Beruflich Dokumente
Kultur Dokumente
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Nổ kho phế liệu ở Bắc Ninh
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Chemistry for fund…
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• Arrangement of electrons in space around the nucleus
• Electron energy
(thus related to its physical and chemical activity)
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1. The wave nature of light
Wavelength =distance
between 2 maxima
Amplitude = maximum
intensity
Period = time between 2
maxima (seconds)
Frequency = number of
periods per second
= 1/period
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λ = distance traveled during one period
So λ =speed x period = speed/frequency
E = energy (J)
h = Planck’s constant 6.63 x 1034 J . s
ν = frequency of the radiation (Hz) 15
Photons
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Einstein 1905: a revolutionary theory
BOTH !
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Line Spectra
SPECTRUM
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Continous spectrum: a rainbow of colors, containing light of
all wavelengths
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He balloons
Xmas in Lab
(Ar balloons provide inert atmosphere for experiments)
• Arrangement of electrons in space around the nucleus
• Electron energy
(thus related to its physical and chemical activity)
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He, Ne, Ar are inert gases
Li, Na, K are soft, very active (violently reaction with water or O2)
h - Planck's constant
c - the speed of light Energies are negative since
RH – Rydberg’s these are bound states: positive
constant
energy must be given to extract
the electron
Only the specific frequencies of light that have an
energy (hν) = energy difference between states
can be absorbed or emitted by the atom.
Energy
Photon hν
Photon hν E1 emitted
absorbed
E2
Electron is promoted (excited) Electron de-excites to a
to a higher energy state lower energy state
CONSERVATION OF ENERGY :
Photon energy is the difference between the 2 states
hν = E1-E2 (higher- lower)
If a compound X absorbs the photon λ1,
it will emit photon λ2 where:
A) λ1 = λ2
B) λ1 > λ2
C) λ1 < λ2
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There are many possible
transitions between
allowed states but always
hν = E1-E2 (higher –lower)
Line spectrum
h
where
mu
λ = wavelength “associated” to the particle
m = mass (kg) for an electron moving at 5.0×106 m/s
u = velocity (m/s) λ= 1.46×10−10 m (0.146 nm). Quite small !
So not detected earlier…
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QUANTUM MECHANICS : THE PHYSICS OF
MATTER WAVES
Example of an electron
density distribution
n, ℓ, and mℓ
Quantum numbers
If n increases,
- the orbital becomes larger
- the electron spends more time farther from the
nucleus
- the electron has a higher energy
- the electron is less tightly bound to the nucleus
ℓ = angular momentum quantum number, has
integer values from 0 to (n - 1) for
each value of n
( for instance if n=1 ℓ =0 ; if n=3 ℓ can be 0, 1, 2 )
ℓ defines the shape of the orbital
Orbitals are named s, p, d, f depending on the
value of ℓ :
sharp
principal
diffuse
Orbital name fundamental
mℓ = magnetic quantum number
-ℓ and ℓ, including 0
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How to manage these quantum numbers ?
n= 1, 2, 3… 0 ≤ ℓ ≤ n-1 - ℓ ≤ ml ≤ +ℓ
if ℓ=2 ml =-2 or -1 or 0 or +1 or +2
5 Orbitals 3d (n=3 and d means l=2)
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REPRESENTATIONS OF ORBITALS
1) probability= f(distance to nucleus)
example : s orbitals
As n increases, the most likely
distance from the nucleus to
1s find the electron increases
2s 3s
REPRESENTATIONS OF ORBITALS
2) volumes within which 90% chances to find the electron
s orbitals : spherical
1s 2s 3s
boundary surfaces for p orbitals (dumbbell-shaped)
p orbitals
have
preferential
orientations
pz px py
(m=0) (m=1) (m=-1)
boundary surfaces for d orbitals
H2O
dry Co(NO3)2 [Co(H2O)6](NO3)2
Colorless powder Pink solution
NH3
[Co(NH3)6](NO3)2
Blue solution
2s < 2p
3s < 3p <3d
etc.
Orbital energy levels Orbital energy levels
in H or one electron ions In many electron atoms
Note
that 3d
is above
4s
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A little more physics : electron Spin
BUT :
AN ELECTRON IS NOT A SPHERE (it is dimensionless)
and IT DOES NOT SPIN AROUND AN AXIS
Spin is quantified : 2 possible values
4th quantum number ms = -1/2 or +1/2
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Only MoV species provide ERP signal.
MoIV and MoVI states are silent
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Spin is quantified : 2 possible values
4th quantum number ms = -1/2 or +1/2
1 Orbital = 1 box
Electrons =arrows representing spin (1/2 or -1/2 , up or down)
??? No !!!
1s 2s 2p
1 electron
in each p
orbital
N: 1s2 2s2 2p3
How to build electron
configuration of atoms ?
The diagonal rule to fill
orbitals with electrons
Remember 4s < 3d so
4s is filled before 3d
Same for 5s and 4d,4f etc.
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Transition metals
Hydrogenase Enzymes: Made of Fe, Ni
Condensed Writing
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8. THE PERIODIC TABLE
Mendeleev 1869
based on
« periodicity »
of chemical
properties
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Elements with similar electronic structure of the outer
shell (valence shell) : in the same column
Z= 2 He Helium 1s2
Z= 10Ne Neon 1s2 2s2 2p6
Z= 18Ar Argon 1s2 2s2 2p6 3s2 3p6
Z= 36Kr Krypton 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6
2 electrons at 6 electrons at
most, 2 different most, 6 different
elements elements
STRUCTURE OF THE PERIODIC CLASSIFICATION
d-block
5 orbitals d
He :
10 electrons at most
exception
10 columns for 10 different
elements on each line
s-block p-block
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electrons 3 orbitals p
at most 6 electrons
at most
2 columns
for 2 6 columns
different for 6
elements different
on each elements on
line each line
d6
dx2-y2 dz2
ΔE
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• Arrangement of electrons in space around the nucleus
• Electron energy
(thus related to its physical and chemical activity)
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Spherical coordinates