𝜕𝜌

1 + 𝛻. ഥ =0
𝜌𝑈
𝜕𝑡
𝜕(𝜌𝑈)ഥ
2 + 𝛻. (𝜌𝑈𝑈) = - 𝛻P - 𝛻.(𝜏Ӗ + 𝜏ന𝑡 ) + 𝜌തg
𝜕𝑡

2
3 ഥ + (𝛻 𝑈)
𝜏Ӗ = -𝜇 𝛻 𝑈 ഥ 𝛿Ӗ
ഥ 𝑇 - ( 𝜇 − 𝑘) (𝛻.𝑈)
3

2
4 ഥ + (𝛻 𝑈)
𝜏ന𝑡 = 𝜇𝑡 𝛻 𝑈 ഥ 𝑇 - (𝜇𝑡 ഥ + 𝜌𝑘)𝛿Ӗ
(𝛻.𝑈)
3

𝜕(𝜌ℎ)
5 ഥ = 𝛻.((λ+ λt ) 𝛻T) + 𝛻. σ𝑛𝑖=1 ℎ𝑖𝜌 𝐷𝑖 + 𝐷𝑡 𝑖 𝛻𝑌𝑖
+ 𝛻. (𝜌𝑈h)
𝜕𝑡 ,

6 𝜕(𝜌𝑠𝐶𝑝 𝑠 𝑇𝑠)
, = 𝛻.(λs,eff 𝛻𝑇𝑠) + 𝑆ℎ
𝜕𝑡

7 Sh = 𝜌 s σ 𝑚
𝑗=1 𝑟𝑗 (−∆
𝐻𝑗)
8 CH4 + H2O ↔ CO +3H2 ∆H1= 206.1 KJ/mol

9 CO + H2O ↔ CO2 + H2 ∆H2= -41.15 KJ/mol

10 CH4 + 2H2O ↔ CO2 + 4H2 ∆H3= 165.0 KJ/mol

 𝜕(𝜌𝑌𝑖 )
11 ഥ i)= 𝛻. (𝜌(𝐷𝑖 + 𝐷𝑡 𝑖) 𝛻Yi
+𝛻. (𝜌𝑈Y
𝜕𝑡 ,

12 𝜕(𝜌𝑠𝑌𝑠 𝑖 )
, = 𝛻. 𝜌𝑠𝐷𝑠, 𝑒𝑓𝑓 , 𝑖𝛻𝑌𝑠, 𝑖 + 𝑆𝑖
𝜕𝑡

𝜀𝑠 𝐷𝑠 𝑖 𝐷𝐾 𝑖
13 D s,eff,i = , ,
𝜏𝑠 𝐷𝑠 𝑖 +𝐷𝐾 𝑖
, ,

14 Si = 𝜌𝑠 σ𝑛𝑗=1 𝛼𝑖𝑗 𝑟𝑗 𝑀𝑖

15 ∆𝑃 (1−𝜀)2 𝜇 𝑈0 (1−𝜀) 𝜌 𝑈02

= 150 2+ 1.75
𝐿 𝜀3 φ2𝑠 𝑑𝑝 𝜀3 φ𝑠 𝑑𝑝
 ∆𝑃 (1−𝜀)2 𝜇 𝑈0 (1−𝜀) 𝜌 𝑈02
16 =A 2 + B
𝐿 𝜀3 𝑑𝑝 𝜀3 𝑑𝑝

1
17 Aw = Bw = 1+ 𝑑𝑡
2 (1−𝜀)
𝑑𝑝

∆𝑃 (1−𝜀)2 𝜇 𝑈0 (1−𝜀) 𝜌 𝑈02

18 =A 2+ B
𝐿 𝜀3 φ2𝑠,𝑐 𝑑𝑝 𝜀3 φ𝑠,𝑐 𝑑𝑝

19 φ𝑠,𝑐 = φ𝑠+ C

20 C= C1 (𝑈𝑂 )𝐶2
 𝜎2 𝐷 𝐷 2 𝑈0𝐿
21 = 2 −2 [1 − exp − ]
𝑡ҧ 2 𝑈0 𝐿 𝑈0 𝐿 𝐷

2 σ 𝑡𝑖2 𝐶𝑖 ∆𝑡𝑖
22 𝜎 = σ 𝐶𝑖 ∆𝑡𝑖
- 𝑡ҧ 2

σ 𝑡𝑖𝐶𝑖 ∆𝑡𝑖
23 ҧ
𝑡= σ 𝐶𝑖 ∆𝑡𝑖

1 𝑉
𝑉𝑝
‫׬‬0 𝑝 𝑟𝑖 (𝐶𝑖, 𝑇𝑖 )𝑑𝑉𝑝
24 η𝑖= 1 𝐴
𝐴𝑝
‫׬‬0 𝑝 𝑟𝑖 (𝐶𝑖𝑠 ,𝑇𝑖𝑠 )𝑑𝐴𝑝