Beruflich Dokumente
Kultur Dokumente
Group member
Dilpreet, Digvijay Singh, Govardhan,
Happy devi, Bhupinder
Simplified notation
H2O(l) H+ (aq) + OH-(aq)
What is pH?
It is the measure of hydrogen ions in solution
pH LogH 3O
pH=14.0
What is pH?
pH LogH 3O
Basic
pH=7.0 Neutral
pH Log H
Acidic
pH=1.0
What are some of the ways to
measure pH?
1. Using an acid-base indicator
2. Using pH paper
3. Using pH meter
4. ……………..
What are acid-base indicators?
How do they work?
An organic dye, whose color depends on the
concentration of H3O+ or pH
K eq 3 eqb eqb
K eq 3 eqb eqb
HA c eqb
Ionization constant of an acid
H O A
K eq 3 eqb eqb
HA c eqb
H O A
K a K eq c 3 eqb eqb
HA eqb
H O A
Ka 3 eqb eqb
HA eqb
Ka 3 eqb eqb
HA eqb
H O A
HA eqb
Since Log
(ab) b
can be written as Log (a) Log
c c
[A ]
[ HA]
but, LogKa pK and LogH O pH
a 3
[A ]
pK a pH Log
[ HA]
Ionization constant of an acid
[ A ]
pK a pH Log
[ HA]
[A ]
pH pK a Log
[ HA]
Henderson-Hasselbach equation
In the above equation, if we can make the [A-] = [HA]
[ HA]
pH pK a Log
[ HA]
Ionization constant of an acid
[ HA]
pH pK a Log
[ HA]
pH pKa 0
pH pKa
Vinitial Vfinal- Vinitial =Vused
100mL
Mix the solution in
volumetric flask to the
1.0 g of HA
Solution in the erlenmeyer
In 100mL of flask
water
250mL
Measure the pH of the
250mL
final solution with
50 mL of HA indicators and pH paper
+ 2 drops phenolphthalein