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water Chemistry
Water cooling was introduced in 1956 by AEI (UK) with a view to accommodate
larger generator power outputs
Generator with above 400 MVA require a more efficient cooling method. So that
adopted the Hydrogen-Water cooling system.
The stator windings are directly water cooled by Deionized water. Supplied by a
closed loop cooling system.
Deionized water flows through hollow copper strands located in the stator
windings.
Introduction:
Briefly the schematics for stator water system is :
Water & Hydrogen cooling system
Simplified Schematic diagram
Vent at Roof
Drain
Generator
Make-up line
Deionizer
Main filter
Storage tank
Plate heat
exchanger
FCV PHE-A P
PHE-B P
SCW pumps
Make-up filter
Stator water cooling system
Five points of stator water cooling system
To provide deionize water for cooling to the Generator stator hollow
windings at a rated pressure and rated flow.
To detect and alarm if the conductivity of DM water goes up to
unsafe level.
To provide filtration to remove any particulates which could plug the
very small bores of the stator tubes.
To provide venting to atmosphere for any H2 gas that becomes
entrained in the stator coolant.
To provide for addition of DM coolant to make-up for any loss due to
leaks or evaporation from the stator cooling system.
Problems on Stator water coils and solutions
End-winding vibration
2. There is always some dissolution of the oxide layer, but the dissolved copper is trapped by the ion
exchanger. However, the risk of forming thick oxide layers cannot be excluded. In order to achieve a
stable oxide layer, oxygen levels must be maintained high (e.g. forced air flow into the water tank) at all
times. By introducing air, carbon dioxide is also added to the system. However, it may still be susceptible to
low-pH corrosion from carbon dioxide and carbonates if these are not removed by the mixed bed polisher. So
in this case mix bed polisher will be large.
3. If there is a hydrogen leak into the stator cooling water system, the hydrogen can replace the dissolved
oxygen and create low–dissolved oxygen transients in the system, causing oxides to be released.
B. High Dissolved Oxygen and Neutral pH
Showing the configuration of a typical Neutral pH and High Dissolved Oxygen Type Stator Water System
C . Low Dissolved Oxygen and High pH
Description :
1.This treatment has the basic features of a low oxygen operation. With alkaline treatment, the water is
alkalized by adding a small concentration of sodium hydroxide, in order to lower copper oxide solubility
and thus the chance of migration of oxides. The quantity of oxides produced however is as with neutral
treatment.
2. The same requirements as mentioned above for low oxygen/neutral pH treatment apply. In order to
achieve a constant low solubility, it is very important to keep the pH value stable.
3. Alkalization can be achieved in two different ways:
injection of a diluted NaOH solution via an injection pump, controlled by conductivity [4].
constant leaching of NaOH from an ion exchanger
4. One method is the use of a dual bed demineralizer, consisting of a mixed bed filter followed in
series by a weakly acidic cation exchanger, loaded with a measured quantity of NaOH. The
cation exchanger provides constant high purity water, that leaches an equilibrium concentration
of NaOH from the cation exchanger [4].
5. Another method is the use of a dual bed demineralizer, consisting of a mixed bed filter in
parallel to a strongly acidic cation exchanger, loaded with NaOH. The Na concentration is
controlled by suitable adjustment of the water flow through these two ion exchange beds [14].
Possible ingress of carbon dioxide traces are buffered by the alkalizer and therefore have smaller
influence on pH than with neutral treatment.
C . Low Dissolved Oxygen and High pH
Showing the configuration of a typical High pH and Low Dissolved Oxygen Type Stator Water System
Monitoring Chemistry Parameters
Our system is neutral pH & high DO system. So accordingly these below
chemistry parameters to be monitored round the clock.
b) pH:
Measurement of pH required to maintain it according to respective treatment
regime. (N.B. It may be noted that measurement of pH of in high purity water is
difficult and may be unreliable. Conductivity is commonly used to indirectly
monitor the pH).
For elevated pH system, caustic/ammonia dosing system adopted.
Chemistry Parameters
c) Conductivity:
It’s the measure of water’s ability to pass on a current of electricity.
Free ions presence in 1 centimeter water sample is known as water
conductivity.
Conductivity is temperature dependent.
e.g. Conductivity of pure DM water at 25 Deg C= 0.054 us/cm, while that at 60
deg C= 0.25 us/cm
d) Electro Chemical Potential ( ECP):
Research project developed by EPRI has concluded that ECP as a significant
parameters for copper release and deposition
It shows that change in oxidation state of Copper (+1 to +2 and vice versa)
induces stresses which is driving factor for particulate release and deposition
Chemistry Parameters
Range of ECP as established by EPRI for two operating regimes are as follows :
e) Copper:
The monitoring of copper is a essential part of stator water chemistry control.
Regular copper analysis give reference values for trending. The value should be
less than 40 ppb to be in safer zone.
Operational Parameters
In addition to the chemistry parameters, some operational parameters to be
monitored periodically .
Cleaning/Replacing filters