
O2
NO
NO 2
-
C H 3S O 2
CHO
C H 3S O 2N H 2
NO
• Reactant Concentration is independent of formation of products-Laser flash photolysis to
find intermediates finally mechanism (N-O bond cleavage methane sulphonamide and
nitro benzaldehyde are the products)
HO
M
eO N Me
O S
O
M
eO N
O2
H O
N M e
O S
O
N O 2
H O
N M e
O S
O
• HNO detection by vibrational spectroscopy DFT calculation to electron density movement and
• S0NO2(n,π) S1 or T1NO2(n,π*) based on the LFP data
• Use of TXPTS trap for (will be checked)
HO H
O
NC
F3Me
O NC
F
OS 3
O
S
O O
N
O
2 M
eO
OMe OMe
OMe
k
hv H+
H2O O
O N
NO2 N
OH O
(a) (b) (c)
OMe OMe
CHO
OH
O MeOH
N N O NO
OH
(e) (f)
(d)
s
CHO
H H O
O H
O
H
N S R hv .
O S
.N S R
H O
O
RSO2NH2
O O
O H
O
H
N S R hv
C O .. N H S R C H
O R S O 2N H 2
O O H
N O 2
N N O
O O
O
H
O O O N S CH3
H H
O N S CH3 hv O N S CH3 O
O O
O
NO2 N O
N
OH O H
NO
CH3SO2- HNO
O O
H H
O N S CF3 hv O N S CF3 CHO
O CF3SO2NH2
O
NO2 N O
NO2
O
H
Photolysis of o-NBOC-ONHSO2CH3 (24)
5%
70%
25%
8
LC-MS results
Photolysis of
CHO
NO 2
Photolysis of
O
ON S CH
3
H
O
N
O2
O
ON S CH
3
H
O
N
O2
Photolysis of NB-ONHSO2CH3
BLANK
NB-ONHSO2CH3
METHANE SULFONAMIDE didn’t show up in a
negative mode!
CH3SO2NH2
O O
H H
CHO O N S C H 3 h v O N S C H 3 C H O
Photolysis of N O
O
N O
O C H 3 S O 2 N H 2
2
NO 2 N O 2
O
H
h v
C O O H
N O