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4 Energy Balance
• Flow system
Q- W + FiHi – FoHo ± ΔHRVrA = dE/dt
(neglecting KE and PE) kJ/s
• in a pipe where no accumulation term and possibly KE and
PE:
Qo – Ŵs+ mo ((ui2- uo2)/2 + g(zi-zo)+ (hi-ho)) = 0 kJ/ s or
Q-Ws+ m((ui2- uo2)/2 + g(zi-zo)+ (hi-ho)) = 0 kJ/
• get Bernoulli eqn if substitute ho-hi = Δh - Δ(Pv) = Q-W
• and W = PΔv – lw (friction loss)
Δh – vΔP - PΔv = Q-PΔv + lw
Δh = Q + vΔP + lw
Ws+ (uo2- ui2)/2+g(zo-zi) + vΔP + lw = 0
v = 1/ρ
Ws+ (uo2- ui2)/2+g(zo-zi) + ∫P/ρ + lw = 0
• Typically in process flow calcs perform
material balances followed by energy (as they
are coupled)
• Terms used in energy calcs:
Heat of reaction – ΔHr - enthalpy change
when stoichiometric quantities of reactants
at T and P are completely converted to
products at same T and P
ΔHr < 0 reaction is exothermic e.g most fossil fuel
combustion
ΔHr > 0 reaction endothermic e.g. most fossil fuel
pyrolysis
1.3 Heat Exchange Equipment
i. shell and tube
ii. Condensers
• heat transfer equip used to liquefy vapours where latent heat of
vap us absorbed w/ coolant
iii. Reboiler
• usually shell/tube ex used to boil liquid for recirculation
www.distillationgroup.com
iv. Cooling Towers
• used to lower temp of recirc water used in condensers and heat exchangers
• large diameter columns with special packing to give good contact with low P
drop
• water distributed thru tower via nozzles or troughs of pies and air passed thru
forced draft and induced draft fans
a)Eqm relationship
• in our applications focus on distillation columns which are series of eqm stages
• where two streams run counter-currently to each other, in each stage they are
brought into contact, mixed, and separated, to work must enter stage not in eqm
and leave very close to eqm
• distillation or fractionation is a method of separation of HC by relative volatility
ij=Ki/Kj
where K- K-values = yi/xi really a measure of separation between liquid (x)
and gas (y) fractions at a give T and P
i. fractionators
• are designed as a series of equilibrium flashes:
equilibrium flash – say have a pure component of vapour and liquid at specified T
and P, at equilibrium a certain fraction exists as vapour the rest as liquid, if change
temp and/or pressure and allow to equilibrate fractions will shift, if now add other
compounds to pure and allow to equilibrate the l and v fractions and composition
will again shift how shift determined by thermo f(comp, T, P)
v, y1
Tin, Pin, z1 TS
PS
TS
Tin
l, x1
x1 y1
in series of flashes:
vapour enters from stage below @ T1
l enters from stage above @ T2 (T1>T2)
heat and mass transfer occurs so exit streams from stage
@ bubble pt l and dew pt v at same T and P
dew pt v l at T2
T2
Stage may be a tray T
or part of packing contact
(discussed in detail
later)
v at T1 bubble pt l
T1
xBP yDP
composition of exit streams are related by equilibrium constant (K)
Ki = ydp/xbp where K=f(T,P) – calculate using thermodynamics
(del G or chem potential)
Condenser – may have total or
partial reflux
Reflux Overhead
Rectifying
Section – v enriched w/
low boilers
Stripping section – l
enriched w/ high boilers
Reboiler
Figure modified from Perry’s
Bottom Product
• May have multiple feeds at low T as approach top to provide reflux
• Use top l feed w/ crude stabilizers and deethanizers
purpose is usually meet specs for bottom product , OH composition
determined by upstream process units
• trayed
1. bubble cap – prevents l from weeping thru vapour passages
- turndown ratio 8:1-10:1
2. valve – lower cost
3. sieve or Perforated – lowest cost, high capacity but subject to weeping
• initial design calcs based in theoretical trays (eqm calcs) and then apply a tray
efficiency
http://www.tower-packing.com/Dir_structured_packing.htm
• initial design calcs based on P drop and diameter (Eckert method)
• must minimize P drop across column (low gas mass velocity) which also
prevents flooding (high l or v rates when delPgas > net gravity head of l) but
if gas mass velocity too low then must have larger column to maximize
contact between l and v
e.g. del Pmax=5-15 mm H2O/ft packed depth (max of 25) or
del Pflood = 0.115Fp0.7
where Fp is packing factor (dimensionless, del P in H2O/ft pack)
(l/v)max
flooding
operating
liquid
strippingrange
flowrate
max delP
rectifying
channeling min allowable eff
vapour flowrate
• other column problems that must be mitigated by operating properly:
foaming
entrainment
weeping (when trays rely on gas pressure to hold l start leaking l thru gas
orifices)
• the maximum amount of solute that can be absorbed by the liquid is defined
by equilibrium calcs, actual amount is less and called the operating line:
Tower top
• fluidized beds solid particles are fluidized to enhance mass and heat transfer