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PRE-REQUISITE
1. Show ELASTicity
ELASTO-MERS
Rubbers and elastomers are synonym
Highly amorphous
Highly random orientation
High elongation
GENERAL PROPERTIES OF RUBBERS
• The most often used item for this stabilization is ammonia (HA latex –
maximum 0.7 % NH3). It is long term preservation
Some rubber products (e.g. foam rubber, gloves, glues) are produced directly
from latex.
The latex is modified for these reasons to have higher dry rubber content
(DRC) values (minimum 60 – 65 % of rubber).
There are few methods that can be used to concentrate natural rubber latex:
Concentration by creaming
Concentration by centrifugation & sedimentation
Concentration by evaporation
electro-decantation is used.
• Hardness
• Stress-Strain properties (Tensile strength)
• Abrasion resistance
• Set properties
• Resistance to cut growth, fatigue, flex cracking
• Resistance to degradation by
Heat, Oxygen, Ozone
Flame
Liquids
Light
• Miscellaneous property requirements
Low temperature flexibility
Electrical properties
Permeability
Contact with food stuff and drugs
Bonding to metal & textiles
Swelling
Other specific requirements
The chemicals used in latex compounding can be divided
into three general classifications:
The vulcanization or curing process occurs in three stages and each stage
is of importance and affects the service life of the finished product:
(1) Induction or flow time (Scorch resistance)
(2) Crosslinking or rate of cure
(3) Optimum state of cure or overcure
The cross-links are even not created or only a little. Its length depends on
the type of vulcanization system and vulcanization temperature. In the
case of sulfur vulcanization it is affected by present accelerators,
eventually vulcanization retarders or pre-cure inhibitors.
2. Crosslinking or rate of cure. The second stage is
the main vulcanization stage which is fast curing of
rubber macromolecules and the formation of ones'
own vulcanizate. That is why the vulcanization rate
can be considered as the rate of this stage.. Once
vulcanization begins, it should be completed as fast
as possible in order to have practical batch cycle.
Optimal vulcanization time is the difference between
maximum and minimum torsion moment
3. The third stage of the curing or vulcanization process is a point
at which all technological properties of the rubber compound
are forming and is necessary to cure the rubber compound to
its “optimum state of cure” (maximum stress value), but not
past that point—“overcure.” It must stop at the right time .
Compounding
Mixing
Shaping
Vulcanizing.
VULCANIZATION
http://www.tutorvista.com/content/chemistry/chemistry-
ii/carbon-compounds/natural-rubber.php
http://rubberboard.org.in/ManageCultivation.asp?Id=196