Chemical bonds Types of bonds Intermolecular forces Nature of bonding and properties Chemical bond • Force of attraction between atoms that holds them together • Octet rule • Duplet rule • 3-ways to complete octet Types of chemical bonds • Ionic bond • Colvalent bond • Coordinate covalent bond • Metallic bond Ionic bond • The bond which forms by complete transfer of electron from one atom to another atom • NaCl • Na (Ne) • Cl(Ar) • Exo Covalent bond • The bond which is formed by mutual sharing of electrons is called covalent bond • Types • 1)single covalent bond • H2,Cl2,CH4 etc • 2)double covalent bond • O2,C2H4 etc • 3)triple covalent bond • N2,C2H2 etc • Coordinate covalent bond • The bond in which bond pair is donated by only one bonded atom • Acceptor • Donor • NH4,NH3+BF3 Polar and non polar covalent bond • Non polar • Covalent bond between 2 similar atoms • H2, Cl2 etc • Polar • Covalent bond between 2 different atoms • HCl,H2O etc • Ionic or covalent • Electronegativity difference 1.7 Metallic bond • The bond between metal atoms due to free electrons Intermolecular forces • The weak forces between molecules are called intermolecular forces • HCll 17 kj HClg • 430 kj to break chemical bond Dipole dipole interaction • When partial positive and partial nagative molecules locate at different positions they arranged themselves in way that partial positive charge attract partial nagative charge and the force exist is dipole dipole interaction • HCl Hydrogen bonding • When partially positive charged hydrogen atom of one molecule attracts and forms a bond with the partially negatively charged atom of the other molecule the bonding is called hydrogen bonding • H2O etc • Physical properties water and alcohol boiling points • Ice and water density Nature of bonding and properties • Ionic bond • Properties • Crystalline solids • Conductance • High melting and boiling points • Solubility Covalent bond • Properties • Low melting and boiling points • Solubility • Conductance • Large molecules have high melting and boiling points Polar and non polar compounds • Conductance • Solubility Coordinate covalent compounds • Solubility • Rigid • Metals properties • Maleable and ductile • Cations • Conductors • High melting and boiling points
Electrochemical Determination of Gatifloxacin, Moxifloxacin and Sparfloxacin Fluoroquinolonic Antibiotics On Glassy Carbon Electrode in Pharmaceutical Formulations