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Z
X
Basic Notation
A
Z
X
• is a specific nucleus, X is chemical symbol.
A
X * is in an excited state
Z
The Nucleus.
92
U U
92
Example: Isomers
113 113m
49
In In
49
Atomic mass unit.
The Masses of the three primary
atomic subparticles are.
6.5 x 10 -19 j
C + O2 = C O2 + 4 ev
Nuclear Reactions vs. Chemical
Reactions.
A nuclear reaction can be expressed as,
A1 A2 A3 A4
A + B C + D
z1 z2 z3 z4
where A and C are the initial and final nuclei, B is the
incident particle or light nucleus (projectile) and D is the
emitted particle, light nucleus or photon
Z1+Z2=Z3+Z4 & A1+A2=A3+A4
In nuclear reactions, the product do not have the same
reactant nuclei but some other nuclei. The number of
nucleons in the product are the same as those in the
reactants.
Nuclear Reactions vs. Chemical
Reactions.
Sometimes, Electromagnetic radiations (γ-
rays) and neutrino(ν) are often emited but
they do not effect the balance, since only
they carry energy.
Example:
235U + n --> fission + 2 or 3 n + 200 MeV
Beta particles are very 'light' and move fairly fast. They
are not as strongly ionizing as alpha particles as they
cannot knock electrons off atoms as easily.
Δ N = - λ N Δ t,
where is called the decay constant. Note that has units of inverse time, or s
- 1. The decay rate, R , is defined as the number of decays per unit time:
…………………………………..
Nuclear Fission.
Fission may be defined as the process of splitting
an atomic nucleus into fission fragments
The fission fragments are generally in the form of
smaller atomic nuclei and neutrons
Large amounts of energy are produced by the
fission process
There are 2 types of fission that exist:
1. Spontaneous Fission
2. Induced Fission
Nuclear Fission.
Fissile nuclei are generally heavy atoms with
large numbers of nucleons
The nuclei of such heavy atoms are struck by
neutrons initiating the fission process
Fission occurs due to electrostatic repulsion
created by large numbers of protons within
the nuclei of heavy atoms
Nuclear Fission.
Spontaneous Fission
• Some radioisotopes contain nuclei which are
highly unstable and decay spontaneously by
splitting into 2 smaller nuclei.
• Such spontaneous decays are accompanied
by the release of neutrons.
Induced Fission
1 235
0 n 92 U
The Fission Process
A neutron travels at high speed towards a uranium-235
nucleus.
1 235
0 n 92 U
The Fission Process
A neutron travels at high speed towards a uranium-235
nucleus.
1 235
0 n 92 U
The Fission Process
The neutron strikes the nucleus which then captures the
neutron.
1 235
0 n 92 U
The Fission Process
The nucleus changes from being uranium-235 to
uranium-236 as it has captured a neutron.
236
92 U
The Fission Process
The uranium-236 nucleus formed is very unstable.
1
0 n
141
56 Ba
1
0 n
92
36 Kr
1
0 n
The Fission Process
It then splits into 2 fission fragments and releases
neutrons.
1
0 n
141
56 Ba
1
0 n
92
36 Kr
1
0 n
The Fission Process
It then splits into 2 fission fragments and releases
neutrons.
1
0 n
141
56 Ba
1
0 n
92
36 Kr
1
0 n
The Fission Process
It then splits into 2 fission fragments and releases
neutrons. 1
0n
141
56 Ba
1
0 n
92
36 Kr
1
Nuclear Fission Examples
235 1 141 92 1
92
U + 0
n 56
Ba + 36
Kr + 3 0
n
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Nuclear Fission.
Countries Generating Most Nuclear
Power
Country Total MW
USA 99,784
France 58,493
Japan 38,875
Germany 22,657
Russia 19,843
Canada 15,755
Ukraine 12,679
United Kingdom 11,720
Sweden 10,002
South Korea 8,170
Radioactive Decay & Half Life Time.
• Fast Spectrum of fission neutrons 1-10 MeV, 2MeV is
typical
•
• Slow or thermal Slowed to thermal equilibrium
•
• 0.0253 eV at 20°
• C
•
• Epi-thermal
•
• anything in between
Radioactive Decay & Half Life Time.
Radioactive Decay & Half Life Time.
Radioactive Decay & Half Life Time.
Atomic Structure.
………
……
……..
Atomic Structure.
………
……
……..
Atomic Structure.
………
……
……..
Basic Notation
Uranium Basics
Natural uranium ore mined
– Usually found as U3O8
Contains a mixture of isotopes
U-238 is not fissionable
• makes up 99.3%
– U-235 is easily fissionable
• makes up 0.7%
Nuclear Basics
• Nearly all reactor require enriched uranium
– Most require 3% to 5% U-235
• Some newer reactors can run on natural U
• Nuclear weapons require >90% U-235
Enrichment Methods
• Four main methods have been used
– Gaseous diffusion
– Gas centrifuges
– Jet nozzle or aerodynamic separation
– Electromagnetic separation
• Laser and chemical methods also exist
– Under development; not commercially feasible
Conversion
• Uranium ore (U3O8) must be converted to
UF6 before the enrichment process