Beruflich Dokumente
Kultur Dokumente
Hydrogen from
Steam/CO2 Reforming
NHA Hydrogen Conference and Expo
Long Beach, CA
May 5, 2010
INTELLERGY
Biomass Sources in the U.S.
Sector Total Energy, Oil
dtpd GWe Equiv.
Mtoe/yr
Medical 29,000 29 56
Beef 180,500 18 35
Poultry 120,655 12 23
Diary 13,900 14 27
Pork/Lamb 11,900 12 23
MSW 962,500 100 194
Sewage Sludge 157,500 16 31
or Biosolids
Forest Debris 30,000 29 58
Ag Crop Waste 105,600 12 22
Food Processing 85,000 11 21
Total F eed 1,701,955 253 490
No combustion
CH4 ----> C + 2 H2
Traditional Steam Reforming of Biomass
Log(mol-%) File: C:\HSC4\sr13.OGI
3.0
CH4(g) H2(g)
2.0
H2O(g) C2H2(g)
1.0
0.0 HCl(g) C6H6(BZEg)
-1.0 C3H4(PPYg)
C2H6(g) C3H4(ALEg)
-2.0 CO(g)
CH3(g)
-3.0 H(g)
-4.0
CO2(g)
-5.0
-6.0
C2H4(g)
-7.0
CH3OH(g)
-8.0 C3H6O(PREg)
-9.0
C6H4Cl2(12Dg)
-10.0
Temperature
-11.0
200 400 600 800 1000 1200 1400 C
Steam Reforming - Intellergy Optimized Process
Log(mol-%) File: C:\HSC4\sr15.OGI
3.0
CH4(g) H2(g)
2.0
1.0 CO2(g) CO(g)
0.0
HCl(g) H2O(g)
-1.0
-2.0 H(g)
-3.0
C2H6(g)
-4.0
C2H2(g)
-5.0
CH3OH(g)
-6.0 C4H6(13B1144d4g)
C2H4(g) C4H6(13B23d2g)
-7.0
C3H6O(PREg)
-8.0 C3H8(PPEg) C4H10(NBAg)
-9.0 C4H6(13Bd6g) C4H8(2MPg)
C3H6(PPYg) C3H6(CPAg)
C6H6(BZEg)
-10.0
Temperature
-11.0
200 400 600 800 1000 1200 1400 C
Steam Reforming Gas Test Results
With 20% CO/CO2 With 50% CO/CO2
Recycle* Recycle
H2 “Green” Hydrogen 62.71% 68.0%
CO Carbon Monoxide 18.57% 6.8%
CO2 Carbon Dioxide 10.67% 25.0%
CH4 Methane 7.58% nil
C2H6 Ethane 0.48% 1ppb
C3-C6 Propane through Hexane <0.01% 1ppb
C6H6 Benzene <17 ppm 1ppb
COS Carbonyl Sulfide 4 ppm 1ppb
CS2 Carbon Disulfide 0.05 ppm 1ppb
H2S Hydrogen Sulfide <5 ppm 1ppb
C10H8 Napthalene 2.6 ppb nil
C10H7CH3 2-Methylnapthalene ~0.6 ppb nil
C12H8 Acenapthalene ~0.4 ppb nil
C12H8O Dibenzofuran 0.36 ppb nil
Polychlorinated dibenzofurans + dioxins 0.0041 TEQ ppt nil
W Hydrogen
Biomass Steam Purification
Or Waste Reformer
Rotary Kiln
Fuel-Grade
Hydrogen
°°°°°°
H2O
Electricity to SR
run plant 15% of feed-
sterilized Electricity Steam
granular generation
residue sold
as fertilizer
Hydrogen
Product Electricity
Generation
H2 Separator
Cathode
Or Waste Syngas
Anode
SOFC
Rotary Kiln
°°°°°° W
Steam
Air
Water
Kiln
W
15% of feed-sterilized Vent Solar PV &
Electricity to granular carbon-
WW thermal
Run Plant sequestering residue Steam
sold as fertilizer
Glycol Tank Electricity
20-30’
X1 X1
B1
X2 8’
T1 R2
X3 B2
P1 R2
CO2
8’ 28’ 8’ 14’ 8’
X4 P1 C1 C1
INTELLERGY
Hydrogen Use in U.S. & World
U.S. World
Ammonia 38% 61%
Oil Refining 37% 23%
Methanol 10% 9%
Merchant Use 12% 4%
Other 4% 3%
• 70-80% Carbon
• 10% Phosphorus, K2O
• 10% Potassium, P2O5
• 6% Calcium
• 4% Sodium
• 2% Sulfur
• 2% Magnesium
• 2% Organic
• 0.1-0.5% Fe, Mn, Cu, Zn
• 0% NH3
• Salt content 44 lbs/ton
Equipment Patent
Patents Applications
7 Basic 13
Chemistry
Patents
New Patent 3
Know-how
Disclosures
Trade secrets
6
Rick Noling
President and CEO
Cell: 805 698-2244
Email: noling@intellergy.com
ENERGETICS
60 dtpd Plant
3.43MWt
Fuel Cell
Thermal
Input
Hydrogen
Product
O 0.95 MW
Syngas
BioSolids To H2
Hot
7.8 MW Syngas
Drying+
Steam/CO2
Reforming
Brayton
6% No-Burn
Heat
Loss Cycle
Residue
Thermal
Reuse
Energetics100426