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REMOVAL OF ZINC AND lead BY USING MICRO
SIZE SYZYZIUM CUMINI L. LEAVES BIOMASS:
Equilibrium And Kinetic Studies
Presenter: M.Gangadhar
Authors:
M.Gangadhara, P.Kalpanaa*, N.Rakeshb, P.Kingc , B.Niranjana Raoa
Guntur, AP.
cDepartment of Chemical Engineering, A U College of Engineering,
Visakhapatnam, AP.
CLASSIFICATION OF WATER
POLLUTANTS
Sewage and other oxygen demanding
wastes
Disease causing agents
Plant nutrients
Synthetic Organic Compounds
Inorganic chemicals and minerals
Sediments
Radioactive substances
Thermal Discharge
Various technologies to remove toxic
metal ions from water
Distillation Reverse
Ion exchange osmosis
Filtration Electro dialysis
Ultra filtration Biosorption
Chemical
oxidation or
reduction
Merits and Demerits in These Technologies
Either
they are of low cost, but not effective
– can’t remove trace metal of ions
Or
Low cost
High efficiency
Minimisation of chemical and biological
sludge
No additional nutrient requirement
Regeneration of biosorbent and
Possibility of metal recovery
Examples for Biomaterials
(Agricultural Waste)
Examples for Biomaterials
(Bacteria)
Examples for Biomaterials
(Algae)
Syzygium Cumini L.Leaves
Materials and Methods
Preparation of Syzygium Cumini L. Leaves adsorbent:
The dried leaves were then cut into small pieces and
powdered using domestic mixer. In the present study the
powdered materials in the range of 75-212 m average
particle size were then directly used as adsorbents without
any pre-treatment.
Chemicals
Metal ion solutions were prepared by diluting stock metal
ion solutions, which were obtained by dissolving weighed
quantity of ZnSO4.7H2O of analytical reagent grade
obtained from MERCK (India) in double distilled water.
Metal Solution
Preparation of zinc metal solution
Stock solution of zinc concentration 1000 mg/L was prepared
by dissolving 4.354 g of 100% ZnSO4.7H2O in 1000 mL of
distilled water.
After each interval of time the sample was filtered and was
analyzed for determination of zinc ion. This gives an opportunity
for determination of optimum contact time.
The data obtained from the adsorption of zinc ions on the Syzygium
Cumini showed that a contact time of 10 min was sufficient to
achieve equilibrium and the adsorption did not change significantly
with further increase in contact time.
Effect of contact time
Cumini L leaves
% adsorption
60
20 sufficient to achieve
equilibrium and the
0
0 10 20 30 40 50 60 70 adsorption did not
Time, min
Fig.1. Effect of contact time on adsorption of lead and zinc by change significantly
Syzygium Cumini L. for 20 mg/L of metal and 0.1 g/30 mL
of adsorbent concentrations.
with further increase in
contact time.
Effect of pH
(Syzygium Cumini L Leaves)
The effect of solution pH on the equilibrium uptake of zinc
was analyzed over a pH range from 2 to 6.
concentration of zinc
40
metal solution). A sharp
increase in the
20
Lead
Zinc
biosorption occurred in
the pH range 3-6. It was
shown that the
0
1 2 3 4 5 6 7
pH
Fig.3. Effect of pH on lead,zinc adsorption by Syzygium Cumini L. percentage of adsorption
for 20 mg/L of metal and 0.1 g/30 mL of adsorbent concentration.
(Size 75 micro meter) increased by increasing
the pH.
Effect of metal ion concentration
Syzygium Cumini L leaves
Then the samples were filtered from adsorbent and they are
analyzed for metal ion.
Effect of metal ion concentration
60 60
Lead % Adsorption
Lead Metal Uptake
initial metal ion concentration.
40 Zinc % Adsorption
Zinc Metal Uptake
40 This increase (4.83 to 20.35
mg/g) is a result of the increase
20 20 in the driving force i.e.
concentration gradient.
0
0 20 40 60 80 100
0
120
However, the percentage
Concentration, mg/L adsorption of zinc ions on
Fig.2. Effect of metal concentration on the adsorption of lead,zinc by
Syzygium Cumini L. at 0.1 g/30 mL of adsorbent concentration.
Syzygium Cumini was
(Size 75 micro meter and pH is 6) decreased from 80.51 to 67.86%.
Effect of average particle size of the
adsorbent
(Syzygium Cumini L Leaves)
80
Adsorbent size, m
Fig.5. Effect of Syzygium Cumini L. particle size on adsorption of lead,zinc
for 20 mg/L of metal and 0.1 g/30 mL of adsorbent concentration.
(pH is 6)
Effect of adsorbent dosage
(Syzygium Cumini L leaves)
92
% adsorption
90 increase in adsorbent
88 dosage from 0.1 to 0.5 g.
86
This shows that very small
dosage of adsorbent i.e. 0.1
84
82 Lead
80
Zinc
g is sufficient to treat about
78
0.0 0.1 0.2 0.3 0.4 0.5 0.6
30 mL of 20 mg/L zinc
Adsorbent dosage, g concentration solutions
effectively.
Fig.4. Effect of Syzygium Cumini L. dosage on adsorption of lead,zinc
for 20 mg/L of metal concentration.
(Size 75 micro meter and pH is 6)
ADSORPTION ISOTHERMS
qeq K f C m
eq
where K f and m are Freundlich constants characteristic of the
system. and are indicators of adsorption capacity and adsorption
intensity, respectively.
1.4
1.2
log qe
1.0
0.8
Lead
Zinc
0.6
0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6
log Ce
1.8
1.6
1.4
Ce/qe, g/L
1.2
1.0
0.8
Lead
0.6
Zinc
0.4
0 5 10 15 20 25 30 35
Ce, mg/L
The Langmuir model is probably the best known and most widely applied
sorption isotherm. It has produced good agreement with a wide variety of
experimental data. The Langmuir equation has been used extensively for
dilute solutions in the following form,
ACe
qe
1 BC eg
Where A(L/g) and B (L/mg) are the Redlich-Peterson isotherm constants
and g is the Redlich Peterson isotherm exponent, which lies between 0 and
1
Freundlich isotherm
1.6
1.4
1.2
log qe
1.0
0.8
Lead
Zinc
0.6
0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6
log Ce
ln AT C e
RT
qe
bT
22
20
18
16
14
qe
12
10
6 Lead
Zinc
4
2
0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0
ln Ce
25
20
15
qe
10
5
Experimental
Langmuir
0 Freundlich
Redlich-Peterson
Temkin
0 5 10 15 20 25 30
Ce
20
15
10
qe
5 Experimental
Langmuir
Freundlich
Redlich-peterson
0
Temkin
0 5 10 15 20 25 30 35
Ce
R2 0.9971
K f mg / g
2.027
n
Freundlich 0.678
R2 0.9908
bT A ( L / mg ) 0.78
B L mg 56.9401
Redlich-Peterson
g -1.5644
0.3950
R2
AT L g 0.455
Temkin bT 345.95
R2
0.98709
CONCLUSIONS
M.Gangadhar
GMRIT