WATER ANALYSIS -ADSORPTION- AHMAD ZULHAFIZAM BIN AHMAD ZAINI_2016691894 MOHAMAD HEIRY MOHD AZMI_2016691928
NUR ANINA ASMIRA BINTI ASMURI_2016691932
BACKGROUND _ INTRODUCTION Dyeing industry is one of the largest water consuming industries. The effluent coming out of the dyeing industries contains various chemicals and colouring compounds and the effluent requires proper treatment before it is discharged into any water body. But, the dye house effluents are very difficult to treat satisfactorily because they are highly variable in composition. There are various type of dye (e.g. methyl blue, methyl orange) have been applied in different industries [1]. The discarding of coloured wastes into the water bodies damages the environment and toxic to human and aquatic life. The wastewater contains very high concentration of COD and BOD; and huge amount of suspended solids and other contaminants. Most sophisticated methods are required for treating wastewater in textile industries [2]. Methods such as chemical, coagulation, flocculation, reverse osmosis, nano‐filtration, Ultra‐filtration have been recommended. However these methods are very much complex and expensive. Adsorption has gained supreme importance for environment protection by removing textile dyes from disposed water. Some of the adsorbents are effective in removing dyes and various pollutants, but some are not. That is why, new effective adsorbents are needed which should be cost effective, energy efficient, design flexible, biodegradable and available [3] BACKGROUND _ PROBLEM STATEMENT Synthetics dyes are mostly xenobiotic compounds [4]. The natural system of microorganism in water do not contain specific enzymes for degradation of these compounds. The dyes and their by- products are carcinogenic and mutagenic [5]. Besides that, the pollution of water by dyes alters biological cycle of photosynthesis [6]. Efficient technologies of effluent treatment are necessaries to minimize environmental impact. The removal of color is necessary for the reuse of water from dyeing process[7]. The methods for decolorization dyes involve various technologies due to the complexity[8]. So, among the best technologies to treat the dyes is adsorption. This experiment will focus on the adsorbent dosage to determine the adsorbate capacity for a given amount of adsorbate. It can be carried out by prepare adsorbent-adsorbate solution with different amount of adsorbents added to fixed initial dye concentration then shaken together until equilibrium time. OBJECTIVES 1. To determine the effect of removal efficiency of methyl-blue dye on different adsorbent dosage via adsorption process.
𝐹𝑖𝑛𝑎𝑙 𝐶𝑂𝐷 −𝐼𝑛𝑖𝑡𝑖𝑎𝑙 𝐶𝑂𝐷
% Removal = × 100% 𝐼𝑛𝑖𝑡𝑖𝑎𝑙 𝐶𝑂𝐷 PROCEDURE Initial COD for dye solution will be test The effect of first using DB200 adsorbent dosage on Reactor at 150ºC for the removal of MB 30 minutes and was studied with check the value by Batch adsorption different adsorbent using UV- experiments will dosages (0.2–1.0 g) Spectrophotometer. carried out in 250 mL in a 100 mL dye Further flasks and the total solution of 10 ppm experimental volume of the concentration, pH 6.0 procedure will Fresh stock reaction solution was and shaken till carried out for COD solution is prepare kept at 100 mL. The equilibrium time. test to determine in 1L Volumetric flasks were shaken at the final COD of dye flask with the 200 rpm for an after the adsorption mixture of 5mg equilibrium time of process and methylene blue 25 min on a calculate the Coconut shell and distilled mechanical shaker. removal efficiency. activated water. The carbon is adsorbate is pour prepare with about 500ml of 10 varies ppm adsorbent concentration in dosage (0.2, 250ml erlenmeyer 0.4, 0.6, 0.8, flask. 1.0g)/0.1L RAW DATA TABLE Table 1: Raw Data of Methyl Blue Dye Removal at Varies Adsorbent Dosage Via Adsorption Method
Adsorbent Initial COD Final COD % Removal
dosage value (mg/L) Value (mg/L) (g) 0.2 0.4 0.6 0.8 1.0 REFERENCES 1. L.G. Beslin, Textural Features - Indicators of Pollution, J. Environ. Anal. Toxicol. 07 (2017). 2. [2] R. FBA, A. M, Removal of Dyes Form Textile Wastewater by Adsorption using Shrimp Shell, Int. J. Waste Resour. 6 (2016). 3. [3] Shelley, M.L., Randall, C.W. and King, P.H., Evaluation of Chemical-Biological and Chemical-Physical Treatment for Textile Dyeing and Finishing Waste, Journal WPCF, 4, 753, 2006 4. Tchobanoglus G, Burton F.L, Stensel H.D,Wastewater Engineering- Treatment and Reuse (2002) 5. F.S.C.Andrea, D.C.Clarissa,A.S.Alexander, A.S.Leonie, Color removal from industrial dyeing and laundry effluent by microbial consortium and coagulant agents, Process Safety and Environment 118 (2018)203- 210 6. Dellamatrice,Monteiro, Decolorization and toxicity of municipal waste by horseradish, Quimica Nova 29 (2006)419-421. 7. J.Arnal, M.Lora, J.Gonzalev, Ultrafiltration as a pre-treatment of other membrane technologies in the reuse of textile wastewater, Desalination 221 (2004) 405-412. 8. G.Sudarjanto, B,Keller, Optimization of integrated chemical-biological degradation of a recative azo dye using response surface methodology, Journal Hazard Matter 138 (160-168)