ELECTRONIC CONFIGURATION CONFIGURATION Electron Configuration The distribution of electrons of an atom or molecule in atomic or molecular orbitals. VALENCE ELECTRON
• Electrons in the outermost energy level.
Lewis Electron-Dot Structure Used to represent the number of valence electron. Pioneered and named after Gilbert Newton Lewis who explained the relationship between electron structure and chemical bonding. Quantum theory (otherwise known as quantum physics or quantum mechanics) is one of the two main planks of modern physics, along with general relativity, and between them the two theories claim to explain virtually everything about the universe. General relativity gives us our picture of the very big (space-time and gravity), while quantum theory gives us our picture of the very small (atoms and their constituents).
In 1900, physicist Max Planck presented his quantum theory to the
German Physical Society. Planck had sought to discover the reason that radiation from a glowing body changes in color. Planck wrote a mathematical equation involving a figure to represent these individual units of energy, which he called quanta. The Development of Quantum Theory In 1900, Planck made the assumption that energy was made of individual units, or quanta. In 1905, Albert Einstein theorized that not just the energy, but the radiation itself was quantized in the same manner. In 1924, Louis de Broglie proposed that there is no fundamental difference in the makeup and behavior of energy and matter; on the atomic and subatomic level either may behave as if made of either particles or waves. This theory became known as the principle of wave-particle duality: elementary particles of both energy and matter behave, depending on the conditions, like either particles or waves. In 1927, Werner Heisenberg proposed that precise, simultaneous measurement of two complementary values - such as the position and momentum of a subatomic particle - is impossible. Contrary to the principles of classical physics, their simultaneous measurement is inescapably flawed; the more precisely one value is measured, the more flawed will be the measurement of the other value. This theory became known as the uncertainty principle, which prompted Albert Einstein's famous comment, "God does not play dice." QUANTUM MECHANICAL MODEL According to the Quantum Machanical Model, elctrons have no precise orbits. Instead their motion can only be described by the probability of finding them in certain regions surrounding the nucleus. ORBITALS An atomic orbital is a region around the nucleus of an atom where an electron with a given energy is likely to be found.
Orbitals have characteristics of shapes, sizes, and
energies. But orbitals do not describe how the electron actually moves. The distribution of electrons among the orbitals of an atom is called electron configuration. The electron configuration of an atom describes where the electrons are found and what energies they possess. Electron configuration of atoms are determined by distributing the atom's electrons among levels, sublevels, and orbitals based on a set of stated principles. The s sublevel is always lowest in energy, followed by the p , then the d , and finally the f. When the electrons populate the lowest energy orbitals available the atom is said to be in its ground state. How are the electrons distributed in an atom? 1. The selection of orbitals for the electrons of an atom in its ground state follows an order determined by what is known as the “Aufbau ( German: build -up) principle”. Electrons will successively occupy the available orbitals in order of increasing energy. 2. When electrons enter a sublevel containing more than one orbital, they will spread out over the available orbitals with their spins in the same direction before they pair up with opposite spins. This rule is known as Hund's rule of multiplicity, which was proposed by Friedrich Hund, a German Physicist. Example: Give the electron configuration of Oxygen and its orbital diagram. Electron Configuration
1S2 2s2 2p4
Orbital Diagram SHORT HAND METHOD OF ELECTRON CONFIGURATION STEP 1 Find the element on the periodic table. STEP 2 Go back to the last noble gas that was passed (atomic #). STEP 3 Write the symbol of the noble gas in brackets to start your electron configuration. Put the atomic # of the noble gas beneath the symbol to let you know the number of electrons already presented. STEP 4 Continue your electron configuration using row after the noble gas. STEP 5 Continue writing your electron configuration following the chart until you reach the correct number of electron. ACTIVITY Give the electronic configuration of the following: 1.Na 2.N 3.Ne 4.Ca 5.Rb