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Chlorides of Period 2
compound LiCl BeCl2 BCl3 CCl4 NCl3 OCl2 Cl2
Chlorides of Period 3
compound NaCl MgCl2 AlCl3 SiCl4 PCl3 SCl6 Cl2
high low
CRC Handbook of Chemistry and Physics, 1995
Bonding
Can we explain the melting point behavior
across a period?
He H-
Ne Ca+2
Ar O-2
Kr Br-
+ -
Na Cl
electron transfer
and the formation of ions
Cl Cl
covalent
HCl H 2O CH4
Some exceptions to the Octet Rule
BF3
PCl5
SF6
Electronegativity
The electronegativity difference - EN = ENhigher – EN lower
Chlorides of Period 2
compound LiCl BeCl2 BCl3 CCl4 NCl3 OCl2 Cl2
Chlorides of Period 3
Compound NaCl MgCl2 AlCl3 SiCl4 PCl3 SCl6 Cl2
non-polar
bond X Y EN = 0
Which element
is more X Y EN = 0.3
negative
O O OO O O
N2
octet complete
N N NN N N N N
X2 + energy X + X
Increasing EN
Increasing EN
105 107
Db Bh
NO RbF FeS H 2S
Modified from http://www.cem.msu.edu/~djm/cem384/ptable.html
Draw the Lewis dot structures
CO2 NH2-
H3O+ CO
HCN H2CO
(C in center)
Show the direction of electron
migration ( ) in the following.
C–H
H–F
C=O
C – Cl
H
C O
H
ionic covalent
ions
molecules
molten salts non-
conductive conductive
valence
transfer of sharing of
electrons
electrons electrons
high mp low mp
EN > 1.7 EN < 1.7
100% covalent 100% ionic
Bonding spectrum
A B A B A+ B-
Increasing EN