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This document discusses solubility equilibria and Ksp expressions. It provides examples of dissolution reactions for salts such as AgCl, Mg(OH)2, and Ca3(PO4)2. Standard methods are described for determining Ksp experimentally from solubility data and for predicting solubility and precipitation based on Ksp values and ion concentrations. The common ion effect on solubility is also explained.
This document discusses solubility equilibria and Ksp expressions. It provides examples of dissolution reactions for salts such as AgCl, Mg(OH)2, and Ca3(PO4)2. Standard methods are described for determining Ksp experimentally from solubility data and for predicting solubility and precipitation based on Ksp values and ion concentrations. The common ion effect on solubility is also explained.
This document discusses solubility equilibria and Ksp expressions. It provides examples of dissolution reactions for salts such as AgCl, Mg(OH)2, and Ca3(PO4)2. Standard methods are described for determining Ksp experimentally from solubility data and for predicting solubility and precipitation based on Ksp values and ion concentrations. The common ion effect on solubility is also explained.
FeCl3 (s) Fe 3+ (aq) + 3 OH - (aq) Ksp = [Fe3+ ][OH- ]3 = 2.0 10-39 Standard Types Determining if a precipitation will occur: Determining if a precipitation will occur:
If 5.0 mL of 1.0 x 10-3 M NaCl is added to 1.0 mL of 1.0 x 10-3 M Pb(NO3)2,
will solid PbCl2 (Ksp = 1.7 x 10-5) precipitate? If a precipitate will not form, what chloride ion concentration will cause a precipitate of lead chloride to form? Determining if a precipitation will occur:
If 5.0 mL of 1.0 x 10-3 M NaCl is added to 1.0 mL of 1.0 x 10-3 M Pb(NO3)2,
will solid PbCl2 (Ksp = 1.7 x 10-5) precipitate? If a precipitate will not form, what chloride ion concentration will cause a precipitate of lead chloride to form? Common Ion Effect: The presence of an ion common to a solubility equilibrium will decrease solubility of the salt.
What is the solubility of PbCl2 in pure water and
in a 0.200 M NaCl solution? (Ksp = 1.7 x 10-5) Common Ion Effect: The presence of an ion common to a solubility equilibrium will decrease solubility of the salt.
Critical Evaluation of Equilibrium Constants Involving 8-Hydroxyquinoline and Its Metal Chelates: Critical Evaluation of Equilibrium Constants in Solution: Part B: Equilibrium Constants of Liquid-Liquid Distribution Systems
Coordination Chemistry—XIV: Plenary Lectures Presented at the XIVth International Conference on Coordination Chemistry Held at Toronto, Canada, 22—28 June 1972