Beruflich Dokumente
Kultur Dokumente
P2V2 P1V1
W PV const.
1
P1 ,T1 P2 , V2 , T2
Pf , V f , T f
Equation of state for real gases
PV
Z 1 BP C P 2
RT
or specific volume
PV B C
Z 1 2
RT V V
RT B C RT B C
V 1 2 Vn 1 1 2
P V V P V V
n n
Cubic equation of state
Cubic equations were developed to explain behavior of both
liquid and vapors
RT a
P 2 (van der Waal’s equation)
V b V
Isotherms in van
der Waals equation
Other cubic equations of state
1) Redlich-Kwong (1949)
2) Soave-Redlich-Kwong (1972)
3) Peng-Robinson (1976)
RT a (T )
P
V b (V b)(V b)
Example – using cubic equation of state
Q: Find the molar volume of n-pentane at T = 100oC and P = 1bar.
The Peng-Robinson parameters for n-pentane at this temperature
are a = 2.417 *107 bar cm6/mol2 and b = 90.18 cm3/mol
RT a
Peng-Robinson EOS P
V b V (V b) b(V b)
P
Pc
V / VC
Tr = 1.1
Pr = 2
PV
Z 0.4
RT
V 1.6 10 4 m 3