14/15 Semester 5

Computational Method in
Chemical Engineering
(TKK-2109)

Instructor: Rama Oktavian

Email: rama.oktavian@ub.ac.id
Office Hr.: M.13-15, T. 13-15, W. 13-15, F. 13-15
 HYSYS for unit operation
Pump

Problem statement

Water at 120 C and 3 bar is fed into the pump.

The flow rate 100 kgmole/h and the outlet
pressure is 84 bar. Using Peng-Robinson EoS,
determine the outlet temperature of the water.
 Simulasi pada Unit Operasi
 Start HYSYS dengan NEW CASE
 Pilih Komponent Components Tab, add component pada CASE
 Jika komponen tidak ada pada library, pilih Hypothetical
button dan HYSYS akan memprediksi property component
tersebut secara thermodynamic berdasarkan input yang
saudara inputkan
 Fluid Package = Property Package+Component List
 Pemilihan property package sesuai dengan komponen

Thermodynamic models
Selesai memilih Fluid Package perhatikan
apakah parameternya tersedia!
Procedure

 Buat Stream,
 kemudian klik Stream
 Isikan kolom-kolom pada stream
tersebut dengan memperhatikan
degree of freedom dari sistim.
Klik Stream
 Procedure

 Install pump pada PFD

• Double klik pada pompa (P-100)

 Procedure

 Hubungkan pompa dengan stream

 Pada inlet pilih Feed dan pada outlet
pilih Outlet

• Pada kolom enenrgy ketik work

 HYSYS for unit operation
Compressor

Problem statement
 Simulasi pada Unit Operasi
 Start HYSYS dengan NEW CASE
 Pilih Komponent Components Tab, add component pada CASE
 Fluid Package = Property Package+Component List
 Pemilihan property package sesuai dengan komponen

Thermodynamic models
 Simulasi pada Unit Operasi
 C7+ tidak ada dalam list HYSYS maka didefinisikan sendiri
dengan hypothetical component

Procedure:
- Click hypothetical and Quick Create Hypo Component
 Simulasi pada Unit Operasi
 Click ID..isikan nama component dengan C7+
 Simulasi pada Unit Operasi
 Add hypo
Procedure

 Buat Stream,
 kemudian klik Stream
 Isikan kolom-kolom pada stream
tersebut dengan memperhatikan
degree of freedom dari sistim.
Klik Stream
Procedure

 Install compressor pada PFD

• Double klik pada kompressor
Procedure

 Click parameter tab

• Change adiabatic efficiency to 30%
Procedure

 Click worksheet tab

• Input all the conditions
 HYSYS for unit operation

Heat exchanger available in HYSYS

 Cooler/Heater
 Air Cooler
 Heat Exchanger
 Fired Heater
 LNG
 Cooler/Heater

17
Dr. Heru Setyawan, Jurusan Teknik Kimia FTI-ITS
 Heat Exchanger

Dr. Heru Setyawan, Jurusan Teknik Kimia FTI-ITS

Heat Exchanger

19
 Heat Exchanger

Dr. Heru Setyawan, Jurusan Teknik Kimia FTI-ITS

 HYSYS for unit operation
Heat exchanger (Shell and Tube)

Problem statement
 Simulasi pada Unit Operasi
 Start HYSYS dengan NEW CASE
 Pilih Komponent Components Tab, add component pada CASE
 Fluid Package = Property Package+Component List
 Pemilihan property package sesuai dengan komponen

Thermodynamic models
Procedure

 Buat Stream,
 kemudian klik Stream
 Isikan kolom-kolom pada stream
tersebut dengan memperhatikan
degree of freedom dari sistim.
Klik Stream
Procedure

 Install heat exchanger pada PFD

• Double klik pada heat exchanger
Procedure

 Click parameter tab

• Set no pressure drop in Shell and
Tube
Procedure

 Click worksheet tab

• Input all the conditions
 FLASH SEPARATOR
 Description:
 Find the flowrate of the liquid and vapor outlet streams of
the flash separator
 Operate a flash separator in HYSYS to model the flash
separation process

 A flash separator is performed to determine the

product conditions and phases
 FLASH SEPARATOR
Liquid at a pressure equal to or greater than its bubblepoint
pressure “flashes” or partially evaporates when the pressure is
reduced, producing a two-phase system of vapor and liquid in
equilibrium.

Consider a simple process in which a multicomponent feed is

allowed to separate into a vapor and a liquid phase with the
phases coming to equilibrium, as shown in Figure below
 FLASH SEPARATOR
An overall material balance and component material balances can
be written as:
F=V+L
Fzi = Vyi + Lxi
where F = feed flowrate (kmol·s−1)
V = vapor flowrate from the separator (kmol·s−1)
L = liquid flowrate from the separator (kmol·s−1)
zi = mole fraction of Component i in the feed (–)
yi = mole fraction of Component i in vapor (–)
xi = mole fraction of Component i in liquid (–)
 FLASH SEPARATOR
Consider a system containing one mole
The material-balance equations are:
L+V=1
zi  xi L  yiV
zi  xi (1  V )  yiV
y
Dengan K i  yi , , subtituting
xi  i
Ki
xi
zi K i
yi 
1  V ( K i  1)

since  y 1
i i
zi K i
i 1  V ( K  1)  1
i
 Flash Calculation of a ethanol-water
mixture
• Mulai dengan new case
• Pilih components ethanol and water
• Pilih FLUID PACKAGE yang sesuai (UNIQUAC) dan check parameter
dari UNIQUAC apakah tersedia, kalau tidak tersedia apa implikasinya
apa dan hal apa yang harus dilakukan?
• Enter Simulation environment manager dan buat stream dan namai
stream tersebut
• Buat perhitungan flash untuk mendapatkan distribusi uap dan cairan
jika kondisi feed adalah F= 100 kgmole/h, P= 150 kPa danT=92 deg
C. Dengan menekan F12 dan memilih vessel terus separator dan beri
nama stream keluar Vapor dan Liquid, untuk inlet pasang Feed.
Flash Calculation of a ethanol-water
mixture
Flash Calculation of a ethanol-water
mixture
Flash Calculation of a ethanol-water
V
mixture

L
Flash Calculation of a ethanol-water
mixture
 HYSYS for unit operation
Conversion reaction

Problem statement
 Simulasi pada Unit Operasi
 Start HYSYS dengan NEW CASE
 Pilih Komponent Components Tab, add component pada CASE
 Fluid Package = Property Package+Component List
 Pemilihan property package sesuai dengan komponen

Thermodynamic models
Procedure

 Adding the reactions

Procedure

 Click add rxn and choose conversion,

• Input all stoichiometry coefficient
• Click basis and input the conversion
value
 HYSYS for unit operation
Distillation column

Problem statement

A binary liquid stream containing 70 mass percent

Benzene and the rest Toluene entering at 30ºC and 1
atm flowing at a rate of 1 kg-mol/sec will be distilled to
ultra pure distillate and bottoms streams.
 Simulasi pada Unit Operasi
 Start HYSYS dengan NEW CASE
 Pilih Komponent Components Tab, add component pada CASE
 Fluid Package = Property Package+Component List
 Pemilihan property package sesuai dengan komponen

Thermodynamic models

Component: Benzene and Toluene

Property package: Peng-Robinson

Setting distillation column

 Buat Stream, install distillation

column kemudian double click
Setting distillation column

 Buat Stream, install distillation

column kemudian double click
Setting distillation column

 There are no pressure drop in condenser and reboiler, the

whole process run at 101.3 kPa
Setting distillation column

 specify the reflux ratio and distillate flow rateA refux ratio of 3
and a distillate flow rate of 2700 kgmol/hr and then click Done
Setting distillation column

 Specify number of trays and feed tray

Setting distillation column

 Specify feed condition, an inlet temperature of 30 C, a pressure

of 101.3 kPa, a flow rate of 1 kg-mol/sec, and a feed with 70
mass % benzene
Setting distillation column

 Double click again distillation column and click Run until it is

converged