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where VA is the molar volume of component A in solution
which is the volume divided by the number of moles of A.
Using ideal gas law and , μA can be related to the partial
vapor pressure by:
PB = kXB
Where
where the i factor is the ratio of number of total moles after the
solution to the number of moles before the solution. For non-
electrolytes i = 1.
(b) At 47.39 kPa water boils at 80◦C. From the Dühring plot, the
boiling point of 10% NaCl solution for the pressure yielding boiling
point of water at 80◦C can be read as 83◦C. Therefore, the
boiling point elevation is:
∆TB = 3◦C
(B) Freezing Point Depression
When equilibrium exists between solid A and its solution,
the chemical potentials of A must be the same in both
phases:
μ S A = μ LA
For small freezing point depression:
where
In freezing point depression, the term (wB/wAMB) is
expressed in terms of molality as (m/1000).
Then equation becomes:
μA(solution, P + π) = μA(solvent, P)