Beruflich Dokumente
Kultur Dokumente
(Sem-III)
Chemistry Paper-III
Paper Code No. CECH-303 (Inorganic
Chemistry)
Unit-I
Wave Mechanics
de Broglie Hypothesis
Dualism of Light
• Light has dual nature (Dualism of Light)
E = h ν -------- (1)
Where,
E= Energy
h= Planck’s constant = 6.626 X 10-34 J s
ν= frequency of the radiation
m= mass of the matter
c= velocity of light
• Comparing the two equations we can write
mc2 = h ν
mc2 = h c/ λ
λ = h/mc ----------(3)
de Broglie replaced ‘c’ the velocity of light in equation (3) with the velocity of light
‘v’ and expressed the wave length associated with a material particle as
λ = h/m v ----------(4)
λ = h/m v -------(4)
or
λ = h/p
y = g (x)
y = F (x)
y= ψ (x)